Balliranoite
{{Short description|Mineral from Italy}}
{{Infobox mineral
| name = Balliranoite
| category = Tectosilicates
| formula = (Na,K)6Ca2(Si6Al6O24)Cl2(CO3)
| system = Hexagonal
| class = 6 - Pyramidal
| symmetry = P63
| unit cell = a = 12.696 Å, c = 5.327 Å, V = 743.6 Å3, Z = 1
| color = Colorless
| habit = Prismatic
| twinning =
| cleavage = Perfect on (10-10)
| fracture =Irregular/Uneven
| tenacity = Brittle
| mohs = 5
| luster = Vitreous
| opticalprop = uniaxial positive
| streak =White
| density = 2.48 g/cm3
| references = [https://e-rocks.com/item/mtr759582/balliranoite E-Rock MinTreasure. 2020. England. Available in]
Chukanov, N.V., Zubkova, N.V., Pekov, I.V., Olysych, L.V., Bonaccorsi, E., Pushcharovsky, D.Yu (2010): Balliranoite, (Na,K)6Ca2(Si6Al6O24)Cl2(CO3), a new cancrinite-group mineral from Monte Somma - Vesuvio volcanic complex, Italy. European Journal of Mineralogy, 22, 113-119. Available in [https://rruff.info/rruff_1.0/uploads/EJM22_113.pdf]Hudson Institute of Mineralogy. 2021. Balliranoite. Mindat. Available in [https://www.mindat.org/min-39332.html]
}}
Balliranoite ((Na,K)6Ca2(Si6Al6O24)Cl2(CO)3) is a mineral that was discovered at Monte Somma – Vesuvio volcanic complex, Campania, Italy. This mineral is named in honor of [http://www.dst.uniroma1.it/en/Ballirano Paolo Ballirano] (b. 1964), Italian crystallographer and professor in the Department of Earth Sciences, University of Rome ‘‘La Sapienza’’, who has made important contributions to the crystal chemistry of cancrinite-group minerals.
Occurrence
Balliranoite is found in an alkaline skarnlike rock composed of orthoclase, phlogopite, clinohumite, calcite, diopside, pargasite, haüyne, apatite and balliranoite,{{cite web |title=Balliranoite |url=https://www.mindat.org/min-39332.html |website=www.mindat.org}} as product of the metasomatic interactions between alkaline magma and limestone. These chemical alterations by hydrothermal and other fluids replace elements in the chemical structure, changing the mineral composition of the rock.
Mineral properties
The idealized formula for balliranoite is (Na,K)6Ca2(Si6Al6O24)Cl2(CO3), and the empirical formula based on 12 Si atoms with isomorphic substitution by Al atoms is: Na4.70Ca2.53K0.73(Si6.02Al5.98O23.995)Cl2.34(CO3)0.82(SO40.27*0.12H2O. This is a uniaxial (+) mineral with w = 1.523(2), e = 1.525(2), composed of the following compounds:
| class="wikitable" | ||
| Compound | wt% | Range |
|---|---|---|
| Na2O | 13.05 | 12.80-13.24 |
| K2O | 3.08 | 3.01-3.16 |
| CaO | 12.70 | 12.56-12.85 |
| Al2O3 | 27.28 | 27.17-27.42 |
| SiO2 | 32.38 | 32.23-32.55 |
| CO2 | 3.24 | 3.18-3.30 |
| SO3 | 1.96 | 1.79-2.10 |
| Cl | 7.43 | 7.20-7.70 |
| H2O
|0.19 |0.15-0.23 | ||
| -O=Cl2 | -1.68 | - |
| Total | 99.63 | - |
X-ray crystallography
The powder diffraction data for balliranoite is:
| class="wikitable"
!d-spacing (Å) !Intensity |
| 4.797
|(100) |
| 3.669
|(57) |
| 3.281
|(73) |
| 2.754
|(16) |
| 2.662
|(58) |
| 2.648
|(13) |
| 2.446
|(31) |
| 2.120
|(18) |