Bromoantimonates

!Name (full or part)

!Formula

!System

!Space group

!Unit cell (Å)

!Volume

!Density

!Notes

!Ref

|[H₄N]₂SbBr₆

|tetragonal

|I4₁/amd

|a=10.66 c=21.52

|

|

|black; Sb(III) and Sb(V)

|{{Cite journal |last1=Lawton |first1=Stephen L. |last2=Jacobson |first2=Robert A. |date=May 1966 |title=The Crystal Structure of Ammonium Hexabromoantimonate, (NH 4 ) 4 Sb III Sb V Br 12 |url=https://pubs.acs.org/doi/abs/10.1021/ic50039a011 |journal=Inorganic Chemistry |language=en |volume=5 |issue=5 |pages=743–749 |doi=10.1021/ic50039a011 |issn=0020-1669|url-access=subscription }}

|(NH₄)₃Sb₂Br₉

|

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|

|

|inefficient photovoltaic; soluble in ethanol

|{{Cite journal |last1=Zuo |first1=Chuantian |last2=Ding |first2=Liming |date=2017-06-01 |title=Lead-free Perovskite Materials (NH 4 ) 3 Sb 2 I x Br 9− x |url=https://onlinelibrary.wiley.com/doi/10.1002/ange.201702265 |journal=Angewandte Chemie |language=en |volume=129 |issue=23 |pages=6628–6632 |doi=10.1002/ange.201702265|bibcode=2017AngCh.129.6628Z |url-access=subscription }}

|(NH₄)₇Sb₃Br₁₆

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|{{Cite journal |last=Pugh |first=W. |date=1954 |title=Hydrazine. Part VII. Some halogeno-antimonites and -bismuthites of hydrazine |url=http://xlink.rsc.org/?DOI=jr9540001385 |journal=Journal of the Chemical Society (Resumed) |language=en |pages=1385–1388 |doi=10.1039/jr9540001385 |issn=0368-1769|url-access=subscription }}

|[C(NH₂)₃]SbBr₆

|

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|black; Sb(V)

|{{Cite journal |last1=Furukawa |first1=Yoshihiro |last2=Terao |first2=Hiromitsu |date=2002-07-01 |title=81 Br NQR and 1 H NMR of Guanidinium Hexabromoantimonate(V) [C(NH 2 ) 3 ]SbBr 6 : Phase Transition and Molecular Motion |journal=Zeitschrift für Naturforschung A |language=en |volume=57 |issue=6–7 |pages=399–402 |doi=10.1515/zna-2002-6-719 |bibcode=2002ZNatA..57..399F |s2cid=93394742 |issn=1865-7109|doi-access=free }}

|[C(NH₂)₃]₃Sb₂Br₉

|monoclinic

|C2/c

|a = 15.695 b = 9.039 c = 18.364 β = 96.94° Z=4

|

|

|@143K; phase transition 435/450 K

|{{Cite journal |last1=Terao |first1=Hiromitsu |last2=Furukawa |first2=Yoshihiro |last3=Miki |first3=Satomi |last4=Tajima |first4=Fukue |last5=Hashimoto |first5=Masao |date=2005-12-24 |title=NQR, NMR and Crystal Structure Studies of [C(NH2)3]3Sb2Br9 |url=http://link.springer.com/10.1007/s10751-005-9099-y |journal=Hyperfine Interactions |language=en |volume=159 |issue=1–4 |pages=211–216 |doi=10.1007/s10751-005-9099-y |s2cid=95437922 |issn=0304-3843|url-access=subscription }}{{Cite journal |last1=Szklarz |first1=P |last2=Zaleski |first2=J |last3=Jakubas |first3=R |last4=Bator |first4=G |last5=Medycki |first5=W |last6=Falińska |first6=K |date=2005-04-20 |title=The structure, phase transition and molecular dynamics of [C(NH 2 ) 3 ] 3 [Sb 2 Br 9 ] |url=https://iopscience.iop.org/article/10.1088/0953-8984/17/15/021 |journal=Journal of Physics: Condensed Matter |volume=17 |issue=15 |pages=2509–2528 |doi=10.1088/0953-8984/17/15/021 |bibcode=2005JPCM...17.2509S |s2cid=96818420 |issn=0953-8984|url-access=subscription }}

|(CH₃NH₃)₃SbBr₆

|monoclinic

|P2₁/c

|a=13.577 b=8.254 c=21.665 β=134.05° Z=4

|

|

|

|{{Cite journal |last1=Okuda |first1=Tsutomu |last2=Kinoshita |first2=Yoshihiro |last3=Terao |first3=Hiromitsu |last4=Yamada |first4=Koji |date=1994-02-01 |title=Structure and Bonding of Bromoantimonate (III) Complexes with Unusual Valency by Means of NQR and Powder X-Ray Diffraction |journal=Zeitschrift für Naturforschung A |language=en |volume=49 |issue=1–2 |pages=185–192 |doi=10.1515/zna-1994-1-228 |s2cid=3503225 |issn=1865-7109|doi-access=free }}

|(CH₃NH₃)₃Sb₂Br₉

|

|P{{overbar|3}}m1

|a=8.188 c=9.927 Z=1

|

|3.049

|yellow

|{{Cite journal |last1=Varma |first1=Vijay |last2=Bhattacharjee |first2=Ramendu |last3=Vasan |first3=H.N. |last4=Rao |first4=C.N.R. |date=November 1992 |title=Infrared and Raman spectroscopic investigations of methylammonium haloantimonates(III), [N(CH3)4−nHn]3 Sb2X9 (n = 0–3, X = Cl or Br), through their phase transitions |url=https://linkinghub.elsevier.com/retrieve/pii/058485399280237Q |journal=Spectrochimica Acta Part A: Molecular Spectroscopy |language=en |volume=48 |issue=11–12 |pages=1631–1646 |doi=10.1016/0584-8539(92)80237-Q|bibcode=1992AcSpA..48.1631V |url-access=subscription }}{{Cite journal |last1=Ishihara |first1=Hideta |last2=Watanabe |first2=Koichi |last3=Iwata |first3=Ayako |last4=Yamada |first4=Koji |last5=Kinoshita |first5=Yoshihiro |last6=Okuda |first6=Tsutomu |last7=Krishnan |first7=V. G. |last8=Dou |first8=Shi-qi |last9=Weiss |first9=Alarich |date=1992-02-01 |title=NQR and X-ray Studies of [N(CH 3 ) 4 ] 3 M 2 X 9 and (CH 3 NH 3 ) 3 M 2 X 9 (M = Sb,Bi; X = Cl,Br) |journal=Zeitschrift für Naturforschung A |language=en |volume=47 |issue=1–2 |pages=65–74 |doi=10.1515/zna-1992-1-213 |s2cid=51832125 |issn=1865-7109|doi-access=free }}

|[(CH₃)₂NH₂]₃SbBr₆

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|[(CH₃)₂NH₂]₃Sb₂Br₉

|monoclinic

|P2₁/a

|a = 14.612 b = 9.228 c = 10.005 β = 94.91° Z = 2

|

|

|

|{{Cite journal |last1=Jakubas |first1=R. |last2=Sobczyk |first2=L. |last3=Matuszewski |first3=J. |date=August 1987 |title=Ferroelectricity and phase transitions in tris (dimethylammonium) nonabromodiantimonate (III) |url=http://www.tandfonline.com/doi/abs/10.1080/00150198708201316 |journal=Ferroelectrics |language=en |volume=74 |issue=1 |pages=339–345 |doi=10.1080/00150198708201316 |bibcode=1987Fer....74..339J |issn=0015-0193|url-access=subscription }}

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|[(CH₃)₃NH]₃Sb₂Br₉

|orthorhomic

|

|a 11.40 b 10.31 c 12.91

|

|

|

|{{Cite journal |last1=Jha |first1=N.K. |last2=Rizvi |first2=S.S.A. |date=July 1974 |title=Some studies on bromoantimonate(III) complexes |url=https://linkinghub.elsevier.com/retrieve/pii/002219027480610X |journal=Journal of Inorganic and Nuclear Chemistry |language=en |volume=36 |issue=7 |pages=1479–1489 |doi=10.1016/0022-1902(74)80610-X|url-access=subscription }}

|[NMe₄]₃[Sb₂Br₉]

|hexagonal

|P6₃/mmc

|a=9.499 c=22.225 Z=2

|

|

|crimson red

|{{Cite journal |last1=Hall |first1=Michael |last2=Nunn |first2=Michael |last3=Begley |first3=Michael J. |last4=Sowerby |first4=D. Bryan |date=1986 |title=Nonahalogenodiantimon(III)ates; their preparation and the crystal structures of [Hpy]3[Sb2Cl9], [NMe4]3[Sb2Br9], and [NMe4]3[Sb2Br3Cl6] |url=http://xlink.rsc.org/?DOI=dt9860001231 |journal=Journal of the Chemical Society, Dalton Transactions |language=en |issue=6 |pages=1231–1238 |doi=10.1039/dt9860001231 |issn=0300-9246|url-access=subscription }}{{Cite journal |last=Petzold |first=Walter |date=1933-11-10 |title=Komplexe Bromoverbindungen des Antimons |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19332150111 |journal= Zeitschrift für anorganische und allgemeine Chemie|language=de |volume=215 |issue=1 |pages=92–102 |doi=10.1002/zaac.19332150111 |issn=0863-1786|url-access=subscription }}

|[NMe₄]₃[Sb₂Br₉]•Br₂

|hexagonal

|P6₃/mmc

|a=9.585 c=22.667 Z=2

|

|

|

|{{Cite journal |last1=Hubbard |first1=Camden R. |last2=Jacobson |first2=Robert A. |date=September 1972 |title=Molecular bromine bridging of SbIII2Br93- anions and the crystal structure of tetraethylammonium nonabromodiantimonate(III)-dibromine |url=https://pubs.acs.org/doi/abs/10.1021/ic50115a053 |journal=Inorganic Chemistry |language=en |volume=11 |issue=9 |pages=2247–2250 |doi=10.1021/ic50115a053 |issn=0020-1669|url-access=subscription }}

|[(CH₃)₄N]₃Sb₃Br₉•Br₂

|hexagonal

|P6₃/mmc

|a=9.5850 c=22.667 Z=2

|

|2.48

|red; yellow-orange when cold

|{{Cite journal |last=Hubbard |first=Camden Richards |date=1971-09-01 |title=Crystal structure determinations of rubidium hexabromoantimonate (III, V) and tetramethylammonium nonabromodiantimonate (III) dibromine and a highly efficient white radiation neutron diffraction technique |url=http://www.osti.gov/servlets/purl/4709000/ |language=en |pages=IS–T–-476, 4709000 |doi=10.2172/4709000|doi-access=free }}

|[(CH₃)₄N]₃Sb₂Br₉•I₂

|triclinic

|P{{overbar|1}}

|a=9.4869 b=9.5409 c=22.4906 α=92.058° β=90.933° γ=118.386° Z=2

|1788.5

|

|dark

|{{Cite journal |last1=Adonin |first1=Sergey A. |last2=Udalova |first2=Liubov I. |last3=Abramov |first3=Pavel A. |last4=Novikov |first4=Alexander S. |last5=Yushina |first5=Irina V. |last6=Korolkov |first6=Ilya V. |last7=Semitut |first7=Evgeniy Y. |last8=Derzhavskaya |first8=Tatiyana A. |last9=Stevenson |first9=Keith J. |last10=Troshin |first10=Pavel A. |last11=Sokolov |first11=Maxim N. |last12=Fedin |first12=Vladimir P. |date=2018-10-01 |title=A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks |url=https://onlinelibrary.wiley.com/doi/10.1002/chem.201802100 |journal=Chemistry - A European Journal |language=en |volume=24 |issue=55 |pages=14707–14711 |doi=10.1002/chem.201802100|pmid=30020549 |s2cid=51676863 |url-access=subscription }}

|(C₂H₅NH₃)₂[SbBr₅]

|orthorhombic

|Cmca

|a= 7.815 b=22.301 c=18.100 Z=8

|3154.5

|2.584

|at 298K; yellow; phase transition at 158.5K; decompose >450K

|

|(C₂H₅NH₃)₂[SbBr₅]

|orthorhombic

|Pbca

|a=7.684 b=22.413 c=17.780 Z=8

|3062.1

|2.661

|at 90K; yellow

|

|(C₂H₅NH₃)₂[SbBr₇]

