1,2-Dibromobenzene
{{Chembox
| ImageFile = 1,2-dibromobenzene_200.svg
| ImageSize = 144px
| ImageAlt =
| PIN = 1,2-Dibromobenzene
| OtherNames = o-Dibromobenzene
|Section1={{Chembox Identifiers
| CASNo = 583-53-9
| PubChem = 11414
| ChEBI = 37152
| ChEMBL = 1797135
| EC_number = 209-507-3
| ChemSpiderID = 13875212
| Gmelin = 130950
| Beilstein = 970241
| UNNumber = 2711
| UNII = 52K9W7U6EH
| DTXSID = DTXSID0022064
| StdInChI=1S/C6H4Br2/c7-5-3-1-2-4-6(5)8/h1-4H
| StdInChIKey = WQONPSCCEXUXTQ-UHFFFAOYSA-N
| SMILES = C1=CC=C(C(=C1)Br)Br
}}
|Section2={{Chembox Properties
| C=6|H=4|Br=2
| MolarMass =
| Appearance = colorless liquid
| Density = 1.9940 g/cm3
| MeltingPtC = 7.1
| BoilingPtC = 225
| Solubility = }}
|Section3={{Chembox Hazards
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|315|319|335}}
| PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|501}}
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
| Section4 = {{Chembox Related
| OtherCompounds = {{ubl|1,3-Dibromobenzene|1,4-Dibromobenzene|1,2-Dichlorobenzene}}
}}
}}
1,2-Dibromobenzene (o-dibromobenzene) is an aryl bromide and isomer of dibromobenzene. It is one of three isomers, the others being 1,3- and 1,4-dibromobenzene. It is a colorless liquid, although impure samples appear yellowish. The compound is a precursor to many 1,2-disubstituted derivatives of benzene. For example, it is a precursor to 1,2-dicyanobenzene{{Ullmann|author=Löbbert, Gerd|title=Phthalocyanines|year=2000|doi=10.1002/14356007.a20_213}} and dithioethers.{{cite journal |doi=10.15227/orgsyn.042.0022|title=1,2-bis(n-Butylthio)benzene|journal=Organic Syntheses|year=1962|volume=42|page=22|first1=Roger|last1= Adams|first2=Walter| last2=Reifschneider|first3=Aldo|last3=Ferretti
}}