:Hexaborane(12)

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| ImageFile = B6H12.png

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| ImageFile1 = Hexaborane(12)-GED-view-1-3D-bs-17.png

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| Section1 = {{Chembox Identifiers

| CASNo_Ref = {{cite web |title=Hexaborane(12) |url=https://webbook.nist.gov/cgi/formula?ID=C12008194 |website=webbook.nist.gov |publisher=National Institute of Standards and Technology |language=en}}

| CASNo = 12008-19-4

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| EINECS =

| StdInChI=1S/B6H12/c7-1-3-4(5(1,3,7)10-4)2-6(3,4,8-2)9-3/h3-6H,1-2H2

| StdInChIKey =ZMLJCODVOXNMHE-UHFFFAOYSA-N

| SMILES = [BH2]12[BH]34([H]1)[BH]256[BH]38([H]4)[BH]75([H]6)[BH2]8[H]7

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| Section2 = {{Chembox Properties

| B=6 | H=12

| Appearance = colorless liquid

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| MeltingPtC = -82.3

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| BoilingPt = {{convert|85|C|F K}} (approx)

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| Section3 = {{Chembox Hazards

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Hexaborane(12) is an inorganic compound with the formula B6H12. It is an obscure member of the boranes. It is a colorless liquid that, like some other boron hydride clusters, is readily hydrolyzed and flammable.

The molecular structure conforms to C2 symmetry group. With the formula BnHn+6, it is classified as an arachno-cluster. As such the boron positions match six of the boron positions in the closo-B8H{{su|b=8|p=2−}}.

Preparation

It is typically prepared by the cluster expansion method from B5H{{su|b=8|p=−}}, the conjugate base of pentaborane(9):{{Greenwood&Earnshaw2nd}} p.172.

:LiB5H8 + 1/2 B2H6 → LiB6H11

:LiB6H11 + HCl → B6H12 + LiCl

References

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{{Boron compounds}}

{{Hydrides by group}}

Category:Boranes

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