|

|

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|

|

|{{Cite journal |last1=Rosenheim |first1=Arthur |last2=Stellmann |first2=Wilhelm |date=October 1901 |title=Ueber die Pentahalogenide des Antimons und ihre Doppelverbindungen |url=https://ia800708.us.archive.org/view_archive.php?archive=/22/items/crossref-pre-1909-scholarly-works/10.1002%252Fcber.190103402102.zip&file=10.1002%252Fcber.19010340322.pdf |journal=Berichte der Deutschen Chemischen Gesellschaft |language=en |volume=34 |issue=3 |pages=3377–3384 |doi=10.1002/cber.19010340322 |issn=0365-9496}}

|([C₂H₅]₂NH₂)₃SbBr₆

|hexagonal

|R3c

|a=15.155 c=20.085 Z=6

|

|

|dissolves in acetone

|{{Cite journal |last1=Okuda |first1=Tsutomu |last2=Hiura |first2=Morio |last3=Koshimizu |first3=Etsuo |last4=Ishihara |first4=Hideta |last5=Kushi |first5=Yoshihiko |last6=Negita |first6=Hisao |title=The NQR and Structure of Hexabromoantimonate(III) and Bismuthate(III) Ions |date=1982-09-05 |url=http://www.journal.csj.jp/doi/10.1246/cl.1982.1321 |journal=Chemistry Letters |language=en |volume=11 |issue=9 |pages=1321–1324 |doi=10.1246/cl.1982.1321 |issn=0366-7022|url-access=subscription }}

|[(C₂H₅)₄N]₂SbBr₆

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|

|

|very dark reddish brown

|

|[(C₂H₅)₄N]₃Sb₂Br₉

|hexagonal

|P6₃22

|a=10.3 c=24.4 Z=2

|2242

|2.02

|yellow

|{{Cite journal |last1=Miniewicz |first1=A. |last2=Jakubas |first2=R. |last3=Zaleski |first3=J. |date=June 1991 |title=Measurements of pyroelectric properties in [(C 2 H 5 ) 4 N] 3 Sb 2 Br 9 |url=http://www.tandfonline.com/doi/abs/10.1080/00150199108014740 |journal=Ferroelectrics |language=en |volume=118 |issue=1 |pages=23–28 |doi=10.1080/00150199108014740 |bibcode=1991Fer...118...23M |issn=0015-0193|url-access=subscription }}{{Cite journal |last1=Zaleski |first1=J. |last2=Jakubas |first2=R. |last3=Galewski |first3=Z. |last4=Sobczyk |first4=L. |date=1989-11-01 |title=Structural Phase Transitions in [(C 2 H 5 ) 4 N] 3 Sb 2 Br 9 and [(C 2 H 5 ) 4 N] 3 Bi 2 Br 9 |journal=Zeitschrift für Naturforschung A |language=en |volume=44 |issue=11 |pages=1102–1106 |doi=10.1515/zna-1989-1110 |bibcode=1989ZNatA..44.1102Z |s2cid=101200132 |issn=1865-7109|doi-access=free }}

|[(C₂H₅)₄N]SbBr₆

|tetragonal

|I4₁md

|a=8.7008 c=24.797 Z=4

|1877.3

|2.59

|dark red-brown

|{{Cite journal |last1=Clark |first1=Robin J. H. |last2=Duarte |first2=Maria Lenor |date=1977 |title=Raman, resonance-Raman, and electronic spectra of tetraethylammonium hexabromoantimonate(V) and of tetra-n-butylammonium hexa-bromoantimonate(V) |url=http://xlink.rsc.org/?DOI=dt9770000790 |journal=Journal of the Chemical Society, Dalton Transactions |language=en |issue=8 |pages=790–793 |doi=10.1039/dt9770000790 |issn=0300-9246|url-access=subscription }}{{Cite journal |last1=Jacobson |first1=Robert A. |last2=Hackert |first2=Marvin L. |last3=Keiderling |first3=Timothy A. |date=May 1971 |title=Crystal structure of tetraethylammonium hexabromoantimonate(V), (C2H5)4NSbBr6 |url=https://pubs.acs.org/doi/abs/10.1021/ic50099a044 |journal=Inorganic Chemistry |language=en |volume=10 |issue=5 |pages=1075–1078 |doi=10.1021/ic50099a044 |issn=0020-1669|url-access=subscription }}

|(n-C₃H₇NH₃)₂SbBr₅

|orthorhombic

|?

|a =7.884 b=14.516 c=15.913 Z=4

|1821.1

|2.33

|4 phase transitions: 189K, 165/163, 137/154

|{{Cite journal |last1=N. |first1=Pislewski |last2=J. |first2=Tritt-Goc |last3=R. |first3=Jakubas |title=Study on phase transitions and dynamics of n-propyl amine groups in (n-C₃H₇NH₃)₂SbBr₅ |url=https://inis.iaea.org/search/search.aspx?orig_q=RN:29023450 |language=Polish}}{{Cite journal |last1=Jakubas |first1=R. |last2=Bator |first2=G. |last3=Foulon |first3=M. |last4=Lefebvre |first4=J. |last5=Matuszewski |first5=J. |date=1993-03-01 |title=Structural Phase Transitions in (n-C 3 H 7 NH 3 ) 2 SbBr 5 |journal=Zeitschrift für Naturforschung A |language=en |volume=48 |issue=3 |pages=529–534 |doi=10.1515/zna-1993-0314 |bibcode=1993ZNatA..48..529J |s2cid=102140570 |issn=1865-7109|doi-access=free }}

|[(n-C₃H₇)₂NH₂]₃SbBr₆

|hexagonal

|R{{overbar|3}}c

|a=13.649 c=31.548 Z=6

|

|

|dissolves in acetone

|

|[(n-C₃H₇)₃NH]₃Sb₂Br₉

|orthorhombic

|?

|a 12.91 b 14.51 c 20.0

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|[(i-C₃H₇)₂NH₂]₂SbBr₅

|orthorhombic

|

|a 14.99 b 16.687 c 21.72

|

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|[(C₃H₇)₄N][SbBr₄]

|orthorhombic

|Pbca

|a=15.566 b=13.822 c=19.574 Z=8

|4211.5

|

|yellow

|{{Cite journal |last1=Weslati |first1=Najoua |last2=Elgahami |first2=Hanen |last3=Hamdi |first3=Mohamed |last4=Oueslati |first4=Abderrazek |last5=Naïli |first5=Houcine |date=June 2022 |title=Crystal structure, phase transition and electrical conductivity studies of [(C3H7)4N][SbBr4] compound |url=https://link.springer.com/10.1007/s13738-021-02472-w |journal=Journal of the Iranian Chemical Society |language=en |volume=19 |issue=6 |pages=2481–2493 |doi=10.1007/s13738-021-02472-w |s2cid=246235582 |issn=1735-207X|url-access=subscription }}

|[(CH₃)₂CHNH₃]₂SbBr₅

|orthorhombic

|

|a=12.013 b =12.134 c=12.525

|

|

|phase transition at 171K, 180 K

|{{Cite journal |last1=Tritt-Goc |first1=By J. |last2=Pislewski |first2=N. |last3=Goc |first3=R. |last4=Jakubas |first4=H. PISLEWSKA and R. |date=November 1997 |title=Molecular motion in solid \[(CH3)2 CHNH3]2 BiBr5 and \[(CH3)2 CHNH3]2SbBr5 as studied by proton nuclear magnetic resonance |url=http://www.tandfonline.com/doi/abs/10.1080/002689797169961 |journal=Molecular Physics |language=en |volume=92 |issue=4 |pages=687–692 |doi=10.1080/002689797169961 |bibcode=1997MolPh..92..687T |issn=0026-8976|url-access=subscription }}

|[(CH₃)₂CHNH₃]₂SbBr₅

|monoclinic

|

|

|

|

|

|{{Cite journal |last1=Jakubas |first1=R |last2=Bator |first2=G |last3=Ciapala |first3=P |last4=Zaleski |first4=J |last5=Baran |first5=J |last6=Lefebvre |first6=J |date=1995-07-03 |title=Calorimetric, dielectric, infrared spectra and thermal expansion studies of structural phase transitions in ((CH 3 ) 2 CHNH 3 ) 2 MX 5 (M=Sb, Bi; X=Cl, Br) crystals |url=https://iopscience.iop.org/article/10.1088/0953-8984/7/27/018 |journal=Journal of Physics: Condensed Matter |volume=7 |issue=27 |pages=5335–5350 |doi=10.1088/0953-8984/7/27/018 |bibcode=1995JPCM....7.5335J |s2cid=250915716 |issn=0953-8984|url-access=subscription }}

|(Et(n-Pr)₃N)₃[Sb₃Br₁₂]

|triclinic

|P{{overbar|1}}

|a 10.6469 b 14.8847 c 18.3714 α 86.082° β 85.502° γ 84.116°

|

|

|

|{{Cite journal |last1=Petrov |first1=M. D. |last2=Sokolov |first2=M. N. |last3=Fedin |first3=V. P. |last4=Adonin |first4=S. A. |date=November 2020 |title=CRYSTAL STRUCTURES OF POLYNUCLEAR ANTIMONY BROMIDECOMPLEXES (Et(n-Pr)3N)3[Sb3Br12] AND (2,2′-bipyH)4[Sb4Br20] |url=http://link.springer.com/10.1134/S0022476620110128 |journal=Journal of Structural Chemistry |language=en |volume=61 |issue=11 |pages=1794–1799 |doi=10.1134/S0022476620110128 |s2cid=229372408 |issn=0022-4766|url-access=subscription }}

|(i-C₄H₉NH₃)₂SbBr₅

|

|

|

|

|

|

|{{Cite journal |last1=Jakubas |first1=R. |last2=Jóźków |first2=J. |last3=Bator |first3=G. |last4=Zaleski |first4=J. |last5=Baran |first5=J. |last6=François |first6=P. |date=December 1997 |title=Phase transitions in i-butylammonium halogenoantimonate(III) and bismuthate(III) crystals |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286097002135 |journal=Journal of Molecular Structure |language=en |volume=436-437 |pages=315–325 |doi=10.1016/S0022-2860(97)00213-5|bibcode=1997JMoSt.436..315J |url-access=subscription }}

|[NH₃(CH₂)₂NH₃]₅(Sb₂Br₁₁)₂·4H₂O

|monoclinic

|P2₁/a

|a = 14.346 b = 13.206 c = 17.027 β = 113.05° Z = 2

|

|2.941

|

|{{Cite journal |last1=Chaabouni |first1=S. |last2=Kamoun |first2=S. |last3=Jaud |first3=J. |date=March 1998 |title=Calorimetric Studies and Crystal Structure of [C2H10N2]5(Sb2Br11)2·4H2O |url=https://linkinghub.elsevier.com/retrieve/pii/S0025540897002511 |journal=Materials Research Bulletin |language=en |volume=33 |issue=3 |pages=377–388 |doi=10.1016/S0025-5408(97)00251-1|url-access=subscription }}

|(C₆H₅NH₃)₂SbBr₅

|orthorhombic

|Pbca

|a = 19.704 b = 7.914 c = 25.556, Z = 8

|3985

|2.365

|yellow green; insoluble water

|

|(N₂H₅)₂SbBr₅

|

|

|

|

|

|yellow

|

|(N₂H₅)₃Sb₂Br₉

|

|

|

|

|

|yellow

|

|(N₂H₅)₁₁Sb₂Br₁₇

|

|

|

|

|

|yellow; melt 165°

|

|(N₂H₅)₁₀Sb₃Br₁₉

|

|

|

|

|

|yellow

|

|(C₂H₄N₃)₂[SbBr₅]·(C₂H₄N₃)Br

|orthorhombic

|P2₁2₁2₁

|a=8.6087 b=11.7985 c=20.5457

|

|

|

|{{Cite journal |last=Bujak |first=Maciej |date=January 2015 |title=Primary- and secondary-octahedral distortion factors in bis(1,4-H2-1,2,4-triazolium) pentabromidoantimonate(III)–1,4-H2-1,2,4-triazolium bromide |url=https://linkinghub.elsevier.com/retrieve/pii/S0277538714006123 |journal=Polyhedron |language=en |volume=85 |pages=499–505 |doi=10.1016/j.poly.2014.09.009|url-access=subscription }}

|(C₂N₃H₄)₃[SbBr₆]

|tetragonal

|P4₂/m

|a=11.149 c=8.318 Z=2

|1033.9

|2.606

|@320K

|{{Cite journal |last1=Chański |first1=Michał |last2=Białońska |first2=Agata |last3=Jakubas |first3=Ryszard |last4=Rok |first4=Magdalena |last5=Zaręba |first5=Jan K. |last6=Janicki |first6=Rafał |last7=Durlak |first7=Piotr |last8=Piecha-Bisiorek |first8=A. |date=2023-05-18 |title=Progressive Structural Complexity in Ferroelectric 1,2,4-Triazolium Hexabromoantimonate(III): Interplay of "Order–Disorder" and "Displacive" Contributions to the Structural Phase Transitions |journal=The Journal of Physical Chemistry Letters |language=en |volume=14 |issue=19 |pages=4524–4531 |doi=10.1021/acs.jpclett.3c00924 |issn=1948-7185 |pmc=10201570 |pmid=37159252}}

