Americium(III) chloride

{{Chembox

| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 477000816

| ImageFile = UCl3.png

| ImageFile_Ref = {{Chemboximage|correct|??}}

| ImageSize = 240px

| ImageName = Unit cell, ball and stick model of americium(III) chloride with a legend

| IUPACName = Americium(III) chloride

| SystematicName = Americium(3+) chloride

| OtherNames = Americium chloride

Americium trichloride

|Section1={{Chembox Identifiers

| CASNo = 13464-46-5

| CASNo_Ref = {{cascite|changed|??}}

| ChemSpiderID = 15964177

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| PubChem = 17815325

| SMILES = [Cl-].[Cl-].[Cl-].[Am+3]

| StdInChI = 1S/Am.3ClH/h;3*1H/q+3;;;/p-3

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = GQKWPBIZTINWCF-UHFFFAOYSA-K

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

}}

|Section2={{Chembox Properties

| Am=1 | Cl=3

| Appearance = Light red, opaque crystals

| Density = 5.87 g cm−3

| MeltingPtC = 715

| MeltingPt_ref = {{Citation|last1 = Perry|first1 = Dale L.|last2 = Phillips|first2 = Sidney L.|year = 1995

| title = Handbook of Inorganic Compounds|publisher = CRC Press|isbn = 0-8493-8671-3|pages = 15|url = https://books.google.com/books?id=0fT4wfhF1AsC&pg=PA15|access-date = 2008-06-25}}

| BoilingPtC = 850

| BoilingPt_ref = {{cite web|url= http://www.webelements.com/compounds/americium/americium_trichloride.html|title= Chemistry: Periodic Table: americium: compound data (americium (III) chloride)|access-date=2008-06-24|publisher= WebElements}}}}

|Section3={{Chembox Structure

| Coordination = Tricapped trigonal prismatic
(nine-coordinate)

| CrystalStruct = hexagonal (UCl3 type), hP8

| SpaceGroup = P63/m, No. 176}}

| Section8 = {{Chembox Related

| Related_ref =

| OtherAnions =Americium(III) fluoride
Americium(III) bromide
Americium(III) iodide

| OtherCations =Plutonium(III) chloride
Curium(III) chloride
Europium(III) chloride

| OtherFunction =Americium(II) chloride

| OtherFunction_label =americium chlorides

| OtherCompounds =

}}

}}

Americium(III) chloride or americium trichloride is the chemical compound composed of americium and chlorine with the formula AmCl3. This salt forms pink hexagonal crystals.

In the solid state each americium atom has nine chlorine atoms as near neighbours, at approximately the same distance, in a tricapped trigonal prismatic configuration.L. B. Asprey, T. K. Keenan, F. H. Kruse: "Crystal Structures of the Trifluorides, Trichlorides, Tribromides, and Triiodides of Americium and Curium", Inorg. Chem. 1965, 4 (7), 985–986; {{doi|10.1021/ic50029a013}}.A. F. Wells: Structural Inorganic Chemistry 5th edition (1984) Oxford Science Publications, {{ISBN|0-19-855370-6}}.

The hexahydrate has a monocline crystal structure with: a = 970.2 pm, b = 656.7 pm and c = 800.9 pm; β = 93° 37'; space group: P2/n.John H. Burns, Joseph Richard Peterson: "The Crystal Structures of Americium Trichloride Hexahydrate and Berkelium Trichloride Hexahydrate", Inorg. Chem. 1971, 10 (1), 147–151; {{doi|10.1021/ic50095a029}}.

Reactions

An americium(III) chloride electrorefining method has been investigated to separate mixtures of actinides, since the standard Gibbs free energy of formation of americium(III) chloride is much different than the rest of the actinide chlorides.

{{Citation

| last = Nuclear Energy Agency

| year = 2001

| title = Proceedings of the Workshop on Pyrochemical Separations

| place = Avignon, France

| publisher = OECD Publishing

| isbn = 92-64-18443-0

| pages = 276–277

| url = https://books.google.com/books?id=Gv7ohTjfG0UC&q=%22Americium+chloride%22&pg=PA277

| access-date = 2008-06-24

}}

This can be used to remove americium from plutonium by melting the crude mixture together with salts such as sodium chloride.

{{Citation

| year = 1992

| title = Plutonium Processing In The Nuclear Weapons Complex

| publisher = Diane Publishing

| isbn = 1-56806-568-X

| pages = 21

| url = https://books.google.com/books?id=0fc3lpCtUM4C&q=%22Americium+chloride%22&pg=PA21

| access-date = 2008-06-24

}}

References

{{Reflist}}

{{Americium compounds}}

{{Chlorides}}

{{Actinide halides}}

Category:Americium compounds

Category:Chlorides

Category:Actinide halides

{{Inorganic-compound-stub}}