Beryllium hydroxide
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 459976597
| ImageFile1 = Be(OH)2.png
| IUPACName = Beryllium hydroxide
| OtherNames = {{ubl|Beryllic acid|Hydrated beryllia}}
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 13327-32-7
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 2X0LRF1T6Q
| PubChem = 25879
| ChemSpiderID = 24110
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| EINECS = 236-368-6
| MeSHName = Beryllium+hydroxide
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 35102
| RTECS = DS3150000
| Gmelin = 1024
| SMILES = O[Be]O
| StdInChI = 1S/Be.2H2O/h;2*1H2/q+2;;/p-2
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| InChI = 1/Be.2H2O/h;2*1H2/q+2;;/p-2
| StdInChIKey = WPJWIROQQFWMMK-UHFFFAOYSA-L
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| InChIKey = WPJWIROQQFWMMK-NUQVWONBAB
}}
|Section2={{Chembox Properties
| H=2 | Be=1 | O=2
| Appearance = Vivid white, opaque crystals
| Density = 1.92 g cm−3Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, {{ISBN|0-07-049439-8}}
| MeltingPtC =
| MeltingPt_notes = (decomposes)
| Solubility = 0.0000023965 g/L
| SolubilityProduct = 6.92{{e|−22}}{{cite book |author1=John Rumble |title=CRC Handbook of Chemistry and Physics |date=June 18, 2018 |publisher=CRC Press |isbn=978-1138561632 |pages=4–47|edition=99 |language=English}}
}}
|Section3={{Chembox Structure
| MolShape = Linear
}}
|Section4={{Chembox Thermochemistry
| DeltaHf = −904 kJ mol−1{{cite book |author= Zumdahl, Steven S.|title= Chemical Principles 6th Ed. |publisher= Houghton Mifflin Company |year= 2009 |isbn= 978-0-618-94690-7}}
| DeltaGf = −818 kJ/mol
| HeatCapacity = 1.443 J K−1
}}
|Section5={{Chembox Hazards
| MainHazards = Carcinogenic
| NFPA-H = 4
| NFPA-F = 0
| NFPA-R = 0
| GHSPictograms = {{GHS06}}{{GHS08}}{{GHS09}}{{cite web |title=Beryllium Hydroxide |url=https://www.americanelements.com/beryllium-hydroxide-13327-32-7 |website=American Elements |access-date=5 July 2023}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|}}
| PPhrases = {{P-phrases|}}
| LD50 = 4 mg kg−1 (intravenous, rat)
| REL = Ca C 0.0005 mg/m3 (as Be){{PGCH|0054}}
| PEL = TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be)
}}
|Section6={{Chembox Related
| OtherCompounds = Aluminium oxide
}}
}}
Beryllium hydroxide, Be(OH)2, is an amphoteric hydroxide, dissolving in both acids and alkalis. Industrially, it is produced as a by-product in the extraction of beryllium metal from the ores beryl and bertrandite.Jessica Elzea Kogel, Nikhil C. Trivedi, James M. Barker and Stanley T. Krukowski, 2006, Industrial Minerals & Rocks: Commodities, Markets, and Uses, 7th edition, SME, {{ISBN|0-87335-233-5}} The natural pure beryllium hydroxide is rare (in form of the mineral behoite, orthorhombic) or very rare (clinobehoite, monoclinic).Mindat, http://www.mindat.org/min-603.htmlMindat, http://www.mindat.org/min-1066.html When alkali is added to beryllium salt solutions the α-form (a gel) is formed. If this left to stand or boiled, the rhombic β-form precipitates.Mary Eagleson, 1994, Concise encyclopedia chemistry, Walter de Gruyter, {{ISBN|3-11-011451-8}} This has the same structure as zinc hydroxide, Zn(OH)2, with tetrahedral beryllium centers.{{Greenwood&Earnshaw2nd}}
Reactions
Beryllium hydroxide is difficult to dissolve in water. With alkalis it dissolves to form the tetrahydroxoberyllate (also known as tetrahydroxidoberyllate) anion, [Be(OH)4]2−.Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier {{ISBN|0-12-352651-5}} With sodium hydroxide solution:
:2 NaOH(aq) + Be(OH)2(s) → Na2[Be(OH)4](aq)
With acids, beryllium salts are formed. For example, with sulfuric acid, H2SO4, beryllium sulfate is formed:
:Be(OH)2 + H2SO4 → BeSO4 + 2 H2O
Beryllium hydroxide dehydrates at 400 °C to form the soluble white powder, beryllium oxide:
:Be(OH)2 → BeO + H2O
Further heating at higher temperature produces acid insoluble BeO.
References
{{Reflist}}
{{Beryllium compounds}}
{{Hydroxides}}