|(C₂N₃H₄)₃[SbBr₆]

|monoclinic

|

|a=15.699 b=16.294 c=15.018 β = 90.41 Z=8

|4097

|2.631

|@293K

|

|(C₃H₅NH₃)₃SbBr₆

|monoclinic

|C2/m

|

|

|

|4 phases

|{{Cite journal |last1=Płowaś |first1=I. |last2=Białońska |first2=A. |last3=Jakubas |first3=R. |last4=Bator |first4=G. |last5=Zarychta |first5=B. |last6=Baran |first6=J. |date=September 2010 |title=Structural characterization, thermal, dielectric and vibrational properties of tris(allylammonium) hexabromoantimonate(III), (C3H5NH3)3SbBr6 |url=https://linkinghub.elsevier.com/retrieve/pii/S0301010410003265 |journal=Chemical Physics |language=en |volume=375 |issue=1 |pages=16–25 |doi=10.1016/j.chemphys.2010.07.012|bibcode=2010CP....375...16P |url-access=subscription }}

|[n-C₄H₉NH₃]₂•[SbBr₅]

|orthorhombic

|Pnma

|a=16.845 b=54.899 c=15.697

|

|

|340K deep yellow; 3 phases

|{{Cite journal |last1=Tarasiewicz |first1=J. |last2=Jakubas |first2=R. |last3=Baran |first3=J. |last4=Pietraszko |first4=A. |date=July 2004 |title=On the structural phase transitions in [n-C4H9NH3]2[SbBr5]: thermal, dielectric and infrared studies |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286004002984 |journal=Journal of Molecular Structure |language=en |volume=697 |issue=1–3 |pages=161–171 |doi=10.1016/j.molstruc.2004.03.050|bibcode=2004JMoSt.697..161T |url-access=subscription }}

|[n-C₄H₉NH₃]₂•[SbBr₅]

|monoclinic

|P2/m

|a=15.597, b=62.854, c=16.771 β=92.05°

|

|

|300K

|

|[n-C₄H₉NH₃]₃•[SbBr₆]

|

|

|a 11.47 b 15.07 c 18.57

|

|

|

|

|[(n-C₄H₉)₂NH₂]₃•[SbBr₆]

|monoclinic

|P2₁/c

|a 13.03 b 13.51 c 18.94 β 94.0°

|

|

|

|

|[(n-C₄H₉)₄N]•[SbBr₆]

|

|

|

|

|

|

|

|[n-C₅H₁₁NH₃]₂•[SbBr₅]

|orthorhombic

|Pna2₁

|a=17.0105 b=32.875 c=7.8882

|

|

|298K; 3 phases transitions at 388K 224K

|

|[n-C₅H₁₁NH₃]₂•[SbBr₅]

|orthorhombic

|P2₁2₁2₁

|a=16.9234 b=32.3689 c=7.7418

|

|

|86K

|

|[C₂H₆F₂N]₃SbBr₆

|monoclinic

|P₁2₁/n₁

|a=8.0145 b=12.1192 c=21.2967 β=91.686 Z=4

|2067.6

|2.722

|yellow

|{{Cite journal |last1=Song |first1=Ning |last2=Chen |first2=Shaopeng |last3=Fan |first3=Xiaowei |last4=Tan |first4=Yuhui |last5=Tang |first5=Yunzhi |last6=Wang |first6=Lijuan |last7=Liao |first7=Juan |last8=Sun |first8=Zhen |date=2022 |title=Tunable hybrid perovskites with a narrow bandgap and multistage phase transition properties: 2,2-difluoroethylamine·antimony hexabromide |url=http://xlink.rsc.org/?DOI=D2CE00438K |journal=CrystEngComm |language=en |volume=24 |issue=21 |pages=3872–3878 |doi=10.1039/D2CE00438K |issn=1466-8033|url-access=subscription }}

|[C₅N₂H₁₆]₂SbBr₅

|monoclinic

|P2₁/c

|a=21.426 b=7.889 c=19.96 β=116.79° Z=8

|3012

|

|

|{{Cite journal |last1=Mao |first1=Chen-Yu |last2=Liao |first2=Wei-Qiang |last3=Wang |first3=Zhong-Xia |last4=Zafar |first4=Zainab |last5=Li |first5=Peng-Fei |last6=Lv |first6=Xing-Hui |last7=Fu |first7=Da-Wei |date=2016-08-01 |title=Temperature-Triggered Dielectric-Optical Duple Switch Based on an Organic–Inorganic Hybrid Phase Transition Crystal: [C 5 N 2 H 16 ] 2 SbBr 5 |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01107 |journal=Inorganic Chemistry |language=en |volume=55 |issue=15 |pages=7661–7666 |doi=10.1021/acs.inorgchem.6b01107 |pmid=27414504 |issn=0020-1669|url-access=subscription }}

|[C₅N₂H₁₆]₂SbBr₅

|orthorhombic

|Pnma

|a=19.23 b=7.894 c=10.118 Z=4

|1536

|

|yellow

|

|[C₆H₁₈N₂]₂Sb₂Br₁₀

|monoclinic

|P2₁/c

|a = 10.7309 b = 10.5842 c = 14.5551 β = 96.962° Z = 4.

|

|

|yellow

|{{Cite journal |last1=Essalhi |first1=Rim |last2=Abdelbaky |first2=Mohammed S.M. |last3=Elleuch |first3=Slim |last4=Zouari |first4=Fatma |last5=García-Granda |first5=Santiago |date=December 2020 |title=Crystal structure, Hirschfield surface analysis, thermal and DFT investigation accomplished with photoluminescence study of bis(N, N-diethylethylendiammonium)decabromodiantimoinate(III) |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286020311534 |journal=Journal of Molecular Structure |language=en |volume=1221 |pages=128828 |doi=10.1016/j.molstruc.2020.128828|bibcode=2020JMoSt122128828E |hdl=10261/234567 |s2cid=224978285 |hdl-access=free }}

|[NH₃(CH₂)₅NH₃]SbBr₅

|orthorhombic

|P2₁2₁2₁

|a 7.964 b 13.9424 c 14.065

|

|

|@293K

|{{Cite journal |last1=Zhang |first1=Han-Yue |last2=Mei |first2=Guang-Quan |last3=Liao |first3=Wei-Qiang |date=2016-10-05 |title=Symmetry Breaking Phase Transition, Second-Order Nonlinear Optical and Dielectric Properties of a One-Dimensional Organic–Inorganic Hybrid Zigzag Chain Compound [NH 3 (CH 2 ) 5 NH 3 ]SbBr 5 |url=https://pubs.acs.org/doi/10.1021/acs.cgd.6b01179 |journal=Crystal Growth & Design |language=en |volume=16 |issue=10 |pages=6105–6110 |doi=10.1021/acs.cgd.6b01179 |issn=1528-7483|url-access=subscription }}

|[NH₃(CH₂)₅NH₃]SbBr₅

|orthorhombic

|Pnma

|a 14.04 b 8.04 c 13.97

|

|

|@393K

|

|[EtMe₂PhN]₃[Sb₂Br₉]

|orthorhombic

|Pnma

|a = 35.620 b = 9.954 c = 12.761 Z = 4

|

|

|

|{{Cite journal |last1=Jaschinski |first1=Bernd |last2=Blachnik |first2=Roger |last3=Reuter |first3=Hans |date=April 1999 |title=Ethyldimethylphenylammonium-halogenoantimonate(III) |journal=Zeitschrift für anorganische und allgemeine Chemie |language=de |volume=625 |issue=4 |pages=667–672 |doi=10.1002/(SICI)1521-3749(199904)625:4<667::AID-ZAAC667>3.0.CO;2-B |issn=0044-2313|doi-access=free }}

|(C₈H₁₂N)₃[Sb₂Br₉]

|triclinic

|P{{overbar|1}}

|a 9.7857(b 13.7658(c 17.0297(α 66.581( β 78.689( γ 72.601( Z=2

|

|

|

|{{Cite journal |last1=Kharrat |first1=Houda |last2=Kamoun |first2=Slaheddine |last3=Michaud |first3=François |date=2013-07-15 |title=Tris( N , N -dimethylanilinium) tri-μ-bromido-bis[tribromidoantimonate(III)] |url=https://scripts.iucr.org/cgi-bin/paper?S1600536813014335 |journal=Acta Crystallographica Section E: Structure Reports Online |volume=69 |issue=7 |pages=m353 |doi=10.1107/S1600536813014335 |issn=1600-5368 |pmc=3772401 |pmid=24046544|bibcode=2013AcCrE..69M.353K }}

|

|

|11.4258 b=8.9079 c=17.3627 β=92.225 Z=4

|1765.8

|2.647

|

|{{Cite journal |last1=Mousdis |first1=George A. |last2=Ganotopoulos |first2=Nikolaos-Minas |last3=Barkaoui |first3=Hamdi |last4=Abid |first4=Younes |last5=Psycharis |first5=Vassilis |last6=Savvidou |first6=Aikaterini |last7=Raptopoulou |first7=Catherine P. |date=2017-08-02 |title=One-Dimensional Organic–Inorganic Hybrid Materials Based on Antimony |url=https://onlinelibrary.wiley.com/doi/10.1002/ejic.201700277 |journal=European Journal of Inorganic Chemistry |language=en |volume=2017 |issue=28 |pages=3401–3408 |doi=10.1002/ejic.201700277 |issn=1434-1948|url-access=subscription }}

|[C₃H₈N]₂SbBr₅

|monoclinic

|P2₁/c

|a=11.8937 b=19.0986 c=7.8047 β = 108.908°

|1168.0

|2.525

|270K

|{{Cite journal |last1=Li |first1=Maofan |last2=Teng |first2=Bing |last3=Han |first3=Shiguo |last4=Yang |first4=Tao |last5=Li |first5=Yaobin |last6=Liu |first6=Yi |last7=Zhang |first7=Xinyuan |last8=Liu |first8=Xitao |last9=Luo |first9=Junhua |last10=Sun |first10=Zhihua |date=2019 |title=Near-room-temperature tunable dielectric response induced by dual phase transitions in a lead-free hybrid: (C 3 H 8 N) 2 SbBr 5 |url=http://xlink.rsc.org/?DOI=C9CE00458K |journal=CrystEngComm |language=en |volume=21 |issue=24 |pages=3740–3744 |doi=10.1039/C9CE00458K |s2cid=182282425 |issn=1466-8033|url-access=subscription }}

|[C₃H₈N]₂SbBr₅

|orthorhombic

|Pnca

|a=22.5314 b=18.9885 c=7.8845 Z=8

|2336.0

|2.511

|300K

|

|[C₃H₈N]₂SbBr₅

|orthorhombic

|Bbcm

|a=22.4485 b=18.9653 c=7.9488 Z=8

|2256

|2.503

|325K; band gap 2.41 eV; phase changes at 290 K and = 315 K

|

|(C₈NH₁₂)₂SbBr₅

|

|

|

|

|

|yellow

|{{Cite journal |last1=Zhang |first1=Ruiling |last2=Mao |first2=Xin |last3=Yang |first3=Yang |last4=Yang |first4=Songqiu |last5=Zhao |first5=Wenyuan |last6=Wumaier |first6=Tuerdi |last7=Wei |first7=Donghui |last8=Deng |first8=Weiqiao |last9=Han |first9=Keli |date=2019-02-25 |title=Air-Stable, Lead-Free Zero-Dimensional Mixed Bismuth-Antimony Perovskite Single Crystals with Ultra-broadband Emission |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201812865 |journal=Angewandte Chemie International Edition |language=en |volume=58 |issue=9 |pages=2725–2729 |doi=10.1002/anie.201812865 |pmid=30663267 |s2cid=58644281 |issn=1433-7851|url-access=subscription }}

