:Potassium thiocyanate
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477003516
| ImageFile1 = Potassium thiocyanate.png
| ImageSize1 = 150px
| ImageFile2 = Potassium-thiocyanate-xtal-3D-vdW-B.png
| ImageSize2 =
| ImageFile3 = Crystals of Potassium Thiocyanate.jpg
| ImageSize3 = 150px
| Name = Potassium thiocyanate
| OtherNames = Potassium sulfocyanate
Potassium isothiocyanate (tautomeric form)
Potassium thiocyanide
Potassium rhodanide
|Section1={{Chembox Identifiers
| CASNo = 333-20-0
| CASNo_Ref = {{cascite|correct|CAS}}
| Beilstein = 3594799
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 9150
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 30951
| EINECS = 206-370-1
| Gmelin = 21362
| PubChem = 516872
| RTECS = XL1925000
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = TM7213864A
| InChI = 1/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
| InChIKey = ZNNZYHKDIALBAK-REWHXWOFAT
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = ZNNZYHKDIALBAK-UHFFFAOYSA-M
| SMILES = C(#N)[S-].[K+]
}}
|Section2={{Chembox Properties
| Formula = KSCN
| MolarMass = 97.181 g mol−1
| Appearance = Colorless deliquescent crystals
| Odor = Odorless
| Density = 1.886 g/cm3
| Solubility = 177 g/100 mL (0 °C)
217 g/100 mL (20 °C)
| SolubleOther = acetone: 21.0 g/100 mL
ethanol: soluble{{Citation needed|reason=needs reference to literature determination of KSCN solubility in ethanol|date=December 2024}}
| MeltingPtC = 173.2
| BoilingPtC = 500
| BoilingPt_notes = (decomposes)
| MagSus = −48.0·10−6 cm3/mol
}}
|Section7={{Chembox Hazards
| ExternalSDS = [http://www.inchem.org/documents/icsc/icsc/eics1088.htm ICSC 1088]
| NFPA-H = 2
| NFPA-F = 0
| NFPA-R = 0
| NFPA-S =
| GHSPictograms = {{GHS05}}{{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|302|312|318|319|332|412}}
| PPhrases = {{P-phrases|261|264|270|271|273|280|301+312|302+352|304+312|304+340|305+351+338|310|312|322|330|337+313|363|501}}
| FlashPt =
| PEL =
}}
|Section8={{Chembox Related
| OtherCations = Sodium thiocyanate
Ammonium thiocyanate
| OtherAnions = Potassium cyanate
Potassium cyanide
}}
}}
Potassium thiocyanate is the chemical compound with the molecular formula KSCN. It is an important salt of the thiocyanate anion, one of the pseudohalides. The compound has a low melting point relative to most other inorganic salts.
Uses
=Chemical synthesis=
Aqueous KSCN reacts almost quantitatively with Pb(NO3)2 to give Pb(SCN)2, which has been used to convert acyl chlorides to isothiocyanates.{{OrgSynth | author = Smith, P. A. S. | author2 = Kan, R. O. | title = 2a-Thiohomophthalimide | year = 1973 | collvol = 5 | collvolpages = 1051 | prep = cv5p1051}}
KSCN converts ethylene carbonate to ethylene sulfide.{{OrgSynth | author = Searles, S. | author2 = Lutz, E. F. | author3 = Hays, H. R. | author4 = Mortensen, H. E. | title = Ethylenesulfide | year = 1973 | collvol = 5 | collvolpages = 562 | prep = cv5p0562}} For this purpose, the KSCN is first melted under vacuum to remove water. In a related reaction, KSCN converts cyclohexene oxide to the corresponding episulfide and KOCN.
:{{chem2 | C6H10O + KSCN -> C6H10S + KOCN }}
KSCN is also the starting product for the synthesis of carbonyl sulfide.
=Special effects=
Dilute aqueous KSCN is occasionally used for moderately realistic blood effects in film and theatre. It can be painted onto a surface or kept as a colorless solution. When in contact with ferric chloride solution (or other solutions containing Fe3+), the product of the reaction is a solution with a blood red colour, due to the formation of the thiocyanatoiron complex ion. Thus this chemical is often used to create the effect of 'stigmata'. Because both solutions are colorless, they can be placed separately on each hand. When the hands are brought into contact, the solutions react and the effect looks remarkably like stigmata.{{citation needed| date=February 2009}}
=Laboratory=
The reaction with Fe3+ mentioned above is used as a test for Fe3+ ions in the laboratory.
=Law enforcement=
Approximate cocaine purity can be determined using 1 mL 2% cupric sulphate pentahydrate in dilute HCl, 1 mL 2% potassium thiocyanate and 2 mL of chloroform. The shade of brown shown by the chloroform is proportional to the cocaine content. This test is not cross sensitive to heroin, methamphetamine, benzocaine, procaine and a number of other drugs but other chemicals could cause false positives.{{Cite journal | vauthors = Travnikoff B |title=Semiquantitative screening test for cocaine |date=1 April 1983 |journal=Analytical Chemistry |issue=4 |volume=55 |pages=795–796 |doi=10.1021/ac00255a048 |issn=0003-2700}}
References
{{Reflist}}
{{Potassium compounds}}
{{Thiocyanates}}
{{Use dmy dates|date=February 2024}}
{{DEFAULTSORT:Potassium Thiocyanate}}