:Protactinium(V) chloride
{{chembox
| ImageFile = PaCl5.svg
| ImageSize = 300px
| IUPACName = Protactinium(V) chloride
| OtherNames = Protactinium pentachloride, Protactinium chloride
|Section1={{Chembox Identifiers
| Abbreviations =
| CASNo = 13760-41-3
| EINECS =
| PubChem = 11047828
| ChemSpiderID = 9222996
| StdInChI=1S/5ClH.Pa/h5*1H;/q;;;;;+5/p-5
| StdInChIKey = QRPCDPJECLHYKR-UHFFFAOYSA-I
| SMILES = Cl[Pa](Cl)(Cl)(Cl)Cl
}}
|Section2={{Chembox Properties
| Formula = PaCl5
| MolarMass = 408.301 g/mol
| Appearance = yellow monoclinic crystals
| MeltingPtC = 306
{{Cite book
| last = Lide
| first = David R.
| year = 1998
| title = Handbook of Chemistry and Physics
| edition = 87
| location = Boca Raton, FL
| publisher = CRC Press
| isbn = 0849305942
| pages = 484
| url = https://books.google.com/books?id=lFjg0L-uOxoC&q=%22Protactinium(V)+chloride%22&pg=PT869
| access-date = 2008-07-17
}}
| BoilingPtC = 420
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|Section3={{Chembox Structure
| CrystalStruct = monoclinic, mS24
| SpaceGroup = c12/c1, #15
| Coordination = Pa, 7, pentagonal bipyramidal
Cl, 1 and 2
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|Section4={{Chembox Thermochemistry
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|Section7={{Chembox Hazards
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|Section8={{Chembox Related
| OtherAnions = Protactinium(V) fluoride
Protactinium(V) bromide
Protactinium(V) iodide
| OtherCations = Praseodymium(III) chloride
Uranium(IV) chloride
Thorium(IV) chloride
| OtherCompounds = Protactinium(IV) chloride
}}
}}
Protactinium(V) chloride is the chemical compound composed of protactinium and chlorine with the formula PaCl5. It forms yellow monoclinic crystals and has a unique structure composed of chains of 7 coordinate, pentagonal bipyramidal, protactinium atoms sharing edges.R. P. Dodge, G. S. Smith, Q. Johnson, R. E. Elson: „The Crystal Structure of Protactinium Pentachloride“, Acta Crystallogr., 1967, 22, 85–89; {{doi|10.1107/S0365110X67000155}}.
Protactinium(V) chloride can react with boron tribromide at high temperatures to form protactinium(V) bromide.Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6, S. 1177. It also reacts with fluorine to form protactinium(V) fluoride at high temperatures.
See also
References
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{{protactinium compounds}}
{{Chlorides}}
{{Actinide halides}}
Category:Protactinium(V) compounds
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