|(C₆H₅CH₂NH₃)₃SbBr₆

|monoclinic

|P2₁/c

|a 15.2246 b 8.0632 c 24.3042 β 100.005° Z=4

|2938.2

|2.093

|yellow

|{{Cite journal |last1=Chen |first1=Da |last2=Dai |first2=Fulong |last3=Hao |first3=Shiqiang |last4=Zhou |first4=Guojun |last5=Liu |first5=Quanlin |last6=Wolverton |first6=Christopher |last7=Zhao |first7=Jing |last8=Xia |first8=Zhiguo |date=2020 |title=Crystal structure and luminescence properties of lead-free metal halides (C 6 H 5 CH 2 NH 3 ) 3 MBr 6 (M = Bi and Sb) |url=http://xlink.rsc.org/?DOI=D0TC00562B |journal=Journal of Materials Chemistry C |language=en |volume=8 |issue=22 |pages=7322–7329 |doi=10.1039/D0TC00562B |osti=1777408 |s2cid=216208053 |issn=2050-7526}}

|(R-CHEAH)Sb₃Br₁₀

|monoclinic

|P2₁

|a=12.76938 b=30.1777 c=13.2336 β=90.818

|

|

|

|{{Cite journal |last1=Wang |first1=Zhiyu |last2=Zhang |first2=Zixuan |last3=Sung |first3=Herman H. Y. |last4=Williams |first4=Ian D. |last5=Lu |first5=Haipeng |date=2022-08-19 |title=Structural Asymmetry and Chiroptical Activity of Chiral Antimony-Halide Hybrids |url=https://onlinelibrary.wiley.com/doi/10.1002/ejic.202200275 |journal=European Journal of Inorganic Chemistry |language=en |volume=2022 |issue=23 |doi=10.1002/ejic.202200275 |issn=1434-1948|url-access=subscription }}

|[C₄H₉N]₂SbBr₈

|monoclinic

|

|a=31.4 b=9.71 c=15.0 β=99.0° Z=8

|4517

|2.50

|black

|

|[C₄H₆ONH]₂SbBr₈

|

|

|

|

|

|black; orange red when cold

|

|[C₄H₉NCH₃]₃Sb₂Br₉

|trigonal

|R3c

|a=15.6943 c=15.6943 Z=6

|5018.8

|2.424

|yellow @293K

|{{Cite journal |last1=Sun |first1=Zhihua |last2=Zeb |first2=Aurang |last3=Liu |first3=Sijie |last4=Ji |first4=Chengmin |last5=Khan |first5=Tariq |last6=Li |first6=Lina |last7=Hong |first7=Maochun |last8=Luo |first8=Junhua |date=2016-09-19 |title=Exploring a Lead-free Semiconducting Hybrid Ferroelectric with a Zero-Dimensional Perovskite-like Structure |url=https://onlinelibrary.wiley.com/doi/10.1002/ange.201606079 |journal=Angewandte Chemie |language=en |volume=128 |issue=39 |pages=12033–12037 |doi=10.1002/ange.201606079 |bibcode=2016AngCh.12812033S |issn=0044-8249|url-access=subscription }}

|[C₄H₉NCH₃]₃Sb₂Br₉

|trigonal

|R{{overbar|3}}c

|a=15.9951 c=23.1124 Z=5

|5120.9

|2.376

|@335K

|

|(C₆H₁₄N)₃Sb₃Br₁₂

|monoclinic

|P2₁/n

|a=10.9372 b=21.928 c=17.598 β=90.796° Z=4

|4219.5

|

|

|{{Cite journal |last1=Tang |first1=Hao |last2=Zheng |first2=Pengfei |last3=Xiao |first3=Zhifeng |last4=Yuan |first4=Kejia |last5=Zhang |first5=Hanwen |last6=Zhao |first6=Xiaochen |last7=Zhou |first7=Wei |last8=Wang |first8=Shouyu |last9=Liu |first9=Weifang |date=2024-02-27 |title=Crystal Structure and Optical Properties Characterization in Quasi-0D Lead-Free Bromide Crystals (C 6 H 14 N) 3 Bi 2 Br 9 ·H 2 O and (C 6 H 14 N) 3 Sb 3 Br 12 |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c00052 |journal=Inorganic Chemistry |volume=63 |issue=10 |pages=4747–4757 |language=en |doi=10.1021/acs.inorgchem.4c00052 |issn=0020-1669|url-access=subscription }}

|[C₅H₁₁N]₂SbBr₈

|monoclinic

|

|a=28.8 b=19.8 c=18.7 β=116.28 Z=16

|9561

|2.58

|black

|

|(C₄H₁₂N₂)[SbBr₅]·H₂O

|monoclinic

|P2₁/n

|a=9.9162 b=14.4090 c=10.3898 β=99.432 Z=4

|1464.45

|2.846

|

|{{Cite journal |last1=Bujak |first1=Maciej |last2=Siodłak |first2=Dawid |date=2020-03-17 |title=Isostructural Inorganic–Organic Piperazine-1,4-diium Chlorido- and Bromidoantimonate(III) Monohydrates: Octahedral Distortions and Hydrogen Bonds |journal=Molecules |language=en |volume=25 |issue=6 |pages=1361 |doi=10.3390/molecules25061361 |issn=1420-3049 |pmc=7144372 |pmid=32192110 |doi-access=free }}

|[NH₂(C₂H₄)₂O]SbBr₄

|orthorhombic

|Pbca

|a=12.273 b=8.397 c=23.276 Z=8

|2399

|2.933

|yellow

|{{Cite journal |last1=Owczarek |first1=Magdalena |last2=Jakubas |first2=Ryszard |last3=Pietraszko |first3=Adam |last4=Medycki |first4=Wojciech |last5=Baran |first5=Jan |date=2013 |title=Investigation of structure–properties relationship in a novel family of halogenoantimonates(iii) and halogenobismuthates(iii) with morpholinium cation: [NH2(C2H4)2O]MX4. Crystal structure, phase transitions and dynamics of molecules |url=http://xlink.rsc.org/?DOI=c3dt51726h |journal=Dalton Transactions |language=en |volume=42 |issue=42 |pages=15069–15079 |doi=10.1039/c3dt51726h |pmid=23999763 |issn=1477-9226|url-access=subscription }}

|[NH₂(C₂H₄)₂O]₂[SbBr₅]

|orthorhombic

|P2₁2₁2₁

|a 9.274 b 10.325 c 18.472 Z=4

|1768.8

|2.620

|yellow; piezoelectric

|{{Cite journal |last1=Owczarek |first1=Magdalena |last2=Szklarz |first2=Przemysław |last3=Jakubas |first3=Ryszard |last4=Miniewicz |first4=Andrzej |date=2012 |title=[NH2(C2H4)2O]MX5: a new family of morpholinium nonlinear optical materials among halogenoantimonate(iii) and halogenobismuthate(iii) compounds. Structural characterization, dielectric and piezoelectric properties |url=http://xlink.rsc.org/?DOI=c2dt30291h |journal=Dalton Transactions |language=en |volume=41 |issue=24 |pages=7285–7294 |doi=10.1039/c2dt30291h |pmid=22572794 |issn=1477-9226|url-access=subscription }}

|[C₄H₉ONH]₂SbBr₈

|orthorhombic

|Pna2₁

|a=28.01 b=8.31 c=10.02 Z=4

|2332

|2.64

|black; red when cold

|

|(C₅H₅NH)SbBr₄

|triclinic

|P{{overbar|1}}

|

|

|

|@116K

|{{Cite journal |last1=Yamada |first1=K. |last2=Ohtani |first2=T. |last3=Shirakawa |first3=S. |last4=Ohki |first4=H. |last5=Okuda |first5=T. |last6=Kamiyama |first6=T. |last7=Oikawa |first7=K. |date=1996-06-01 |title=Phase Transition of C 5 H 5 NHSbBr 4 Having a Hypervalent Bond: A 2 H NMR and X-Ray Diffraction Study [Phase Transition of C 5 H 5 NHSbBr 4 ] |journal=Zeitschrift für Naturforschung A |language=en |volume=51 |issue=5–6 |pages=739–744 |doi=10.1515/zna-1996-5-664 |bibcode=1996ZNatA..51..739Y |s2cid=98228504 |issn=1865-7109|doi-access=free }}

|(C₅H₅NH)SbBr₄

|monoclinic

|C2/c

|a=11.825 b=13.048 c=7.798 β=93.87° Z=4

|

|2.922

|@297K

|

|(C₅H₅NH)₆Sb^IIISb^V₃Br₂₄

|orthorhombic

|CmC21

|a=17.51 b=23.77 c=16.46 Z=4

|6851

|2.80

|black

|{{Cite journal |last1=Hackert |first1=M. |last2=Lawton |first2=S. |last3=Jacobson |first3=R. |date=1968-01-01 |title=Properties of lntervalence Antimony Bromides |url=https://scholarworks.uni.edu/pias/vol75/iss1/17 |journal=Proceedings of the Iowa Academy of Science |volume=75 |issue=1 |pages=97–108 |issn=0085-2236}}

|(C₆H₅CH₂NH₃)₂SbBr₅

|monoclinic

|P2₁/a

|a=8.0254 b=19.5087 c=14.5079 β=107.451 Z=4

|2166.89

|2.261

|yellow

|{{Cite journal |last1=Anyfantis |first1=George C. |last2=Ganotopoulos |first2=Nikolaos-Minas |last3=Savvidou |first3=Aikaterini |last4=Raptopoulou |first4=Catherine P. |last5=Psycharis |first5=Vassilis |last6=Mousdis |first6=George A. |date=September 2018 |title=Synthesis and characterization of new organic–inorganic hybrid compounds based on Sb, with a perovskite like structure |url=https://linkinghub.elsevier.com/retrieve/pii/S0277538718302626 |journal=Polyhedron |language=en |volume=151 |pages=299–305 |doi=10.1016/j.poly.2018.05.024|s2cid=102517360 |url-access=subscription }}

|(1−CH₃C₅H₄NH)SbBr₄

|monoclinic

|P2₁/c

|a=12.73 b=13.54 c=7.59 β=107.3 Z=4

|1250

|2.85

|pale yellow

|{{Cite journal |last1=Stewart |first1=James M. |last2=McLaughlin |first2=Kevin L. |last3=Rossiter |first3=Joseph J. |last4=Hurst |first4=John R. |last5=Haas |first5=Raymond G. |last6=Rose |first6=Valerie J. |last7=Ciric |first7=Barbara E. |last8=Murphy |first8=Joan A. |last9=Lawton |first9=Stephen L. |date=1974-11-01 |title=Preparation, characterization, and crystallographic data of some substituted-pyridinium antimony(III) bromide salts |url=https://pubs.acs.org/doi/abs/10.1021/ic50141a046 |journal=Inorganic Chemistry |language=en |volume=13 |issue=11 |pages=2767–2769 |doi=10.1021/ic50141a046 |issn=0020-1669|url-access=subscription }}

|(1−CH₃C₅H₄NH)₂SbBr₆•Br₃

|triclinic

|P{{overbar|1}}

|a 7.4567 b 9.4488 c 9.6777 α 68.629° β 89.848° γ 73.002°

|1029.2

|

|

|{{Cite journal |last1=Adonin |first1=Sergey A. |last2=Bondarenko |first2=Mikhail A. |last3=Abramov |first3=Pavel A. |last4=Novikov |first4=Alexander S. |last5=Plyusnin |first5=Pavel E. |last6=Sokolov |first6=Maxim N. |last7=Fedin |first7=Vladimir P. |date=2018-07-17 |title=Bromo- and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen-Rich Halometalate Frameworks |url=https://onlinelibrary.wiley.com/doi/10.1002/chem.201801338 |journal=Chemistry – A European Journal |language=en |volume=24 |issue=40 |pages=10165–10170 |doi=10.1002/chem.201801338 |pmid=29683216 |s2cid=5041888 |issn=0947-6539|url-access=subscription }} (1)

|(2−CH₃C₅H₄NH)SbBr₄

|monoclinic

|P2₁/c

|a=12.84 b=13.31 c=7.65 β=106.6 Z=4

|1252

|2.84

|pale yellow

|

|(3−CH₃C₅H₄NH)SbBr₄

|monoclinic

|P2₁/c

|a=12.51 b=13.64 c=7.72 β=106.9 Z=4

|1260

|2.76

|pale yellow

|

|(2-Br-5-MePy)₂[SbBr₆](Br₃)

|monoclinic

|Im

|a 8.4041 b 13.341 c 12.237 β 95.731°

|

|

|

|

|(3−COOHC₅H₄NH)₂SbBr₅

|monoclinic

|C2/c

|a=14.10 b=19.43 c=8.01 β=98.6° Z=4

|2169

|2.36

|lemon yellow

|

|(4−CH₃C₅H₄NH)SbBr₄

|monoclinic

|P2₁/c

|a 12.011 b 13.581 c 7.7637 β 90.341°

|

|

|

|{{Cite journal |last1=Kulicka |first1=B. |last2=Jakubas |first2=R. |last3=Ciunik |first3=Z. |date=October 2006 |title=Structural characterization and properties of [4-CH3C5H4NH][SbBr4]. The mechanism of phase transitions in 4-methylpyridinium bromoantimonates(III) |url=https://linkinghub.elsevier.com/retrieve/pii/S1293255806001853 |journal=Solid State Sciences |language=en |volume=8 |issue=10 |pages=1229–1236 |doi=10.1016/j.solidstatesciences.2006.05.013|bibcode=2006SSSci...8.1229K |url-access=subscription }}

