1,2-Dimethylcyclopropane
{{Expand Greek|topic=sci|date=March 2010}}
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477203928
| ImageFile=CC1CC1C.svg
| ImageFile1=Dimethylcyclopropane.png
| ImageCaption1 = cis (left) and (S,S)-trans (right) isomers
| PIN=1,2-Dimethylcyclopropane
| OtherNames=
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 92890
| InChI = 1/C5H10/c1-4-3-5(4)2/h4-5H,3H2,1-2H3
| InChIKey = VKJLDXGFBJBTRQ-UHFFFAOYAK
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C5H10/c1-4-3-5(4)2/h4-5H,3H2,1-2H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VKJLDXGFBJBTRQ-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo=2511-95-7
| PubChem=102832
| SMILES=CC1CC1C
| RTECS=
}}
|Section2={{Chembox Properties
| C=5 | H=10
| Appearance=
| Density= cis: 0.6889 g/cm3
trans: 0.6648 g/cm3
| MeltingPt= cis: -140 °C
trans: -149.6 °C
| BoilingPt= cis: 37 °C
trans: 28.2 °C
| RefractIndex= cis: 1.3829 (20 °C)
trans: 1.3713 (20 °C)
| Solubility=
| pKa =
| pKb =
}}
|Section3={{Chembox Hazards
| MainHazards=
| FlashPt=
| AutoignitionPt =
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|Section8={{Chembox Related
| OtherCompounds = cyclopropane, cyclopentane
}}
}}
1,2-Dimethylcyclopropane is a cycloalkane consisting of a cyclopropane ring substituted with two methyl groups attached to adjacent carbon atoms.{{Cite web |last=PubChem |title=1,2-Dimethylcyclopropane |url=https://pubchem.ncbi.nlm.nih.gov/compound/102832 |access-date=2022-11-15 |website=pubchem.ncbi.nlm.nih.gov |language=en}} It has three stereoisomers, one cis-isomer and a pair of trans-enantiomers, which differ depending on the orientation of the two methyl groups. As with other cyclopropanes, ring tension results in a relatively unstable compound.
1,2-Dimethylcyclopropane is 1 of 10 structural isomers (cycloalkanes and aliphatic alkenes) which share the general formula of C5H10, the others being cyclopentane, methylcyclobutane, 1,1-dimethylcyclopropane, ethylcyclopropane, 1-pentene, 2-pentene, 2-methyl-1-butene, 3-methyl-1-butene, and 2-methyl-2-butene.
See also
References
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{{DEFAULTSORT:Dimethylcyclopropane, 1, 2-}}