:Strontium oxide
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 432924813
| Name =
{{Cite book
| last = Lide
| first = David R.
| year = 1998
| title = Handbook of Chemistry and Physics
| edition = 87
| location = Boca Raton, Florida
| publisher = CRC Press
| isbn = 0-8493-0594-2
| pages = 4–87}}
| ImageFile = SrOpowder.jpg
| ImageFile2 = Strontium-oxide-unit-cell-3D-SF.png
| ImageName = __ Sr2+ __ O2−
| IUPACName = Strontium oxide
| OtherNames = Strontia
| SystematicName =
| Section1 = {{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 1314-11-0
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 64RA22280P
| PubChem = 73975
| EINECS = 215-219-9
| InChI = 1S/O.Sr/q-2;+2
| SMILES = [O-2].[Sr+2]
}}
| Section2 = {{Chembox Properties
| Formula = SrO
| MolarMass = 103.619 g/mol
| Appearance = colorless cubic crystals
| Density = 4.70 g/cm3
| Solubility = reacts, forms Sr(OH)2
| SolubleOther = miscible with potassium hydroxide
slightly soluble in alcohol
insoluble in acetone and ether
| MeltingPtC = 2531
| BoilingPtC = 3200
| BoilingPt_notes = (decomposes)
| RefractIndex = 1.810 Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, {{ISBN|0-07-049439-8}}
| MagSus = −35.0·10−6 cm3/mol
}}
| Section3 = {{Chembox Structure
| CrystalStruct = Halite (cubic), cF8
| SpaceGroup = Fm{{overline|3}}m, No. 225
| Coordination = Octahedral (Sr2+); octahedral (O2−)
| LattConst_a =
}}
| Section4 = {{Chembox Thermochemistry
| DeltaHf = −592.0 kJ·mol−1
| DeltaHc =
| Entropy = 57.2 J·mol−1·K−1
| HeatCapacity = 44.3 J·mol−1·K−1
}}
| Section5 =
| Section6 =
| Section7 = {{Chembox Hazards
| ExternalSDS =
| HPhrases =
| PPhrases =
| GHS_ref =
| MainHazards =
| NFPA-H =
| NFPA-F =
| NFPA-R =
| NFPA-S =
| FlashPt = Non-flammable
| LD50 =
| PEL =
}}
| Section8 = {{Chembox Related
| OtherAnions = Strontium sulfide
| OtherCations = Beryllium oxide
Magnesium oxide
Calcium oxide
Barium oxide
| OtherFunction =
| OtherFunction_label =
| OtherCompounds = Strontium hydroxide
}}
}}
Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a strongly basic oxide.
Uses
About 8% by weight of cathode-ray tubes is strontium oxide, which has been the major use of strontium since 1970.{{cite web|url = http://minerals.usgs.gov/minerals/pubs/commodity/strontium/myb1-2007-stron.pdf|title = Mineral Yearbook 2007:Strontium|first1 = Joyce A.|last1 = Ober|first2 = Désirée E.|last2 = Polyak|publisher = United States Geological Survey|access-date = 2009-09-14}}{{Cite book|url=https://books.google.com/books?id=G6c7AQAAMAAJ&dq=faceplate+glass+production+%2C+strontium%27s+major+end+use+since+the+early+1970s&pg=RA6-SA74-PA1|title=Minerals Yearbook|date=May 8, 2011|publisher=Bureau of Mines|isbn=9781411332270|via=Google Books}} Color televisions and other devices containing color cathode-ray tubes sold in the United States are required by law to use strontium in the faceplate to block X-ray emission (these X-ray emitting TVs are no longer in production). Lead(II) oxide can be used in the neck and funnel, but causes discoloration when used in the faceplate.{{cite journal|doi = 10.1016/j.wasman.2005.11.017|pmid = 16427267|year = 2006|last1 = Méar|first1 = F|last2 = Yot|first2 = P|last3 = Cambon|first3 = M|last4 = Ribes|first4 = M|title = The characterization of waste cathode-ray tube glass.|volume = 26|issue = 12|pages = 1468–76|issn = 0956-053X|journal = Waste Management| bibcode=2006WaMan..26.1468M }}
Reactions
Elemental strontium is formed when strontium oxide is heated with aluminium in a vacuum.
References
{{reflist}}
External links
- [https://web.archive.org/web/20060909182921/http://ceramic-materials.com/cermat/oxide/sro.html Hansen, Tony, "SrO (Strontium Oxide, Strontia)", ceramic-materials.com]
{{Strontium compounds}}
{{Oxides}}
{{Authority control}}