|(4−CH₃C₅H₄NH)₂SbBr₅

|triclinic

|P{{overbar|1}}

|a=10.66 b=10.86 c=9.30 α=108.8° β=97.7° γ=99.2° Z=2

|985

|2.39

|yellow needles

|{{Cite journal |last1=Ishihara |first1=Hideta |last2=Dou |first2=Shi-qi |last3=Weiss |first3=Alarich |date=March 1994 |title=NQR and X-Ray Study of Bis(4-methylpyridinium) Pentabromoantimonate(III), (4-CH 3 C 5 H 4 NH) 2 SbBr 5 |url=http://www.journal.csj.jp/doi/10.1246/bcsj.67.637 |journal=Bulletin of the Chemical Society of Japan |language=en |volume=67 |issue=3 |pages=637–640 |doi=10.1246/bcsj.67.637 |issn=0009-2673|url-access=subscription }}

|(4−CH₃C₅H₄NH)₃Sb₂Br₉•I₂

|monoclinic

|P2₁

|a=8.3290 b=23.5510 c=9.4722 β=104.388 Z=2

|1799.7

|

|

|

|(4−CH₃C₅H₄NH)₂SbBr₅•I₂

|monoclinic

|P2₁/n

|a=7.5955 b=14.6757 c=9.5902 β=91.607 Z=2

|2182.85

|

|

|

|(4-C₆H₇NH)₂Sb^VBr₉

|monoclinic

|C2/m

|a=18.39 b=7.440 c=9.84 β=113.14°

|

|2.760

|red

|{{Cite journal |last1=Lawton |first1=Stephen L. |last2=Hoh |first2=David M. |last3=Johnson |first3=Robert C. |last4=Knisely |first4=Alexander S. |date=February 1973 |title=Crystal structure of 4-methylpyridinium nonabromoantimonate(V), (4-C6H7NH)2SbVBr9 |url=https://pubs.acs.org/doi/abs/10.1021/ic50120a006 |journal=Inorganic Chemistry |language=en |volume=12 |issue=2 |pages=277–283 |doi=10.1021/ic50120a006 |issn=0020-1669|url-access=subscription }}

|(2−CH₃C₅H₄NH)₂SbBr₉

|triclinic

|P{{overbar|1}}

|a 9.249 b 9.750 c 7.645 α 90.07° β 107.46° γ 70.52° Z=2

|

|2.77

|black; orange at −174°

|{{Cite journal |last1=Lawton |first1=Stephen L. |last2=Jacobson |first2=Robert A. |date=October 1968 |title=Crystal structure of di-.alpha.-picolinium nonabromoantimonate(V) |url=https://pubs.acs.org/doi/abs/10.1021/ic50068a036 |journal=Inorganic Chemistry |language=en |volume=7 |issue=10 |pages=2124–2134 |doi=10.1021/ic50068a036 |issn=0020-1669|url-access=subscription }}

|(3−CH₃C₅H₄NH)₂SbBr₉

|monoclinic

|

|Z=2

|

|2.74

|black; orange at −174°

|

|(4−CH₃C₅H₄NH)₂SbBr₉

|monoclinic

|

|Z=2

|

|2.77

|black; red at −174°

|

|(1-FPy)₃[Sb₂Br₉]

|monoclinic

|C2/c

|a=21.85 b=21.15 c=13.85 β=104.6° Z=8

|6179

|2.70

|deep yellow

|

|?

|monoclinic

|C2/c

|a=11.83 b=13.03 c=7.70 β=93.9°

|1183

|2.4

|light orange

|

|(2-ClPyH)₂SbBr₅

|monoclinic

|P2₁/a

|a=10.64 b=15.87 c=5.88 β=105.3° Z=2

|957

|2.60

|orange

|

|(2-ClPyH)SbBr₆

|monoclinic

|P2₁/c

|a=13.0770 b=7.3498 c=16.5301 β=112.117°

|

|

|Sb(V)

|{{Cite journal |last1=Adonin |first1=Sergey A. |last2=Bondarenko |first2=Mikhail A. |last3=Samsonenko |first3=Denis G. |last4=Semitut |first4=Evgeniy Yu |last5=Sokolov |first5=Maxim N. |last6=Fedin |first6=Vladimir P. |date=May 2018 |title=Mononuclear bromide complexes of Sb(V): crystal structures and thermal behaviour |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286018301315 |journal=Journal of Molecular Structure |language=en |volume=1160 |pages=102–106 |doi=10.1016/j.molstruc.2018.01.092|bibcode=2018JMoSt1160..102A |url-access=subscription }}

|(2-BrPyH)₂SbBr₅

|monoclinic

|P2₁/a

|a=10.53 b=16.17 c=5.89 β=104.8° Z=2

|989

|2.82

|red

|

|(2-BrPyH)SbBr₆

|monoclinic

|P2₁/c

|a=13.111 b=7.3787 c=16.555 β=111.179°

|

|

|Sb(V)

|

|(2-IPyH)₂[SbBr₆](Br₃)

|monoclinic

|P2₁/n

|a 8.1800 b 12.9394 c 12.5865 β 105.412°

|

|

|

|

|(3-ClPyH)SbBr₆

|orthorhombic

|Pca2₁

|a=16.6414 b=7.3471 c=24.2543 Z=8

|2965.5

|

|cherry-red

|{{Cite journal |last1=Adonin |first1=S. A. |last2=Bondarenko |first2=M. A. |last3=Abramov |first3=P. A. |last4=Korolkov |first4=I. V. |last5=Plyusnin |first5=P. E. |last6=Sokolov |first6=M. N. |last7=Fedin |first7=V. P. |date=February 2019 |title=Mononuclear Sb(V) Bromide Complexes with 3-Halopyridinium Cations: Synthesis, Structures, and Thermal Stability |journal=Russian Journal of Coordination Chemistry |language=en |volume=45 |issue=2 |pages=128–132 |doi=10.1134/S1070328419020027 |s2cid=150157692 |issn=1070-3284|doi-access=free }}

|(3-BrPyH)₂SbBr₅

|monoclinic

|P2₁/c

|a=18.37 b=11.98 c=9.35 β=102.5° Z=4

|2009

|2.77

|pale yellow

|

|(3-BrPyH)SbBr₆

|orthorhombic

|Pca2₁

|

|

|

|cherry-red

|

|(3-IPyH)₂SbBr₅

|monoclinic

|P2₁/c

|a=17.99 b=12.31 c=9.35 β=91.5° Z=4

|2070

|2.99

|pale yellow

|

|(4-BrC₅H₄NH)₂SbBr₅

|triclinic

|P{{overbar|1}}

|a = 9.186 b = 10.622 c = 10.703 α = 99.665° β = 97.393° γ = 108.539° Z = 2

|

|

|

|{{Cite journal |last1=Terao |first1=Hiromitsu |last2=Ninomiya |first2=Seiko |last3=Hashimoto |first3=Masao |last4=Eda |first4=Kazuo |date=February 2010 |title=81Br NQR and crystal structure of 4-bromopyridinium pentabromoantimonate(III); 3c–4e bonding and NQR trans influence |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286009007406 |journal=Journal of Molecular Structure |language=en |volume=965 |issue=1–3 |pages=68–73 |doi=10.1016/j.molstruc.2009.11.040|bibcode=2010JMoSt.965...68T |url-access=subscription }}

|(4-BrPyH)₂[SbBr₆](Br₃)

|monoclinic

|P2₁/c

|a 7.3255 b 20.667 c 16.5665 β 95.627°

|

|

|

|

|(2,6-ClPyH)[SbBr₄]

|monoclinic

|P2/m

|a=10.45 b=10.76 c=13.45 β=110.2 Z=4

|1491

|2.76

|pale yellow

|

|(2,6-BrPyH)₃[SbBr₆](Br₃) · 2H₂O

|monoclinic

|C2/c

|a=32.8242 b=9.6155 c=14.7877 β=101.732°

|

|

|

|{{Cite journal |last1=Bondarenko |first1=M. A. |last2=Adonin |first2=S. A. |last3=Novikov |first3=A. S. |last4=Sokolov |first4=M. N. |last5=Fedin |first5=V. P. |date=May 2020 |title=Supramolecular Bromoantimonate(V) Polybromide (2,6-BrPyH)3[SbBr6]{(Br2)Br} · 2H2O: Specific Features of Halogen···Halogen Contacts in the Crystal Structure |url=https://link.springer.com/10.1134/S1070328420040016 |journal=Russian Journal of Coordination Chemistry |language=en |volume=46 |issue=5 |pages=302–307 |doi=10.1134/S1070328420040016 |s2cid=218624447 |issn=1070-3284|url-access=subscription }}

|(3,5-ClPyH)₂[SbBr₅]

|orthorhombic

|Pbca

|a=21,77 b=8.14 c=24.38 Z=8

|4320

|2.52

|deep yellow

|

|EtPySbBr₆

|

|

|

|

|

|

|{{Cite journal |last=Egger |first=David A. |date=2018-08-16 |title=Intermediate Bands in Zero-Dimensional Antimony Halide Perovskites |url=https://pubs.acs.org/doi/10.1021/acs.jpclett.8b01730 |journal=The Journal of Physical Chemistry Letters |language=en |volume=9 |issue=16 |pages=4652–4656 |doi=10.1021/acs.jpclett.8b01730 |pmid=30052447 |arxiv=1805.09560 |s2cid=51728397 |issn=1948-7185}}

|1-n-PrPySbBr₆

|monoclinic

|P2₁/n

|a=7.3687 b=16.4706 c=13.8620 β=97.054 Z=4

|1669.65

|

|

|{{Cite journal |last1=Adonin |first1=Sergey A. |last2=Bondarenko |first2=Mikhail A. |last3=Novikov |first3=Alexander S. |last4=Abramov |first4=Pavel A. |last5=Plyusnin |first5=Pavel E. |last6=Sokolov |first6=Maxim N. |last7=Fedin |first7=Vladimir P. |date=2019 |title=Halogen bonding-assisted assembly of bromoantimonate( v ) and polybromide-bromoantimonate-based frameworks |url=http://xlink.rsc.org/?DOI=C8CE01944D |journal=CrystEngComm |language=en |volume=21 |issue=5 |pages=850–856 |doi=10.1039/C8CE01944D |s2cid=104450943 |issn=1466-8033|url-access=subscription }} (1)

|1-n=BuPySbBr₆

|orthorhombic

|P2₁2₁2₁

|a=7.4277 b=14.1293 c=16.7699 Z=4

|1760.0

|

|

| (2)

|[2-NH₂C₅H₄NH][SbBr₄]

|monoclinic

|P2₁/c

|a 12.484 b 13.106 c 7.492 β 105.84° Z=4

|1179.1

|3.022

|@100K phase transition at 396/412K

|{{Cite journal |last1=Kulicka |first1=B |last2=Jakubas |first2=R |last3=Bator |first3=G |last4=Ciunik |first4=Z |last5=Medycki |first5=W |date=2004-11-24 |title=Structure and properties of [2-NH 2 C 5 H 4 NH][SbCl 4 ] and [2-NH 2 C 5 H 4 NH][SbBr 4 ] |url=https://iopscience.iop.org/article/10.1088/0953-8984/16/46/004 |journal=Journal of Physics: Condensed Matter |volume=16 |issue=46 |pages=8155–8172 |doi=10.1088/0953-8984/16/46/004 |bibcode=2004JPCM...16.8155K |s2cid=250876595 |issn=0953-8984|url-access=subscription }}

|(4-NH₂C₅H₄NH)SbBr₄

|monoclinic

|P2₁/c

|a 11.548 b 14.029 c 7.432 β 93.19°

|

|

|@220K

|{{Cite journal |last1=Hashimoto |first1=Masao |last2=Terao |first2=Hiromitsu |last3=Fuess |first3=Hartmut |last4=Svoboda |first4=Ingrid |last5=Ehrenberg |first5=Helmut |date=April 2003 |title=Crystal Structure, Hydrogen Bonding, and 81 Br NQR of Low-Temperature Phase of 4-Aminopyridinium Tetrabromoantimonate(III) |url=http://www.journal.csj.jp/doi/10.1246/bcsj.76.749 |journal=Bulletin of the Chemical Society of Japan |language=en |volume=76 |issue=4 |pages=749–753 |doi=10.1246/bcsj.76.749 |issn=0009-2673|url-access=subscription }}

