:Titanium carbide
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{{Expand language|topic=|langcode=uk|otherarticle=Карбід титану|date=December 2024}}
{{chembox
| Verifiedfields = changed
| verifiedrevid = 441066916
| ImageFile = TiC-xtal-3D-vdW.png
| ImageSize =
| IUPACName = titanium carbide
| OtherNames = titanium(IV) carbide
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 12070-08-5
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 7SHTGW5HBI
| PubChem = 4226345
| SMILES = [Ti+]#[C-]
| StdInChI = 1S/C.Ti/q-1;+1
}}
|Section2={{Chembox Properties
| Formula = TiC
| Ti=1|C=1
| Appearance = black crystalline powder
| Density = 4.93 g/cm3
| MeltingPtC = 3160
| BoilingPtC = 4820
| Solubility = insoluble in water
| MagSus = +8.0·10−6 cm3/mol
}}
|Section3={{Chembox Structure
| SpaceGroup = Fm3m, No. 225
| Coordination = Octahedral
}}
|Section7={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
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| Section9 = {{Chembox Related
| OtherCompounds = {{ubl|Zirconium carbide|Hafnium carbide|Beryllium carbide|Vanadium carbide|Tungsten carbide|Molybdenum carbide|Diamond|Silicon carbide|Titanium nitride}}
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Titanium carbide, TiC, is an extremely hard (Mohs 9–9.5) refractory ceramic material, similar to tungsten carbide. It has the appearance of black powder with the sodium chloride (face-centered cubic) crystal structure.
It occurs in nature as a form of the very rare mineral {{ill|khamrabaevite|uz|Hamroboyevit}} ({{Langx|ru|Хамрабаевит}}) - (Ti,V,Fe)C. It was discovered in 1984 on Mount Arashan in the Chatkal District,{{Cite journal |last=Dunn |first=Pete J |date=1985 |title=New mineral names |url=https://pubs.geoscienceworld.org/msa/ammin/article-abstract/70/3-4/436/41735/New-Mineral-Names |journal=American Mineralogist |volume=70 |pages=1329–1335}} USSR (modern Kyrgyzstan), near the Uzbek border. The mineral was named after Ibragim Khamrabaevich Khamrabaev, director of Geology and Geophysics of Tashkent, Uzbekistan. Its crystals as found in nature range in size from 0.1 to 0.3 mm.
Physical properties
Titanium carbide has an elastic modulus of approximately 400 GPa and a shear modulus of 188 GPa.{{cite journal |url=http://scitation.aip.org/content/aip/journal/jap/37/10/10.1063/1.1707923 |title=Low-Temperature Elastic Properties of ZrC and TiC |last1=Chang |first1=R |last2=Graham |first2=L |date=1966 |journal=Journal of Applied Physics |volume=37|issue=10 |pages=3778–3783 |doi=10.1063/1.1707923|bibcode=1966JAP....37.3778C|url-access=subscription }}
Titanium carbide is soluble in solid titanium oxide, with a range of compositions which are collectively named "titanium oxycarbide" and created by carbothermic reduction of the oxide.{{Cite thesis |title=Production of Titanium Metal by an Electrochemical Molten Salt Process |url=https://kilthub.cmu.edu/articles/thesis/Production_of_Titanium_Metal_by_an_Electrochemical_Molten_Salt_Process/6721160/1?file=12255587 |publisher=Carnegie Mellon University |date=2017-05-01 |degree=thesis |language=en |first=Farzin |last=Fatollahi-Fard}}
Manufacturing and machining
Tool bits without tungsten content can be made of titanium carbide in nickel-cobalt matrix cermet, enhancing the cutting speed, precision, and smoothness of the workpiece.{{citation needed|date=September 2014}}
The resistance to wear, corrosion, and oxidation of a tungsten carbide–cobalt material can be increased by adding 6–30% of titanium carbide to tungsten carbide. This forms a solid solution that is more brittle and susceptible to breakage.{{clarify|reason=why would that be an advantage?|date=July 2015}}
Titanium carbide can be etched with reactive-ion etching.
Applications
Titanium carbide is used in preparation of cermets, which are frequently used to machine steel materials at high cutting speed. It is also used as an abrasion-resistant surface coating on metal parts, such as tool bits and watch mechanisms.{{cite journal|doi=10.1016/j.surfcoat.2018.11.060|title=Decorative black coatings on titanium surfaces based on hard bi-layered carbon coatings synthesized by carbon implantation|journal=Surface and Coatings Technology|volume=358|pages=386–393|year=2019|last1=Gupta|first1=P.|last2=Fang|first2=F.|last3=Rubanov|first3=S.|last4=Loho|first4=T.|last5=Koo|first5=A.|last6=Swift|first6=N.|last7=Fiedler|first7=H.|last8=Leveneur|first8=J.|last9=Murmu|first9=P.P.|last10=Markwitz|first10=A.|last11=Kennedy|first11=J.|s2cid=139179067|hdl=2292/46133|hdl-access=free}} Titanium carbide is also used as a heat shield coating for atmospheric reentry of spacecraft.{{cite book|url=https://books.google.com/books?id=ntWcBAAAQBAJ&q=titanium+carbide&pg=PA406|title=Manned Spacecraft Design Principles|last1=Sforza|first1=Pasquale M.|date=13 November 2015|publisher=Elsevier|page=406|language=en|access-date=4 January 2017|isbn=9780124199767}}
7075 aluminium alloy (AA7075) is almost as strong as steel, but weighs one third as much. Using thin AA7075 rods with TiC nanoparticles allows larger alloys pieces to be welded without phase-segregation induced cracks.{{Cite web|url=https://newatlas.com/welding-aa7075-aluminum-alloy/58449/|title=New welding process opens up uses for formerly un-weldable lightweight alloy|website=newatlas.com|date=13 February 2019|language=en|access-date=2019-02-18}}
See also
- Metallocarbohedryne, a family of metal-carbon clusters including {{chem2|Ti8C12}}