:Borane tert-butylamine

{{italic title|string=tert}}

{{Chembox

| Name = Borane tert-butylamine

| ImageFile = Borane tert-butylamine.svg

| ImageSize = 200px

| ImageAlt =

| IUPACName =

| OtherNames = tert-Butylamine borane; Trihydro(2-methyl-2-propanamine) boron

|Section1={{Chembox Identifiers

| CASNo = 7337-45-3

| PubChem = 6364547

| EINECS = 230-851-5

| ChemSpiderID = 451414

| SMILES = NC(C)(C)C.B

}}

|Section2={{Chembox Properties

| C=4 | H=14 | B=1 | N=1

| Appearance = White solid

| Density =

| MeltingPtC = 96

| MeltingPt_ref = {{cite journal|last1=Nöth|first1=Heinrich|last2=Beyer|first2=Hasso|last3=Vetter|first3=Hans-Joanchim|title=Beiträge zur Chemie des Bors, XXV. Bis(amin)-dihydrido-bor(III)-halogenide, [(R3–nHnN)2BH2]X2|journal=Chemische Berichte|volume=97|issue=1|year=1964|pages=110–118|issn=0009-2940|doi=10.1002/cber.19640970115}}

| BoilingPt =

| Solubility =

}}

|Section3={{Chembox Hazards

| MainHazards =

| FlashPt =

| AutoignitionPt =

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Borane tert-butylamine is an amine borane complex derived from tert-butylamine and borane. It is a colorless solid.

The compound is prepared by the reaction of tert-butylammonium chloride and sodium borohydride:Girolami, G. S.; Rauchfuss, T. B. and Angelici, R. J., Synthesis and Technique in Inorganic Chemistry, University Science Books: Mill Valley, CA, 1999.{{ISBN|0935702482}}

:t-BuNH3Cl + NaBH4t-BuNH2BH3 + H2 + NaCl

In organic synthesis, borane tert-butylamine can be used for selective reduction of certain functional groups including aldehydes, ketones, oximes, and imines.{{cite web |title=Tert-Butylamine borane |url=https://pubchem.ncbi.nlm.nih.gov/compound/Tert-Butylamine-borane |website=pubchem.ncbi.nlm.nih.gov |publisher=NCBI |accessdate=3 September 2019}}

In photographic processing, it is used in the E-4 process, as "chemical enlighting" step in the processing of the film.

See also

References