|(2,2′-bipyH)₄[Sb₄Br₂₀]

|monoclinic

|P2₁/c

|a 14.5026 b 14.6945 c 16.5497 β 109.991°

|

|

|

|

|(PyC₂){[SbBr₆](Br₃)}

|triclinic

|P{{overbar|1}}

|a=7.3269 b=9.1941 c=9.7994  α=64.474 β=80.207 γ=86.244 Z=1

|586.99

|

|cherry-red

|{{Cite journal |last1=Bondarenko |first1=Mikhail A. |last2=Abramov |first2=Pavel A. |last3=Plyusnin |first3=Pavel E. |last4=Novikov |first4=Alexander S. |last5=Sokolov |first5=Maxim N. |last6=Adonin |first6=Sergey A. |date=July 2021 |title=Bromoantimonates with bis(pyridinium)-type dications obtained via oxidation by dibromine: Diverse structural types and features of interactions pattern |url=https://linkinghub.elsevier.com/retrieve/pii/S0277538721001996 |journal=Polyhedron |language=en |volume=202 |pages=115217 |doi=10.1016/j.poly.2021.115217|s2cid=234829102 |url-access=subscription }}

|PyC₂²⁺SbBr₅

|triclinic

|P{{overbar|1}}

|a 10.1060 b 10.2956 c 11.1394 α 105.030° β 101.709° γ 117.233°

|

|

|

|{{Cite journal |last1=Usoltsev |first1=Andrey N. |last2=Sukhikh |first2=Taisiya S. |last3=Novikov |first3=Alexander S. |last4=Shayapov |first4=Vladimir R. |last5=Pishchur |first5=Denis P. |last6=Korolkov |first6=Ilya V. |last7=Sakhapov |first7=Ilyas F. |last8=Fedin |first8=Vladimir P. |last9=Sokolov |first9=Maxim N. |last10=Adonin |first10=Sergey A. |date=2021-02-15 |title=Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03699 |journal=Inorganic Chemistry |language=en |volume=60 |issue=4 |pages=2797–2804 |doi=10.1021/acs.inorgchem.0c03699 |pmid=33496171 |s2cid=231710405 |issn=0020-1669|url-access=subscription }}

|3,5-MePyC₂²⁺SbBr₅

|monoclinic

|P2/n

|a 6.2898 b 8.7454 c 20.408 β 90.438°

|

|

|

|

|(C₂Py)₂[Sb₂Br₁₀]

|triclinic

|P{{overbar|1}}

|a 6.1343 b 9.2857 c 17.2041 α 90.331° β 100.259° γ 99.912°

|

|

|

|

|(C₂Py)₂[Sb₂Br₁₀]

|monoclinic

|C2/c

|a 19.6880 b 10.0152 c 20.8410 β 111.104°

|

|

|

|

|(3,5-MePy){[SbBr₄]}

|monoclinic

|P2₁/n

|a 20.5536 b 7.2974 c 21.2510 β 117.694°

|

|

|

|

|(PyC₃)₂[Sb₂Br₉][SbBr₆]

|orthorhombic

|Pmmm

|a=20.3785 b=15.5018 c=7.4618 Z=2

|2357.2

|

|mixed III V valence

|

|(PyC₄){[SbBr₆](Br₃)}

|triclinic

|P{{overbar|1}}

|a=7.8627 b=9.1285 c=10.1514 α=68.392° β=89.669° γ=72.048° Z=1

|639.63

|

|

|

|(4−CH₃CH₂C₅H₄NH)₃Sb₂Br₁₄

|orthorhombic

|Pna2₁

|Z=4

|

|2.55

|black; orange-red at −174°

|

|(4-MePyC₃)₂[SbBr₆]₂[Br₅]₂

|monoclinic

|P2₁/n

|a=7.7157 b=16.1786 c=24.292 β=96.972°

|

|

|Sb(V)

|{{Cite journal |last1=Bondarenko |first1=Mikhail A. |last2=Novikov |first2=Alexander S. |last3=Fedin |first3=Vladimir P. |last4=Sokolov |first4=Maxim N. |last5=Adonin |first5=Sergey A. |date=2020-11-16 |title=The stabilization of decabromide {Br 10 } 2− anion in the structure of Sb(V) bromide complex |url=https://www.tandfonline.com/doi/full/10.1080/00958972.2020.1837785 |journal=Journal of Coordination Chemistry |language=en |volume=73 |issue=20–22 |pages=3038–3043 |doi=10.1080/00958972.2020.1837785 |s2cid=228993870 |issn=0095-8972|url-access=subscription }}

|(3-MePyC₃)₃[Sb4Br16]

|monoclinic

|P2₁/n

|a 11.6777 b 42.282 c 16.5504 β 95.618°

|

|

|

|{{Cite journal |last1=Usol’tsev |first1=A. N. |last2=Sokolov |first2=M. N. |last3=Fedin |first3=V. P. |last4=Adonin |first4=S. A. |date=June 2021 |title=Bi- and Tetranuclear Antimony(III) Bromide Complexes with Alkanediyl-bis(3-methylpyridinium) Cations |url=https://link.springer.com/10.1134/S003602362106019X |journal=Russian Journal of Inorganic Chemistry |language=en |volume=66 |issue=6 |pages=827–833 |doi=10.1134/S003602362106019X |s2cid=235663960 |issn=0036-0236|url-access=subscription }}

|(3-MePyC₂)₃[Sb₂Br₉]₂

|triclinic

|P{{overbar|1}}

|a 10.6368 b 10.8059 c 15.4810 α 76.034° β 81.735° γ 83.387°

|

|

|

|

|(3-MePyC₄)₃[Sb4Br₁₆]

|monoclinic

|P2₁/n

|a 14.2410 b 11.2731 c 19.0662 β 110.674°

|

|

|

|

|(4-MePyC₄)[Sb₂Br₈]

|monoclinic

|P 2/c

|a 26.313 b 6.4010 c 17.9886 β 109.026°

|

|

|

|{{Cite journal |last1=Usol’tsev |first1=A. N. |last2=Petrov |first2=M. D. |last3=Korol’kov |first3=I. V. |last4=Sokolov |first4=M. N. |last5=Blatov |first5=V. A. |last6=Adonin |first6=S. A. |date=September 2021 |title=Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity |url=https://link.springer.com/10.1134/S107032842108008X |journal=Russian Journal of Coordination Chemistry |language=en |volume=47 |issue=9 |pages=620–625 |doi=10.1134/S107032842108008X |s2cid=237474819 |issn=1070-3284|url-access=subscription }}

|(4-MePyC₄)₂[Sb₄Br₁₆]

|monoclinic

|P2₁/n

|a 11.4661 b 19.7236 c 12.5217 β 92.726°

|

|

|

|

|1,3,4-MePy[SbBr₆]

|triclinic

|P{{overbar|1}}

|a 8.3195 b 8.9921 c 12.3360 α 86.146° β 76.520° γ 71.872°

|

|

|Sb(V)

|{{Cite journal |last1=Adonin |first1=Sergey A. |last2=Bondarenko |first2=Mikhail A. |last3=Novikov |first3=Alexander S. |last4=Plyusnin |first4=Pavel E. |last5=Korolkov |first5=Ilya V. |last6=Sokolov |first6=Maxim N. |last7=Fedin |first7=Vladimir P. |date=March 2020 |title=Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state |url=https://linkinghub.elsevier.com/retrieve/pii/S0020169319313532 |journal=Inorganica Chimica Acta |language=en |volume=502 |pages=119278 |doi=10.1016/j.ica.2019.119278|s2cid=209721773 |url-access=subscription }}

|1,4-MePy[SbBr₆]

|triclinic

|P{{overbar|1}}

|a 7.6803 b 8.5900 c 12.6261 α 75.226° β 88.079° γ 79.872°

|

|

|Sb(V)

|

|(1,2-MePy)₂[SbBr₆](Br₃)

|monoclinic

|P2₁/n

|a=7.3284 b=10.5875 c=16.7538 β=96.005°

|

|

|Sb(V)

|

|(1,3-MePy)₂[SbBr₆](Br₃)

|triclinic

|P{{overbar|1}}

|a 7.2611 b 9.086 c 11.1895 α 67.617° β 87.457° γ 72.16°

|

|

|

| (5)

|?

|orthorhombic

|Pmmn

|a=12.06 b=12.97 c=11.49

|1797

|2.2

|yellow

|

|(2,6-MePy)₃[Sb₂Br₉]

|monoclinic

|P2₁/c

|a=12.10 b=15.56 c=21.27 β=115.7 Z=4°

|3629

|2.36

|pale yellow

|

|(1-Et-3-MePy)₂[SbBr₆](Br₃)

|triclinic

|P{{overbar|1}}

|a 7.2472 b 9.4088 c 11.5541 α 69.263° β 81.162° γ 71.303°

|

|

|

|

|(4-Et-1-MePy)₂[SbBr₆](Br₃)

|monoclinic

|P2₁/n

|a 8.4645 b 13.0802 c 13.1574 β 105.702°

|

|

|

|

|(2,6-MePy)₂[SbBr₆](Br₅)

|monoclinic

|P2₁/c

|a 7.4584 b 18.0860 c 21.626 β 93.607° Z=4

|2911.4

|

|

| (3)

|(1,3,5-MePy)₂[SbBr₆](Br₃)

|triclinic

|P{{overbar|1}}

|a 8.1964 b 8.2015 c 12.5202 α 92.883° β 103.923° γ 115.467° Z=4

|1085.3

|

|100K

| (4)

|(2,4,6-MePy)₃[Sb₂Br₉]

|monoclinic

|P2₁/n

|a=10.36 b=42.36 c=9.09 β=100.2° Z=4

|3926

|2.25

|yellow-tan

|

|(2,4,6-MePy)[SbBr]•0.5Br₂

|monoclinic

|P2₁/n

|a 10.4938 b 13.6198 c 12.8807 β 90.339° Z=4

|1840.9

|

|100k

| (5)

|(3,5--MePy)₂[SbBr₆](Br₃)

|orthorhombic

|Pnnm

|a 17.1097 b 10.4401 c 7.3438 Z=2

|1311.8

|

|

| (2)

|(1-Et-3-MePy)₂[SbBr₆](Br₃)

|triclinic

|P{{overbar|1}}

|a 7.2472 b 9.4088 c 11.5541 α 69.263° β 81.162° γ 71.303°

|

|

|

|

|(1-Et-4-MePy)₂[SbBr₆](Br₃)

|monoclinic

|P2₁/n

|a=11.4927 b=7.3613 c=16.9266 β=100.782°

|

|

|Sb(V)

|

|(1-Et-2-MePy)₂[SbBr₆](Br₃)

|monoclinic

|P2₁/n

|a=8.3421 b=13.196 c=13.183 β=105.40°

|

|

|Sb(V)

|

|(1-Et-2,6-MePy)[SbBr₆]

|monoclinic

|P2₁/c

|a 9.9470 b 11.5017 c 16.4632 β 107.201°

|

|

|

|

|

|

|

|

|

|

|{{Cite journal |last1=Usoltsev |first1=A. N. |last2=Korol’kov |first2=I. V. |last3=Adonin |first3=S. A. |date=June 2023 |title=Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes |url=https://link.springer.com/10.1134/S1070328423700598 |journal=Russian Journal of Coordination Chemistry |language=en |volume=49 |issue=6 |pages=345–349 |doi=10.1134/S1070328423700598 |s2cid=259254579 |issn=1070-3284|url-access=subscription }}

