1,8-Naphthyridine

{{Chembox

| ImageFile = 1,8-naphthyridine.svg

| ImageSize = 144

| ImageAlt =

| PIN = 1,8-Naphthyridine{{cite book |author=International Union of Pure and Applied Chemistry |date=2014 |title=Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013 |publisher=The Royal Society of Chemistry |pages=212 |doi=10.1039/9781849733069 |isbn=978-0-85404-182-4}}

| OtherNames =

|Section1={{Chembox Identifiers

| CASNo = 254-60-4

| PubChem = 136069

| UNII = 043R04VL4M

| ChEBI = 36628

| ChEMBL = 261758

| Gmelin = 27124

| EINECS = 675-799-8

| ChemSpiderID = 119846

| DTXSID = DTXSID40180052

| Beilstein = 109347

| StdInChI=1S/C8H6N2/c1-3-7-4-2-6-10-8(7)9-5-1/h1-6H

| StdInChIKey = FLBAYUMRQUHISI-UHFFFAOYSA-N

| SMILES = C1=CC2=C(N=C1)N=CC=C2

}}

|Section2={{Chembox Properties

| C=8|H=6|N=2

| MolarMass =

| Appearance = yellow solid

| Density = 1.359 g/cm3

| MeltingPtC = 98-99

| BoilingPtC =

| Solubility = }}

|Section3={{Chembox Hazards

| GHSPictograms = {{GHS07}}

| GHSSignalWord = Warning

| HPhrases = {{H-phrases|315|319|335}}

| PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|501}}

| MainHazards =

| FlashPt =

| AutoignitionPt = }}

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1,8-Naphthyridine is an organic compound with the formula C8H6N2. It is the most well-studied of the six isomeric naphthyridines, a subset of diazanaphthalenes with nitrogen in the separate rings.{{cite journal|doi=10.1070/RC2000v069n03ABEH000553|bibcode=2000RuCRv..69..201L|title=Naphthyridines. Structure, Physicochemical Properties and General Methods of Synthesis|year=2000|last1=Litvinov|first1=Victor P.|last2=Roman|first2=Sergey V.|last3=Dyachenko|first3=Vladimir D.|journal=Russian Chemical Reviews|volume=69|issue=3|pages=201–220|s2cid=250827396 }}{{cite journal|doi = 10.1107/S0108270184006144|title = Low-Temperature (163 K) Structure of 1,8-Naphthyridine, C8H6N2|year = 1984|last1 = Dapporto|first1 = P.|last2 = Ghilardi|first2 = C. A.|last3 = Mealli|first3 = C.|last4 = Orlandini|first4 = A.|last5 = Pacinotti|first5 = S.|journal = Acta Crystallographica Section C Crystal Structure Communications|volume = 40|issue = 5|pages = 891–894| bibcode=1984AcCrC..40..891D }} Enoxacin, nalidixic acid, and trovafloxacin are 1,8-naphthyridine derivatives with antibacterial properties related to the fluoroquinolones.{{cite book|series=Advances in Heterocyclic Chemistry

|title=Advances in the Chemistry of Naphthyridines|author=V. P. Litvinov|year=2006|pages=189–300|volume=91|doi=10.1016/S0065-2725(06)91004-6|isbn=9780120207916}}

Coordination chemistry

With flanking nitrogen centers, 1,8-naphthyridine serves as a binucleating ligand in coordination chemistry.{{cite journal|doi=10.1039/b923125k|pmid=20372713|title=Probing the electronic communication of linear heptanickel and nonanickel string complexes by utilizing two redox-active [Ni2(napy)4]3+ moieties|year=2010|last1=Hua|first1=Shao-An|last2=Liu|first2=Isiah Po-Chun|last3=Hasanov|first3=Hasan|last4=Huang|first4=Gin-Chen|last5=Ismayilov|first5=Rayyat Huseyn|last6=Chiu|first6=Chien-Lan|last7=Yeh|first7=Chen-Yu|last8=Lee|first8=Gene-Hsiang|last9=Peng|first9=Shie-Ming|journal=Dalton Transactions|volume=39|issue=16|pages=3890–6}}{{cite journal|doi = 10.1002/ejic.200900312|title = 1,8-Naphthyridine Revisited: Applications in Dimetal Chemistry|year = 2009|last1 = Bera|first1 = Jitendra K.|last2 = Sadhukhan|first2 = Nabanita|last3 = Majumdar|first3 = Moumita|journal = European Journal of Inorganic Chemistry|volume = 2009|issue = 27|pages = 4023–4038}}

References

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Category:Naphthyridines