:Hexaborane(12)
{{Chembox
| ImageFile = B6H12.png
| ImageSize =
| ImageAlt =
| ImageFile1 = Hexaborane(12)-GED-view-1-3D-bs-17.png
| IUPACName =
| OtherNames =
| Section1 = {{Chembox Identifiers
| CASNo = 12008-19-4
| RTECS =
| EINECS =
| StdInChI=1S/B6H12/c7-1-3-4(5(1,3,7)10-4)2-6(3,4,8-2)9-3/h3-6H,1-2H2
| StdInChIKey =ZMLJCODVOXNMHE-UHFFFAOYSA-N
| SMILES = [BH2]12[BH]34([H]1)[BH]256[BH]38([H]4)[BH]75([H]6)[BH2]8[H]7
}}
| Section2 = {{Chembox Properties
| B=6 | H=12
| Appearance = colorless liquid
| Density =
| MeltingPtC = -82.3
| MeltingPt_ref =
| BoilingPt = {{convert|85|C|F K}} (approx)
| BoilingPt_ref =
| Solubility =
}}
| Section3 = {{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}
}}
Hexaborane(12) is an inorganic compound with the formula B6H12. It is an obscure member of the boranes. It is a colorless liquid that, like some other boron hydride clusters, is readily hydrolyzed and flammable.
The molecular structure conforms to C2 symmetry group. With the formula BnHn+6, it is classified as an arachno-cluster. As such the boron positions match six of the boron positions in the closo-B8H{{su|b=8|p=2−}}.
Preparation
It is typically prepared by the cluster expansion method from B5H{{su|b=8|p=−}}, the conjugate base of pentaborane(9):{{Greenwood&Earnshaw2nd}} p.172.
:LiB5H8 + 1/2 B2H6 → LiB6H11
:LiB6H11 + HCl → B6H12 + LiCl