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|

|C₆H₅CH₂PySbBr₆

|orthorhombic

|Pnma

|a=12.6594 b=17.3414 c=8.6389 Z=4

|1896.5

|

|

| (6)

|(CH₃-C₆H₅CH₂Py)₂SbBr₆(Br₃)

|triclinic

|P{{overbar|1}}

|a 8.9834 b 10.2599 c 10.3601 α 94.223° β 102.737° γ 111.846°

|

|

|

| (7)

|(BrC₆H₄CH₂Py)₂SbBr₆(Br₃)

|monoclinic

|P2₁/c

|a 8.6483 b 15.1885 c 13.3520 β 98.887°

|

|

|

|

|(2,2'-C₁₀H₈N₂H₂)SbBr₅

|monoclinic

|P2₁/c

|a = 14.575 b = 14.726 c = 16.775 β = 110.34° Z = 8

|

|

|

|{{Cite journal |last1=Ishihara |first1=Hideta |last2=Dou |first2=Shi-Qi |last3=Weiss |first3=Alarich |date=June 1991 |title=The Mutual Influence of Ligands in Sb(III) Complex Salts. An X-Ray Diffraction and NQR Study |url=https://onlinelibrary.wiley.com/doi/10.1002/bbpc.19910950602 |journal=Berichte der Bunsengesellschaft für physikalische Chemie |language=en |volume=95 |issue=6 |pages=659–670 |doi=10.1002/bbpc.19910950602|url-access=subscription }}

|(4,4'-C₁₀H₈N₂H₂)SbBr₅

|triclinic

|P1

|a = 11.28.7 b = 10.121 c = 8.548 α = 98.94° β = 101.06° γ = 113.57° Z = 2

|

|

|

|

|(C₃N₂H₅)₃SbBr₆.H₂O

|monoclinic

|P2₁/c

|a=8.9137 b=19.2032 c=12.7984 β=90.650°

|

|

|

|{{Cite journal |last1=Piecha |first1=A. |last2=Gągor |first2=A. |last3=Pietraszko |first3=A. |last4=Jakubas |first4=R. |date=December 2010 |title=Unprecedented solid-state chemical reaction—from . From centrosymmetric to non-centrosymmetric crystal structure |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459610004779 |journal=Journal of Solid State Chemistry |language=en |volume=183 |issue=12 |pages=3058–3066 |doi=10.1016/j.jssc.2010.10.020|url-access=subscription }}

|(C₃N₂H₅)₅Sb₂Br₁₁

|monoclinic

|P2₁/n

|a 9.1399 b 15.150 c 13.969 β 96.19°

|

|

|ferroelectric Curie Point 145K; 4 phases

|{{Cite journal |last1=Piecha |first1=A. |last2=Pietraszko |first2=A. |last3=Bator |first3=G. |last4=Jakubas |first4=R. |date=May 2008 |title=Structural characterization and ferroelectric ordering in (C3N2H5)5Sb2Br11 |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459608001047 |journal=Journal of Solid State Chemistry |language=en |volume=181 |issue=5 |pages=1155–1166 |doi=10.1016/j.jssc.2008.02.029|bibcode=2008JSSCh.181.1155P |url-access=subscription }}

|(C₃H₄NS)₆Sb₄Br₁₈·2H₂O

|triclinic

|P{{overbar|1}}

|a 11.060 b 11.465 c 12.957 α 116.21° β 100.71° γ 98.87°

|

|

|

|{{Cite journal |last1=Piecha |first1=A. |last2=Jakubas |first2=R. |last3=Kinzhybalo |first3=V. |last4=Medycki |first4=W. |date=April 2012 |title=Crystal structure, dielectric properties and molecular motions of molecules in thiazolium halometalates(III): (C3H4NS)6M4Br18·2H2O (M=Sb, Bi) |url=https://linkinghub.elsevier.com/retrieve/pii/S0022286012000415 |journal=Journal of Molecular Structure |language=en |volume=1013 |pages=55–60 |doi=10.1016/j.molstruc.2012.01.014|bibcode=2012JMoSt1013...55P |url-access=subscription }}

|

|monoclinic

|Cc

|a=15.28 b=14.04 c=7.44 β =118.3 Z=4

|1405

|2.70

|light yellow

|

|(C₉H₇NH)₂SbBr₉

|monoclinic

|P2₁/n

|as=7.518 b=11.316 c=16.351 β =97.41 Z=2

|

|

|Sb(V)

|{{Cite journal |last=McAfee |first=Elwin Ray |date=1970-11-01 |title=The crystal structure of quinolinium nonabromoantimonate (V), (C9H7NH)2SbVBr9 and the refinement of the molecular structure of beta-picoline-n-oxide fumaric acid adduct |doi=10.2172/4036792 |osti=4036792 |url=https://www.osti.gov/biblio/4036792 |language=English}}

|(3-BrQuinH)₄[Sb₂Br₁₀]

|monoclinic

|C2/c

|a 15.3947 b 13.7967 c 22.8880 β 92.039°

|

|

|

|{{Cite journal |last1=Shentseva |first1=Irina A. |last2=Korobeynikov |first2=Nikita A. |last3=Usoltsev |first3=Andrey N. |last4=Gorokh |first4=Igor D. |last5=Novikov |first5=Alexander S. |last6=Korolkov |first6=Ilya V. |last7=Sokolov |first7=Maxim N. |last8=Adonin |first8=Sergey A. |date=June 2023 |title=Haloantimonate(III) complexes with halogen-substituted quinolinium cations: structural features of non-covalent interactions in solid state |url=https://linkinghub.elsevier.com/retrieve/pii/S0277538723002279 |journal=Polyhedron |volume=242 |language=en |pages=116505 |doi=10.1016/j.poly.2023.116505|s2cid=259796849 |url-access=subscription }} 2

|(5-BrQuinH)₂[SbBr₅]

|monoclinic

|C2/c

|a 23.8681 b 12.2567 c 8.6474 β 106.128°

|

|

|

| 3

|(1-Me-3-BrQuin)₃[Sb₃Br₁₂]

|triclinic

|P{{overbar|1}}

|a 9.8582 b 11.7183 c 21.6576, α 98.981° β 96.402° γ 92.371°

|

|

|

| 5

|isoquinHSbBr₄

|monoclinic

|P2₁/a

|a=13.11 b=14.14 c=7.57 β=91.4 Z=4

|1403

|2.71

|light tan

|

|(N-MeQuin)₂{[SbBr₆](Br₃)}

|triclinic

|P{{overbar|1}}

|a=8.0902 b=8.5656 c=11.6475 𝛼 = 68.901° β = 79.204° 𝛾 = 77.120° Z=1

|728.98

|

|

|{{Cite journal |last1=Adonin |first1=Sergey A. |last2=Bondarenko |first2=Mikhail A. |last3=Novikov |first3=Alexander S. |last4=Abramov |first4=Pavel A. |last5=Plyusnin |first5=Pavel E. |last6=Sokolov |first6=Maxim N. |last7=Fedin |first7=Vladimir P. |date=2019-10-14 |title=Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Frameworks: Antimony(V) Bromide and Polybromide Complexes with N-alkylated Quinolinium or Isoquinolinium Cations: Substituent-dependent Assembly of Polymeric Fram |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201900165 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=645 |issue=18–19 |pages=1141–1145 |doi=10.1002/zaac.201900165|s2cid=204138784 |url-access=subscription }}

|(N-MeIsoquin)₂{[SbBr₆](Br₃)}

|monoclinic

|P2₁/c

|a=12.9656 b=9.3423 c=12.5920 β = 107.233° Z=2

|1456.8

|

|

|

|(N-EtQuin)[SbBr₆]

|orthorhombic

|Pnma

|a=14.5122 b=11.4005 c=11.2135° Z=4

|1855.2

|

|

|

|(6-MeQuin)₃[SbBr₆]

|

|

|

|

|

|

|{{Cite journal |last=Bukvetskiǐ B.V., Storozhuk T.V., Mirochnik A.G., Petrochenkova N.V., Karasev V.E. |date=2004 |title=CИНТЕЗ, КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА И СПЕКТРАЛЬНОЛЮМИНЕСЦЕНТНЫЕ СВОЙСТВА КОМПЛЕКСНЫХ СОЕДИНЕНИЙ ГАЛОГЕНИДОВ СУРЬМЫ(III) С 6-МЕТИЛХИНОЛИНОМ |trans-title=SYNTHESIS, CRYSTAL STRUCTURE, AND LUMINESCENT PROPERTIES OF ANTIMONY(III) HALIDE COMPLEXES WITH 6-METHYLQUINOLINE |journal=Russian Journal of Inorganic Chemistry |volume=49 |issue=1 |pages=43–50}}

|SbBr₅(boxH)₂

|triclinic

|P{{overbar|1}}

|a=8.560 b=11.008 c=12.751 α=102.836° β=106.173° γ=93.398°

|

|

|

|{{Cite journal |last1=Ly |first1=Kathy |last2=May |first2=Kathleen L. |last3=Lough |first3=Alan J. |last4=Zhu |first4=Jianfeng |last5=Quail |first5=J. Wilson |last6=Gossage |first6=Robert A. |date=February 2023 |title=Synthesis and structural characterisation of trivalent halidoantimonates and bismuthates of 2-methyl-2-benzoxazole (box): Reactivity and solid-state structural diversity within the [MX(6 – n)] [boxH](3 – n) series (M = Sb or Bi; X = Cl, Br, I; n = 0 or 1) |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459622007782 |journal=Journal of Solid State Chemistry |language=en |volume=318 |pages=123653 |doi=10.1016/j.jssc.2022.123653|bibcode=2023JSSCh.31823653L |url-access=subscription }}

|(C₉H₇NH)₂Sb^VBr₉

|monoclinic

|P2₁/n

|a=7.518 b=11.316 c=16.351 β=97.41° Z=2

|

|2.67

|red

|{{Cite journal |last1=Lawton |first1=Stephen L. |last2=McAfee |first2=Elwin Ray |last3=Benson |first3=James E. |last4=Jacobson |first4=Robert A. |date=December 1973 |title=Crystal structure of quinolinium hexabromoantimonate(V) tribromide, (C9H7NH)2SbVBr9 |url=https://pubs.acs.org/doi/abs/10.1021/ic50130a040 |journal=Inorganic Chemistry |language=en |volume=12 |issue=12 |pages=2939–2944 |doi=10.1021/ic50130a040 |issn=0020-1669|url-access=subscription }}

|(C₇H₁₃NH)₄Sb^IIISb^VBr₁₂.2Br₂

|cubic

|Fm3m

|a=13.873

|2670

|2.45

|black

|{{Cite journal |last1=Lawton |first1=Stephen L. |last2=Jacobson |first2=Robert A. |date=April 1971 |title=Crystal structure of quinuclidinium dodecarbromoantimon(III)antimonate(V)-2-dibromine, (C7H13NH)4Sb(III)Sb(V)Br12.2Br2 |url=https://pubs.acs.org/doi/abs/10.1021/ic50098a010 |journal=Inorganic Chemistry |language=en |volume=10 |issue=4 |pages=709–712 |doi=10.1021/ic50098a010 |issn=0020-1669|url-access=subscription }}

|[C₆H₁₃N₃]²⁺[SbBr₅]²⁻

|orthorhombic

|P2₁2₁2₁

|8.7120 b = 12.6608 c = 14.3498 Z = 4

|

|

|

|{{Cite journal |last1=Taher |first1=Marwa Ben |last2=Chaari |first2=Najla |last3=Bechir |first3=Mohamed Ben |last4=Chaabouni |first4=Slaheddine |date=April 2017 |title=X-ray diffraction, vibrational properties, and dielectric studies of 3-ammoniumpropyl imidazolium pentabromoantimonate (III) |url=http://link.springer.com/10.1007/s00339-017-0895-4 |journal=Applied Physics A |language=en |volume=123 |issue=4 |page=285 |doi=10.1007/s00339-017-0895-4 |bibcode=2017ApPhA.123..285T |s2cid=253852282 |issn=0947-8396|url-access=subscription }}

|(H₃O)₃Sb₂Br₉

|monoclinic

|P2₁/n

|a = 13.4679 b = 7.6319 c = 19.1397 β = 90.240° Z=4

|1967.3

|3.443

|yellow

|{{Cite journal |last1=Chang |first1=Jen-Hui |last2=Doert |first2=Thomas |last3=Ruck |first3=Michael |date=2016-12-01 |title=(H 3 O) 3 Sb 2 Br 9 : the first member of the M 3 E 2 X 9 structure family with oxonium cations |url=https://scripts.iucr.org/cgi-bin/paper?S2053229616017198 |journal=Acta Crystallographica Section C Structural Chemistry |volume=72 |issue=12 |pages=966–970 |doi=10.1107/S2053229616017198 |pmid=27918298 |issn=2053-2296|url-access=subscription }}

|HSbBr₆ · 3H₂O

|monoclinic

|P2₁/c

|a = 7.110 b = 13.532 c = 12.846 β = 94.87 Z=4

|

|

|melt 330K

|{{Cite journal |last1=Henke |first1=H. |last2=Kuhs |first2=W. F. |date=1987-12-01 |title=The protonated water complex H 14 O 6 2+: A neutron diffraction study of HSbBr 6 · 3H 2 O |url=https://www.degruyter.com/document/doi/10.1524/zkri.1987.181.14.113/html |journal=Zeitschrift für Kristallographie - Crystalline Materials |language=en |volume=181 |issue=1–4 |pages=113–126 |doi=10.1524/zkri.1987.181.14.113 |s2cid=101332631 |issn=2196-7105|url-access=subscription }}

