:Zirconyl chloride
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 417178510
| Name = Zirconyl chloride
| IUPACName = Dichloro(oxo)zirconium
| OtherNames = {{Unbulleted list
| basic zirconium chloride
| dichlorooxozirconium
| zirconium oxychloride
| zirconium dichloride oxide
| Zirconium chloride oxide
| Chlorozirconyl
}}
| ImageFile = ZrOCl2_(octahydrate).jpg
|Section1={{Chembox Identifiers
| index1_label = anhydrous
| index2_label = octahydrate
| CASNo1_Ref = {{cascite|correct|CAS}}
| CASNo1 = 7699-43-6
| CASNo2_Ref = {{cascite|correct|CAS}}
| CASNo2 = 13520-92-8
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII2_Ref = {{fdacite|correct|FDA}}
| UNII2 = 2R4A27N98K
| UNII1_Ref = {{fdacite|correct|FDA}}
| UNII1 = T4294601O7
| PubChem = 159678
| ChemSpiderID = 10606302
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| EINECS = 603-909-6
| SMILES = O=[Zr](Cl)Cl
| StdInChI = 1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;
| StdInChI_Ref =
| StdInChIKey = FUBACIUATZGHAC-UHFFFAOYSA-N
| StdInChIKey_Ref =
}}
|Section2={{Chembox Properties
| Cl=2 | O=1 | Zr=1
| Appearance = White crystals
| MeltingPtC =
}}
|Section3={{Chembox Hazards
| LD50 = 400 mg kg−1, rat (intraperitioneal)
}}
}}
Zirconyl chloride is the inorganic compound with the formula of [Zr4(OH)8(H2O)16]Cl8(H2O)12, more commonly written ZrOCl2·8H2O, and referred to as zirconyl chloride octahydrate. It is a white solid and is the most common water-soluble derivative of zirconium. A compound with the formula ZrOCl2 has not been characterized.
Production and structure
File:Zr8O8core(KAVRUX).png and zirconyl chloride.]]
The salt is produced by hydrolysis of zirconium tetrachloride or treating zirconium oxide with hydrochloric acid.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. {{doi|10.1002/14356007.a28_543}} It adopts a tetrameric structure, consisting of the cation [Zr4(OH)8]8+. features four pairs of hydroxide bridging ligands linking four Zr4+ centers. The chloride anions are not ligands, consistent with the high oxophilicity of Zr(IV).{{Greenwood&Earnshaw2nd}} The salt crystallizes as tetragonal crystals.T. W. Mak "Refinement of the crystal structure of zirconyl chloride octahydrate" Canadian Journal of Chemistry, 46, 3491 (1968) {{doi|10.1139/v68-579}}
See also
References
{{Reflist}}
External links
- [http://ptcl.chem.ox.ac.uk/MSDS/ZI/zirconium_oxychloride.html MSDS Data]
- [https://www.sigmaaldrich.com/MSDS/MSDS/DisplayMSDSPage.do?country=NL&language=nl&productNumber=224316&brand=SIGALD&PageToGoToURL=https%3A%2F%2Fwww.sigmaaldrich.com%2Fcatalog%2Fsearch%3Fterm%3DZirconyl%2Bchloride%2Boctahydrate%26interface%3DProduct%2520Name%26N%3D0%2B%26mode%3Dmode%2520matchpartialmax%26lang%3Den%26region%3DNL%26focus%3DproductN%3D0%2520220003048%2520219853286%2520219853205 MSDS data Sigma-Aldrich]
{{Zirconium compounds}}