:Radium carbonate
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| Name = Radium carbonate
| IUPACName = Radium carbonate
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| ImageFileL1 = Radium-ion-3D-vdW.png
| ImageFileR1 = Carbonate-3D-vdW.png
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| CASNo = 7116-98-5
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| SMILES = [Ra+2].[O-]C([O-])=O
| StdInChI = 1S/CH2O3.Ra/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
| StdInChIKey = YPWICUOZSQYGTD-UHFFFAOYSA-L
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| Section2 = {{Chembox Properties
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| Solubility = 0.05 g/L (25 °C)
| SolubilityProduct = {{10^|−7.5{{+-}}0.1}} (25 °C)
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| Section8 = {{Chembox Related
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| OtherCations = {{ubl|Beryllium carbonate|Magnesium carbonate|Calcium carbonate|Strontium carbonate|Barium carbonate|Lead(II) carbonate|Zinc carbonate|Cadmium carbonate}}
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Radium carbonate is a chemical compound of radium, carbon, and oxygen, having the chemical formula {{chem2|RaCO3|auto=1}}. It is the radium salt of carbonic acid. It contains radium cations ({{chem2|Ra(2+)}}) and carbonate anions ({{chem2|CO3(2−)}}). This salt is a highly radioactive, amorphous,{{Cite journal |date=July 21, 2023 |title=Disordered Crystal Structure and Anomalously High Solubility of Radium Carbonate |journal=Inorganic Chemistry |doi=10.1021/acs.inorgchem.3c01513 |pmid=37477287 |last1=Matyskin |first1=Artem V. |last2=Ebin |first2=Burçak |last3=Allard |first3=Stefan |last4=Torapava |first4=Natallia |last5=Eriksson |first5=Lars |last6=Persson |first6=Ingmar |last7=Brown |first7=Paul L. |last8=Ekberg |first8=Christian |volume=62 |issue=30 |pages=12038–12049 |pmc=10394661}} white powder that has potential applications in medicine.{{Cite journal |date=17 January 2018 |title=Ra-224 labeling of calcium carbonate microparticles for internal α-therapy: Preparation, stability, and biodistribution in mice |journal=Journal of Labelled Compounds and Radiopharmaceuticals |volume=61 |pages=472–486|doi=10.1002/jlcr.3610 |last1=Westrøm |first1=Sara |last2=Malenge |first2=Marion |last3=Jorstad |first3=Ida Sofie |last4=Napoli |first4=Elisa |last5=Bruland |first5=Øyvind S. |last6=Bønsdorff |first6=Tina B. |last7=Larsen |first7=Roy H. |issue=6 |pmid=29380410 |pmc=6001669 |s2cid=3884756}} It is notable for forming disordered crystals at room temperature and for being approximately 10 times more soluble than its lighter congener barium carbonate. Radium carbonate is one of a few radium compounds which has significantly different properties from corresponding barium compounds. Moreover, radium is the only alkaline-earth metal which forms disordered crystals in its carbonate phase. Even though radium carbonate has very low solubility in water, it is soluble in dilute mineral acids and concentrated ammonium carbonate.{{cite journal |url=https://www.osti.gov/servlets/purl/4560824/|title=The Radiochemistry of Radium|date= 1964|website=Office of Scientific and Technical Information |publisher= |doi=10.2172/4560824 |access-date=2021-01-08|quote= |last1=Salutsky |first1=M. |last2=Kirby |first2=H.|osti=4560824 }}
Preparation
Radium carbonate can be produced by dissolving radium sulfate at elevated temperatures in concentrated sodium carbonate and subsequent removal of supernatant:{{Cite journal |date=5 July 2016 |title=Disassembly of old radium sources and conversion of radium sulfate into radium carbonate for subsequent dissolution in acid |url=https://link.springer.com/article/10.1007/s10967-016-4927-x |journal=Journal of Radioanalytical and Nuclear Chemistry |volume=310 |pages=589–595|doi=10.1007/s10967-016-4927-x |last1=Matyskin |first1=Artem V. |last2=Ebin |first2=Burçak |last3=Tyumentsev |first3=Mikhail |last4=Allard |first4=Stefan |last5=Skarnemark |first5=Gunnar |last6=Ramebäck |first6=Henrik |last7=Ekberg |first7=Christian |issue=2 |s2cid=100321021|url-access=subscription }}
:{{chem2 | RaSO4(s) -> Ra(2+) + SO4(2-) }}
:{{chem2 | Ra(2+) + CO3(2-) -> RaCO3(s) }}
Because of the very low solubility of {{chem2|RaCO3}}, it will form a white precipitate.
Reactions
Radium carbonate can be used to produce radium nitrate and other radium salts:
:{{chem2 | RaCO3 + 2 HNO3 -> Ra(NO3)2 + H2O + CO2 }}