3-Nitrotoluene
{{Chembox
| Name = 3-Nitrotoluene
| ImageFile = M-Nitrotoluol.svg
| ImageSize = 100
| PIN = 1-Methyl-3-nitrobenzene
| OtherNames = m-Nitrotoluene
|Section1={{Chembox Identifiers
| CASNo = 99-08-1
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 29A9W826KQ
| PubChem = 7422
| ChemSpiderID = 21106146
| ChEBI = 39931
| SMILES = O=[N+]([O-])c1cccc(C)c1
| InChI =1S/C7H7NO2/c1-6-3-2-4-7(5-6)8(9)10/h2-5H,1H3
}}
|Section2={{Chembox Properties
| C=7 | H=7 | N=1 | O=2
| Density = 1.1581 g·cm−3 @ 20°C
| MeltingPtC = 15.5
| BoilingPtC = 232
| VaporPressure = 0.1 mmHg (20°C)
| MagSus = −72.71·10−6 cm3/mol
}}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPtF = 223
| AutoignitionPt =
| IDLH = 200 ppm{{PGCH|0463}}
| REL = TWA 2 ppm (11 mg/m3) [skin]
| PEL = TWA 5 ppm (30 mg/m3) [skin]
}}
}}
{{distinguish|TNT}}
3-Nitrotoluene or meta-nitrotoluene is an organic compound with the formula {{Chem2|CH3C6H4NO2}}. It is one of three isomers of nitrotoluene. A yellow liquid, it is used in the manufacture of meta-toluidine, which is an intermediate in the production of various dyes.
Synthesis and reactions
It is made by nitrating toluene by conventional mixed acid (acetyl nitrate doesn't produce it{{Cite Wikidata|Q61714426}}): this reaction mainly affords a 2:1 mixture of 2-nitro and 4-nitro isomers, but after removal of the 2-isomer, the 3-nitrotoluene can be purified by distillation. It is a precursor to toluidine, which is used in producing azo dyes.{{Ullmann|author=Gerald Booth|title=Nitro Compounds, Aromatic|year=2007|doi=10.1002/14356007.a17_411}}
References
{{reflist}}
External links
- [https://www.cdc.gov/niosh/npg/npgd0463.html CDC - NIOSH Pocket Guide to Chemical Hazards - m-Nitrotoluene]
{{DEFAULTSORT:Nitrotoluene, 3-}}
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