:Triphosphane
{{See also|Triphos (disambiguation){{!}}triphos}}
{{Use dmy dates|date=June 2023}}
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 443287364
| ImageFileL1 = Triphosphine.svg
| ImageFileL1_Ref = {{chemboximage|correct|??}}
| ImageSizeL1 =
| ImageNameL1 = Structural formula of triphosphane
| ImageFileR1 = Triphosphane-3D-balls.png
| ImageSizeR1 =
| ImageNameR1 = Ball-and-stick model
| OtherNames = Triphosphine{{Cite web|title = Triphosphine|url = http://webbook.nist.gov/cgi/cbook.cgi?ID=13597-70-1|work = NIST Chemistry WebBook|publisher = National Institute of Standards and Technology|accessdate = 27 September 2011|location = USA}}
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 13597-70-1
| PubChem = 139510
| ChemSpiderID = 123032
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChEBI = 35893
| ChEBI_Ref = {{ebicite|changed|EBI}}
| SMILES = PPP
| StdInChI = 1S/H5P3/c1-3-2/h3H,1-2H2
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = ITHPEWAHFNDNIO-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
}}
|Section2={{Chembox Properties
| Formula = {{chem2|P3H5}}
| MolarMass = 97.96099 g·mol−1
| Appearance = Colourless gas
}}
|Section9={{Chembox Related
| OtherAnions = triazane
| OtherCations =
| OtherFunction_label = Binary phosphanes
| OtherFunction = phosphane
diphosphane
| OtherCompounds = triazene
}}
}}
Triphosphane (IUPAC systematic name) or triphosphine is an inorganic compound having the chemical formula {{chem2|HP(PH2)2}}. It can be generated from diphosphine but is highly unstable at room temperature:{{Greenwood&Earnshaw2nd}}
:{{chem2|2 P2H4 → P3H5 + PH3}}
Samples have been isolated by gas chromatography. The compound rapidly converts to {{chem2|PH3}} and the cyclophosphine cyclo-{{chem2|P5H5}}.{{cite journal | author = Marianne Baudler, Klaus Glinka | title = Monocyclic and Polycyclic Phosphines | journal = Chem. Rev. | year = 1993 | volume = 93 | pages = 1623–1667 | doi = 10.1021/cr00020a010}}
References
{{Reflist}}
External links
- [http://goldbook.iupac.org/P04548.html IUPAC]
- [http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:35893 CHEBI]
{{Hydrides by group}}