Beryllium chromate

{{chembox

| ImageFile =File:Chromat-Ion.svgFile:Be2+.svg

| Name = Beryllium chromate

|Section1={{Chembox Identifiers

| CASNo_Ref = {{cascite|correct|??}}

| CASNo = 14216-88-7

| StdInChI=1S/Be.Cr.4O/q+2;;;;2*-1

| StdInChIKey=BUEWJAQVIISHRB-UHFFFAOYSA-N

| SMILES=[Be+2].[O-][Cr](=O)(=O)[O-]

}}

|Section2={{Chembox Properties

| Formula = BeCrO4

| MolarMass = 125.0076

| Appearance = }}

|Section3={{Chembox Structure}}

|Section4={{Chembox Thermochemistry}}

|Section7={{Chembox Hazards}}

|Section8={{Chembox Related

| OtherCations = Magnesium chromate, Calcium chromate, Strontium chromate, Barium chromate, Radium chromate

| OtherCompounds = Beryllium chromite}}}}

Beryllium chromate is a hypothetical inorganic compound, with the chemical formula of BeCrO4. It is predicted to have a certain bonding ability with noble gases.{{Cite journal |last1=Pan |first1=Sudip |last2=Ghara |first2=Manas |last3=Ghosh |first3=Sreyan |last4=Chattaraj |first4=Pratim K. |date=2016 |title=Noble gas bound beryllium chromate and beryllium hydrogen phosphate: a comparison with noble gas bound beryllium oxide |url=http://xlink.rsc.org/?DOI=C6RA20232B |journal=RSC Advances |language=en |volume=6 |issue=95 |pages=92786–92794 |doi=10.1039/C6RA20232B |bibcode=2016RSCAd...692786P |issn=2046-2069|url-access=subscription }} Little evidence has been published supporting the existence of this material.

Claims

Beryllium chromate is claimed to be obtained from the reaction of beryllium hydroxide and chromium trioxide:{{Cite journal |last1=Bleyer |first1=B. |last2=Moormann |first2=A. |date=1912-06-11 |title=Über Berylliumchromate |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19120760105 |journal=Zeitschrift für anorganische Chemie |language=en |volume=76 |issue=1 |pages=70–78 |doi=10.1002/zaac.19120760105}}

:Be(OH)2 + CrO3 → BeCrO4 + H2O

The reaction of potassium chromate and beryllium sulfate is claimed to produce beryllium hydroxide:{{Cite journal |last=Orlow |first=N. A. |date=1912-01-16 |title=Über Berylliumchromate |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19120790128 |journal=Zeitschrift für anorganische Chemie |language=en |volume=79 |issue=1 |pages=365–367 |doi=10.1002/zaac.19120790128}}

:BeSO4 + 2K2CrO4 + H2O → K2Cr2O7 + K2SO4 + Be(OH)2

References