Asulam
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 460319166
| ImageFile = Asulam.png
| ImageSize = 240
| ImageAlt = Skeletal formula
| ImageFile1 = Asulam-3D-balls.png
| ImageSize1 = 240
| ImageAlt1 = Ball-and-stick model
| PIN = Methyl (4-aminobenzene-1-sulfonyl)carbamate
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 3337-71-1
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 0Y5ASM7P5S
| PubChem = 18752
| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG = C18350
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 17707
| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 81696
| SMILES = O=S(=O)(c1ccc(N)cc1)NC(=O)OC
| InChI = 1/C8H10N2O4S/c1-14-8(11)10-15(12,13)7-4-2-6(9)3-5-7/h2-5H,9H2,1H3,(H,10,11)
| InChIKey = VGPYEHKOIGNJKV-UHFFFAOYAJ
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C8H10N2O4S/c1-14-8(11)10-15(12,13)7-4-2-6(9)3-5-7/h2-5H,9H2,1H3,(H,10,11)
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VGPYEHKOIGNJKV-UHFFFAOYSA-N
}}
|Section2={{Chembox Properties
| Formula = C8H10N2O4S
| MolarMass = 230.241 g/mol
| Appearance =
| Density = 1.419 g/mL
| MeltingPt =
| BoilingPt =
| Solubility =
}}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}
}}
Asulam is a herbicide invented by May & Baker Ltd, internally called M&B9057,{{cite web|url=http://www.chemspider.com/Chemical-Structure.17707.html?rid=5a4054d2-3aa3-4364-942b-6e3bfa42cd9c|title=ChemSpider – Asulam – C8H10N2O4S|accessdate=30 September 2011}} that is used in horticulture and agriculture to kill bracken{{cite journal
| title = An assessment of aerially applied asulam as a method of long-term bracken control
| author = R. J. Pakemana, M. G. Le Ducb and R. H. Marrs
| journal = Journal of Environmental Management
| volume = 53
| issue = 3
| pages = 255–262
| year = 1998
| url =
| doi = 10.1006/jema.1998.0207 | bibcode = 1998JEnvM..53..255P
| title = Restoration of Calluna heathland on a bracken Pteridium-infested site in north west England
| author = C. S. R. Snow and R. H. Marrs
| journal = Biological Conservation
| volume = 81
| issue = 1–2
| pages = 35–42
| year = 1997
| url =
| doi = 10.1016/S0006-3207(96)00147-4| bibcode = 1997BCons..81...35S
}} and docks.{{cite journal
| title = Interactions Between the Chrysomelid Beetle Gastrophysa viridula, the Weed Rumex obtusifolius and the Herbicide Asulam
| author = R. I. Speight and J. B. Whittaker
| journal = The Journal of Applied Ecology
| volume = 24
| issue = 1
| pages = 119–129
| year = 1987
| doi = 10.2307/2403791
| jstor = 2403791
| bibcode = 1987JApEc..24..119S
}} It is also used as an antiviral agent. It is currently marketed, by United Phosphorus Ltd - UPL, as "Asulox" which contains 400 g/L of asulam sodium salt.
European phase-out and ban
Asulam was declared not approved by the Commission Implementing Regulation (EU) No 1045/2011 of 19 October 2011 concerning the non-approval of the active substance asulam.{{CELEX|32011R1045|format=PDF|text=Commission Implementing Regulation (EU) No 1045/2011 of 19 October 2011 concerning the non-approval of the active substance asulam, in accordance with Regulation (EC) No 1107/2009 of the European Parliament and of the Council concerning the placing of plant protection products on the market, and amending Commission Decision 2008/934/EC}} Concerns included: lack of evidence concerning the fate of the toxic metabolite sulfanilamide and other metabolites; the poorly characterised nature of the impurities potentially present in the technical-grade product; toxicity to birds. This decision is given in with Regulation (EC) No 1107/2009 of the European Parliament and of the Council concerning the placing of plant protection products on the market, and amending Commission Decision 2008/934/EC.{{CELEX|02009R1107-20221121|format=PDF|text=Regulation (EC) No 1107/2009 of the European Parliament and of the Council of 21 October 2009 concerning the placing of plant protection products on the market and repealing Council Directives 79/117/EEC and 91/414/EEC (consolidated tex)}}
References
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