2-Methylfuran
{{chembox
| Watchedfields = changed
| verifiedrevid = 477214477
| ImageFile = 2-Methylfuran.svg
| ImageSize = 150
| ImageName = Skeletal formula
| ImageFile1 = 2-Methylfuran-3D-balls.png
| ImageSize1 = 180
| ImageName1 = Ball-and-stick model
| PIN = 2-Methylfuran
| OtherNames =
| Section1 = {{Chembox Identifiers
| InChI = 1/C5H6O/c1-5-3-2-4-6-5/h2-4H,1H3
| InChIKey = VQKFNUFAXTZWDK-UHFFFAOYAB
| SMILES1 = Cc1ccco1
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C5H6O/c1-5-3-2-4-6-5/h2-4H,1H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VQKFNUFAXTZWDK-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 534-22-5
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 51O3BGW3F2
| PubChem = 10797
| ChEBI = 88912
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 10340
| SMILES = o1c(ccc1)C
| EINECS = 208-594-5
}}
| Section2 = {{Chembox Properties
| Formula = C5H6O
| MolarMass = 82.10 g/mol
| Appearance = Colorless to pale yellow/green liquid
| MeltingPt =
| BoilingPtC = 64 NIST Chemistry WebBook. http://webbook.nist.gov
| RefractIndex = 1.4332 (20 °C)
| Solubility = 3000 mg/L (20 °C)
| SolubleOther = Soluble
| Solvent = ethanol
}}
| Section3 = {{Chembox Hazards
| MainHazards = Very flammable, harmful
| FlashPtF = -8
| AutoignitionPtC =
| NFPA-F = 3 | NFPA-H = 2 | NFPA-R = 1
}}
}}
2-Methylfuran, also known with the older name of sylvane, is a flammable, water-insoluble liquid
{{cite web
|url=http://environmentalchemistry.com/yogi/chemicals/cn/2-Methylfuran.html
|title=Chemical Database - 2-Methylfuran. EnvironmentalChemistry.com. 1995 - 2008. Accessed on-line: 8/26/2008
|author=Kenneth Barbalace
|accessdate=2008-08-26
}} with a chocolate odor, found naturally in Myrtle and Dutch Lavender{{cite web|url=https://phytochem.nal.usda.gov/phytochem/search/list|title=Dr. Duke's Phytochemical and Ethnobotanical Databases. [Online Database] 26 August 2008. 2-METHYL-FURAN|author=Jim Duke|date=|website=|url-status=live|archive-url=https://web.archive.org/web/20161118042257/https://phytochem.nal.usda.gov/phytochem/search/list |archive-date=2016-11-18 |accessdate=2008-08-26}}
used as a FEMA GRAS flavoring substance,
{{cite web
|url=http://www.thegoodscentscompany.com/data/rw1023171.html
|title=2-methyl furan
|publisher=The Good Scents Company.
|accessdate=2008-08-26}} with the potential for use in alternative fuels.
Manufacture
2-Methylfuran is an article of commerce (chemical intermediate) and is normally manufactured by catalytic hydrogenolysis of furfural alcohol or via a hydrogenation-hydrogenolysis sequence from furfural in the vapor phase.L. W. Burnette, et al., "Production of 2-Methylfuran by Vapor Phase Hydrogenation of Furfural" Industrial and engineering Chemistry, V40, P502-505 (1948).
See also
References
{{reflist}}
External links
- [https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=10797 NCBI PubChem database: Methylfuran]
{{DEFAULTSORT:Methylfuran, 2-}}