:Zirconyl chloride

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| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 417178510

| Name = Zirconyl chloride

| IUPACName = Dichloro(oxo)zirconium

| OtherNames = {{Unbulleted list

| basic zirconium chloride

| dichlorooxozirconium

| zirconium oxychloride

| zirconium dichloride oxide

| Zirconium chloride oxide

| Chlorozirconyl

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| ImageFile = ZrOCl2_(octahydrate).jpg

|Section1={{Chembox Identifiers

| index1_label = anhydrous

| index2_label = octahydrate

| CASNo1_Ref = {{cascite|correct|CAS}}

| CASNo1 = 7699-43-6

| CASNo2_Ref = {{cascite|correct|CAS}}

| CASNo2 = 13520-92-8

| CASNo_Ref = {{cascite|correct|CAS}}

| UNII2_Ref = {{fdacite|correct|FDA}}

| UNII2 = 2R4A27N98K

| UNII1_Ref = {{fdacite|correct|FDA}}

| UNII1 = T4294601O7

| PubChem = 159678

| ChemSpiderID = 10606302

| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}

| EINECS = 603-909-6

| SMILES = O=[Zr](Cl)Cl

| StdInChI = 1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;

| StdInChI_Ref =

| StdInChIKey = FUBACIUATZGHAC-UHFFFAOYSA-N

| StdInChIKey_Ref =

}}

|Section2={{Chembox Properties

| Cl=2 | O=1 | Zr=1

| Appearance = White crystals

| MeltingPtC =

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|Section3={{Chembox Hazards

| LD50 = 400 mg kg−1, rat (intraperitioneal)

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Zirconyl chloride is the inorganic compound with the formula of [Zr4(OH)8(H2O)16]Cl8(H2O)12, more commonly written ZrOCl2·8H2O, and referred to as zirconyl chloride octahydrate. It is a white solid and is the most common water-soluble derivative of zirconium. A compound with the formula ZrOCl2 has not been characterized.

Production and structure

File:Zr8O8core(KAVRUX).png and zirconyl chloride.]]

The salt is produced by hydrolysis of zirconium tetrachloride or treating zirconium oxide with hydrochloric acid.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. {{doi|10.1002/14356007.a28_543}} It adopts a tetrameric structure, consisting of the cation [Zr4(OH)8]8+. features four pairs of hydroxide bridging ligands linking four Zr4+ centers. The chloride anions are not ligands, consistent with the high oxophilicity of Zr(IV).{{Greenwood&Earnshaw2nd}} The salt crystallizes as tetragonal crystals.T. W. Mak "Refinement of the crystal structure of zirconyl chloride octahydrate" Canadian Journal of Chemistry, 46, 3491 (1968) {{doi|10.1139/v68-579}}

See also

References

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