:Lithium chloride (data page)

This page provides supplementary chemical data on Lithium chloride.

Solubility

class="toccolours" border="1" style="margin: 0 0 1em 1em; border-collapse: collapse;" ! {{chembox header}} \| Solubility of LiCl in various solvents (g LiCl / 100g of solvent at 25 °C)
H₂O	84.5
Liquid ammonia	3.02
Liquid sulfur dioxide	0.012
Methanol	21 - 41
Formic acid	27.5
Sulfolane	1.5
Acetonitrile	0.14
Acetone	0.83
Formamide	28.2
Dimethylformamide	11 - 28
align="center" colspan="2" \| Reference: Burgess, J. Metal Ions in Solution (Ellis Horwood, New York, 1978) {{ISBN\|0-85312-027-7}}

== Thermodynamic properties ==

border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;" ! {{chembox header}} \| Phase behavior
Triple point \| ? K (? °C), ? Pa
Critical point \| ? K (? °C), ? Pa
Std enthalpy of fusionΔ_fusH^o \| +19.9 kJ/mol
Std entropy of fusionΔ_fusS^o \| ? J/(mol·K)
Std enthalpy of vaporizationΔ_vapH^o \| ? kJ/mol
Std entropy of vaporizationΔ_vapS^o \| ? J/(mol·K)
{{chembox header}} \| Solid properties
Std enthalpy of formation Δ_fH^o_solid \| −408.27 kJ/mol
Standard molar entropy S^o_solid \| 59.33 J/(mol K)
Heat capacity c_p \| 47.99 J/(mol K)
{{chembox header}} \| Liquid properties
Std enthalpy of formation Δ_fH^o_liquid \| −390.76 kJ/mol
Standard molar entropy S^o_liquid \| ? J/(mol K)
Heat capacity c_p \| ? J/(mol K)
{{chembox header}} \| Gas properties
Std enthalpy of formation Δ_fH^o_gas \| −195.2 kJ/mol
Standard molar entropy S^o_gas \| 212.7 J/(mol K)
Heat capacity c_p \| 33.2 J/(mol K)

border="1" cellspacing="0" cellpadding="6" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"

! {{chembox header}} | Phase behavior

Triple point

| ? K (? °C), ? Pa

Critical point

| ? K (? °C), ? Pa

Std enthalpy
of fusionΔ_fusH^o

| +19.9 kJ/mol

Std entropy
of fusionΔ_fusS^o

| ? J/(mol·K)

Std enthalpy
of vaporizationΔ_vapH^o

| ? kJ/mol

Std entropy
of vaporizationΔ_vapS^o

| ? J/(mol·K)

{{chembox header}} | Solid properties

Std enthalpy
of formation Δ_fH^o_solid

| −408.27 kJ/mol

Standard molar entropy
S^o_solid

| 59.33 J/(mol K)

Heat capacity c_p

| 47.99 J/(mol K)

{{chembox header}} | Liquid properties

Std enthalpy
of formation Δ_fH^o_liquid

| −390.76 kJ/mol

Standard molar entropy
S^o_liquid

| ? J/(mol K)

Heat capacity c_p

| ? J/(mol K)

{{chembox header}} | Gas properties

Std enthalpy
of formation Δ_fH^o_gas

| −195.2 kJ/mol

Standard molar entropy
S^o_gas

| 212.7 J/(mol K)

Heat capacity c_p

| 33.2 J/(mol K)

Spectral data

{{chembox header}} \| IR
border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;" ! {{chembox header}} \| UV-Vis
Lambda-max \| ? nm
Extinction coefficient \| ?
Major absorption bands \| ? cm⁻¹
{{chembox header}} \| NMR
Proton NMR
Carbon-13 NMR
Other NMR data
{{chembox header}} \| MS
Masses of main fragments \|

Structure and properties data

border="1" cellspacing="0" cellpadding="3" style="margin: 0 0 0 0.5em; background: #FFFFFF; border-collapse: collapse; border-color: #C0C090;"

! {{chembox header}} | Structure and properties

Index of refraction

| 1.662

Dielectric constant

| ? C²/(N·m²) at ? °C

Bond strength

| ?

Bond length

| ?

Magnetic susceptibility

| -24.3 cgs units

Temperature Relative Humidity over saturated solution in water

Temperature(C){{cite journal\|last1=Arnold\|first1=Wexler\|title=Relative Humidity-Temperature Relationships of Some Saturated Salt Solutions in the Temperature Range 0 0 to 500 C\|journal=Journal of Research of the National Bureau of Standards\|date=1954\|volume=53\|issue=1\|page=19\|doi=10.6028/jres.053.003\|doi-access=free}}	Relative Humidity(%)
class="wikitable"
0.23	14.7
9.56	13.4
19.22	12.4
29.64	11.8
39.64	11.8
46.76	11.4

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as [https://web.archive.org/web/20070630043133/http://siri.org/msds/index.php SIRI], and follow its directions.

References

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