|[(CH₃)₄P]₃[Sb₂Br₉]

|hexagonal

|P3₁/c

|a 9.7931 c 22.697

|

|

|deep yellow

|{{Cite journal |last1=Wojtaś |first1=M. |last2=Jakubas |first2=R. |last3=Ciunik |first3=Z. |last4=Medycki |first4=W. |date=April 2004 |title=Structure and phase transitions in [(CH3)4P]3[Sb2Br9] and [(CH3)4P]3[Bi2Br9] |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459603006728 |journal=Journal of Solid State Chemistry |language=en |volume=177 |issue=4–5 |pages=1575–1584 |doi=10.1016/j.jssc.2003.12.011|bibcode=2004JSSCh.177.1575W |url-access=subscription }}

|[(CH₃)₃PH][SbBr₄]

|monoclinic

|P2₁/c

|a=10.9103 b=19.8342 c=11.3617 β=100.744 Z=4

|2415.54

|2.851

|colourless

|{{Cite journal |last1=Wojtaś |first1=Maciej |last2=Bil |first2=Andrzej |last3=Ga̧gor |first3=Anna |last4=Medycki |first4=Wojciech |last5=Kholkin |first5=Andrei L. |date=2016 |title=Phase stability and dynamics of hybrid organic–inorganic crystals [(CH 3 ) 3 PH][SbCl 4 ] and [(CH 3 ) 3 PH][SbBr 4 ]: a computational and NMR approach |url=http://xlink.rsc.org/?DOI=C6CE00160B |journal=CrystEngComm |language=en |volume=18 |issue=14 |pages=2413–2424 |doi=10.1039/C6CE00160B |issn=1466-8033|url-access=subscription }}

|(MTP)₆SbBr₆Sb₂Br₉⋅H₂O

|trigonal

|R3

|a=19.7793 c=27.2770 Z=3

|9241

|1.749

|

|{{Cite journal |last1=Li |first1=Bohan |last2=Jin |first2=Jiance |last3=Yin |first3=Meijuan |last4=Zhang |first4=Xinlei |last5=Molokeev |first5=Maxim S. |last6=Xia |first6=Zhiguo |last7=Xu |first7=Yan |date=2022-12-05 |title=Sequential and Reversible Phase Transformations in Zero-Dimensional Organic-Inorganic Hybrid Sb-based Halides towards Multiple Emissions |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.202212741 |journal=Angewandte Chemie International Edition |language=en |volume=61 |issue=49 |pages=e202212741 |doi=10.1002/anie.202212741 |pmid=36207278 |s2cid=252758576 |issn=1433-7851|url-access=subscription }}

|(MTP)₂SbBr₅

|monoclinic

|P2₁/c

|a=12.7399 b=12.3833 c=26.0206 β=96.373 Z=4

|4079.7

|1.752

|

|

|P(C₆H₅)₄SbBr₆

|monoclinic

|C2/c

|a = 16.887 b = 7.357 c = 23.367 β = 93.98° Z=4

|2896.1

|

|yellow

|{{Cite journal |last1=Czado |first1=Wolfgang |last2=Müller |first2=Ulrich |date=December 2002 |title=Crystal structure of tetraphenylphosphonium hexabromoantimonate(V), P(C6H5)4SbBr6 |url=https://www.degruyter.com/document/doi/10.1524/ncrs.2002.217.jg.337/html |journal=Zeitschrift für Kristallographie - New Crystal Structures |volume=217 |issue=JG |pages=337–338 |doi=10.1524/ncrs.2002.217.jg.337 |s2cid=98343578 |issn=2197-4578|url-access=subscription }}

|TPPcarzSbBr₄

|triclinic

|P{{overbar|1}}

|a=9.77183 b=11.42472 16.15939 α=88.2199° β=80.7810° γ=71.8474°, Z = 2

|1691.77

|1.857

|red LED

|

|(PPh₄)₄Sb₈Br₂₈

|triclinic

|P{{overbar|1}}

|a=12.491 b=13.078 c=21.523 α=102.93° β=100.83° γ= 100.42°, Z = 2

|3273

|2.318

|

|{{Cite journal |last1=Fachbereich Biologie-Chemie, Universität Gh, D- Kassel |first1=Wolfgang |last2=Fachbereich Biologie-Chemie, Universität Gh, D- Kassel |first2=Ulrich |date=1996-09-01 |title=Tetraphenylphosphonium-ikosioctabromooctaantimonat(III), (PPh 4 ) 4 Sb 8 Br 28 / Tetraphenylphosphonium Ikosioctabromooctaantimonate(III), (PPh 4 ) 4 Sb 8 Br 28 |journal=Zeitschrift für Naturforschung B |language=en |volume=51 |issue=9 |pages=1245–1247 |doi=10.1515/znb-1996-0906 |s2cid=201092106 |issn=1865-7117|doi-access=free }}

|[C(NP(Br_0,78Cl_0,22)₃)₃]SbBr₆

|orthorhombic

|Pbca

|a = 27.92 b = 11.23 c = 17.54 Z = 8

|

|

|

|

|monoclinic

|P2₁/n

|

|

|

|

|{{Cite journal |last=Wheeler |first=H. L. |date=1893-10-01 |title=On the double halides of antimony with rubidium |url=https://ajs.scholasticahq.com/article/62893 |journal=American Journal of Science |language=en |volume=s3-46 |issue=274 |pages=269–279 |doi=10.2475/ajs.s3-46.274.269 |bibcode=1893AmJS...46..269W |s2cid=130685803 |issn=0002-9599}}{{Cite book |last1=Brik |first1=Mikhail G. |url=https://books.google.com/books?id=bEKwEAAAQBAJ&pg=PA102 |title=Luminescent Materials: Fundamentals and Applications |last2=Srivastava |first2=Alok M. |date=2023-03-06 |publisher=Walter de Gruyter GmbH & Co KG |isbn=978-3-11-060787-1 |pages=102 |language=en}}

|tetragonal

|I4₁/amd

|a = 10.70 and c = 21.69 Z=8

|

|4.17

|black

|{{Cite journal |last1=Ephraim |first1=Fritz |last2=Weinberg |first2=S. |date=November 1909 |title=Doppelhalogenide des drei-, vier- und fünfwertigen Antimons |url=https://onlinelibrary.wiley.com/doi/10.1002/cber.19090420441 |journal=Berichte der Deutschen Chemischen Gesellschaft |language=en |volume=42 |issue=4 |pages=4447–4456 |doi=10.1002/cber.19090420441 |issn=0365-9496}}{{Cite journal |last1=Hubbard |first1=Camden |last2=Jacobson |first2=Robert |date=1968-01-01 |title=The Crystal Structure of Rb4SbIIISbvBr12 |url=https://scholarworks.uni.edu/pias/vol75/iss1/16 |journal=Proceedings of the Iowa Academy of Science |volume=75 |issue=1 |pages=85–96 |issn=0085-2236}}

|orthorhombic

|Cmcm

|a = 23.4716 b = 13.57.89 c = 35.3947

|

|

|yellow

|{{Cite journal |last1=Chang |first1=Jen-Hui |last2=Doert |first2=Thomas |last3=Ruck |first3=Michael |date=2020-09-25 |title=The crystal structures of α -Rb 7 Sb 3 Br 16 , α - and β -Tl 7 Bi 3 Br 16 and their relationship to close packings of spheres |url=https://www.degruyter.com/document/doi/10.1515/zkri-2020-0013/html |journal=Zeitschrift für Kristallographie - Crystalline Materials |language=en |volume=235 |issue=8–9 |pages=255–261 |doi=10.1515/zkri-2020-0013 |s2cid=222005314 |issn=2196-7105|url-access=subscription }}

|monoclinic

|P2₁/c

|a=12.021 b=22.454 c=26.372 β=92.506° Z=8

|7112

|2.634

|light orange

|{{Cite journal |last1=Mikhailov |first1=Artem |last2=Korobeynikov |first2=Nikita |last3=Usoltsev |first3=Andrey |last4=Adonin |first4=Sergey A. |last5=Kostin |first5=Gennadiy A. |last6=Schaniel |first6=Dominik |date=2023 |title=Bismuth and antimony halometalates containing photoswitchable ruthenium nitrosyl complexes |url=http://xlink.rsc.org/?DOI=D2DT03497B |journal=Dalton Transactions |language=en |volume=52 |issue=4 |pages=919–927 |doi=10.1039/D2DT03497B |pmid=36594625 |s2cid=254902411 |issn=1477-9226}}

|(C₈H₂₀N₂)₂AgMBr₈

|triclinic

|P{{overbar|1}}

|a 8.0820 b 8.161 c 11.814 α 90.185° β 95.390° γ 90.121°

|

|

|band gap 2.600 eV

|{{Cite journal |last1=Ruan |first1=Hang |last2=Guo |first2=Zhongnan |last3=Lin |first3=Jiawei |last4=Liu |first4=Kunjie |last5=Guo |first5=Lingling |last6=Chen |first6=Xin |last7=Zhao |first7=Jing |last8=Liu |first8=Quanlin |last9=Yuan |first9=Wenxia |date=2021-10-04 |title=Structure and Optical Properties of Hybrid-Layered-Double Perovskites (C 8 H 20 N 2 ) 2 AgMBr 8 (M = In, Sb, and Bi) |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c01669 |journal=Inorganic Chemistry |language=en |volume=60 |issue=19 |pages=14629–14635 |doi=10.1021/acs.inorgchem.1c01669 |pmid=34523334 |s2cid=237514261 |issn=0020-1669|url-access=subscription }}

|(HIS)₂AgSbBr₈

|monoclinic

|C2/c

|a=11.5632 b=12.2529 c=18.694 β=94.264 Z=4

|2641.3

|2.754

|semiconductor; pale yellow

|

|

|

|a=7.9165 c=9.7139

|

|

|yellow; orange at 300°C; perovskite

|{{Cite journal |last1=Zhang |first1=Jian |last2=Yang |first2=Ying |last3=Deng |first3=Hui |last4=Farooq |first4=Umar |last5=Yang |first5=Xiaokun |last6=Khan |first6=Jahangeer |last7=Tang |first7=Jiang |last8=Song |first8=Haisheng |date=2017-09-26 |title=High Quantum Yield Blue Emission from Lead-Free Inorganic Antimony Halide Perovskite Colloidal Quantum Dots |url=https://pubs.acs.org/doi/10.1021/acsnano.7b04683 |journal=ACS Nano |language=en |volume=11 |issue=9 |pages=9294–9302 |doi=10.1021/acsnano.7b04683 |pmid=28880532 |issn=1936-0851|url-access=subscription }}

|tetragonal

|I4₁/amd

|a=10.842 c=21.913 Z=2

|2576

|

|black @300K

|{{Cite journal |last1=Combs |first1=Victoria E. |last2=Oswald |first2=Iain W. H. |last3=Neilson |first3=James R. |date=2019-07-03 |title=Hydrothermal Crystal Growth of Mixed Valence Cs 2 SbBr 6 |url=https://pubs.acs.org/doi/10.1021/acs.cgd.9b00481 |journal=Crystal Growth & Design |language=en |volume=19 |issue=7 |pages=4090–4094 |doi=10.1021/acs.cgd.9b00481 |s2cid=191147344 |issn=1528-7483|url-access=subscription }}

|cubic

|Fm{{overbar|3}}m

|a = 11.1583 Z=4

|1389.2

|4.661

|black; bandgap 1.64 eV

|{{Cite journal |last1=Wei |first1=Fengxia |last2=Deng |first2=Zeyu |last3=Sun |first3=Shijing |last4=Hartono |first4=Noor Titan Putri |last5=Seng |first5=Hwee Leng |last6=Buonassisi |first6=Tonio |last7=Bristowe |first7=Paul D. |last8=Cheetham |first8=Anthony K. |date=2019 |title=Enhanced visible light absorption for lead-free double perovskite Cs 2 AgSbBr 6 |url=http://xlink.rsc.org/?DOI=C9CC01134J |journal=Chemical Communications |language=en |volume=55 |issue=26 |pages=3721–3724 |doi=10.1039/C9CC01134J |pmid=30869691 |s2cid=76665497 |issn=1359-7345|url-access=subscription }}

|(C₈NH₁₂)₄Bi_0.57Sb_0.43Br₇⋅H₂O

|triclinic

|P{{overbar|1}}

|a=13.0207 b=13.1304 c=13.3192 α=93.818° β=102.408° γ=108.610° Z=2

|2085.1

|1.971

|light green

|