:Caesium cadmium chloride
{{chembox
| verifiedrevid = 404130686
| Name = Caesium cadmium chloride
| IUPACName = Caesium cadmium chloride
| OtherNames = {{unbulleted list|Caesium trichlorocadmate|Caesium chlorocadmate|Caesium trichlorocadmate(II)}}
| Section1={{Chembox Identifiers
| CASNo = 13845-08-4
| PubChem = 159356594
| InChI = 1S/Cd.3ClH.Cs/h;3*1H;/q+2;;;;+1/p-3
| InChIKey = LHZPOBUPLFKLBV-UHFFFAOYSA-K
| SMILES = [Cd+2]([Cl-])([Cl-])[Cl-].[Cs+]
| SMILESOther = [Cs+].[Cl-][Cd+2]([Cl-])[Cl-]}}
| Section2 = {{Chembox Properties
| MolarMass = 351.675 g/mol
| Appearance = White or colourless solid
}}
| Section3 = {{Chembox Structure
| Structure_ref =
| CrystalStruct = hexagonal
| SpaceGroup = P63/mmc
| PointGroup =
| LattConst_a = 7.403
| LattConst_b =
| LattConst_c = 18.406
| LattConst_alpha =
| LattConst_beta =
| LattConst_gamma =
| LattConst_ref =
| LattConst_Comment =
| UnitCellVolume =
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| Dipole =
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Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group (where A=alkali metal, M=bivalent metal, X=halogen ions). It crystallizes in a hexagonal space group P63/mmc with unit cell lengths a = 7.403 Å and c = 18.406 Å, with one cadmium ion having D3d symmetry and the other having C3v symmetry.{{cite journal|last1=Chang|first1=Jin Rong.|last2=McPherson|first2=Gary L.|last3=Atwood|first3=Jerry L.|title=Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride|journal=Inorganic Chemistry|date=December 1975|volume=14|issue=12|pages=3079–3085|doi=10.1021/ic50154a044}}
It is formed when an aqueous solution of hydrochloric acid containing an equimolar solution of caesium chloride and cadmium chloride.Electron paramagnetic spectrum of manganese(II)-manganese(II)
pairs in single crystals of cesium cadmium chloride.
Electronic structure of the nonachlorodimanganate(5-) dimer
Gary L. McPherson, and Jin Rong Chang,
Inorg. Chem., 1976, 15 (5), 1018-1022. {{doi|10.1021/ic50159a006}}
References
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{{DEFAULTSORT:Caesium Cadmium Chloride}}
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