:3-Hexanone
{{Chembox
| ImageFile = 3-Hexanone.svg
| PIN = Hexan-3-one
| OtherNames = Ethyl propyl ketone
|Section1={{Chembox Identifiers
| CASNo = 589-38-8
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = P601A79G79
| PubChem = 11509
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 89891
| ChemSpiderID = 11025
| SMILES = O=C(CC)CCC
| InChI = 1/C6H12O/c1-3-5-6(7)4-2/h3-5H2,1-2H3
| InChIKey = PFCHFHIRKBAQGU-UHFFFAOYAM
| StdInChI = 1S/C6H12O/c1-3-5-6(7)4-2/h3-5H2,1-2H3
| StdInChIKey = PFCHFHIRKBAQGU-UHFFFAOYSA-N
}}
|Section2={{Chembox Properties
| C=6 | H=12 | O=1
| Appearance = Colorless liquid{{GESTIS|ZVG=493338}}
| MeltingPtC =
| BoilingPtC = 123
| MagSus = −69.03·10−6 cm3/mol
}}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPtC = 20
| AutoignitionPt =
| LD50 = 2740 mg/kg (oral rat)
2580 mg/kg (dermal, rabbit)
}}
}}
3-Hexanone (ethyl propyl ketone) is an organic compound with the formula C6H12O. It is a ketone used as a solvent and as a chemical intermediate.
According to IFF, it was described as having Sweet, Fruity, Waxy, Grape organoleptic properties.{{cite web | url=http://lmrnaturals.iff.com/en/site-services/flavor-online-compendium-iframe#3-hexanone | title=Online Compendium }}
Preparation
3-Hexanone can be obtained by oxidation of 3-hexanol:
It is also the product of the Grignard reaction of propylmagnesium bromide with propionitrile: