Cadmium bromide
{{Chembox
| Watchedfields = changed
| verifiedrevid = 405682296
| Name = Cadmium bromide
| ImageFile =Cadmium-chloride-3D-balls.png
| ImageFile2 = Cadmium bromide tetrahydrate.jpg
| ImageName = Cadmium bromide
| IUPACName = Cadmium(II) bromide
| OtherNames = Cadmium dibromide
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23011
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 7726AXS0WH
| EINECS = 232-165-1
| InChI = 1/2BrH.Cd/h2*1H;/q;;+2/p-2
| SMILES = Br[Cd]Br
| InChIKey = KPWJBEFBFLRCLH-NUQVWONBAB
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2BrH.Cd/h2*1H;/q;;+2/p-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = KPWJBEFBFLRCLH-UHFFFAOYSA-L
| CASNo = 7789-42-6
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo_Comment =
| CASNo2 = 13464-92-1
| CASNo2_Comment = (tetrahydrate)
| CASNo2_Ref = {{cascite|correct|CAS}}
| RTECS = EU9935000
| PubChem = 24609
}}
|Section2={{Chembox Properties
| Formula = CdBr2
| MolarMass = 272.22 g/mol
| Appearance = white solid
| Density = 5.192 g/cm3, solid
| Solubility = 56.3 g/100 mL (0 °C)
98.8 g/100 mL (20 °C)
160 g/100 mL (100 °C)
| SolubleOther = soluble in alcohol, ether, acetone and liquid ammonia.
| MeltingPtC = 568
| MeltingPt_notes =
| BoilingPtC = 844
| BoilingPt_notes =
| MagSus = −87.3·10−6 cm3/mol
}}
|Section3={{Chembox Structure
| CrystalStruct = Rhombohedral, hr9, SpaceGroup = R-3m, No. 166
}}
|Section7={{Chembox Hazards
| ExternalSDS =
| GHSPictograms = {{GHS07}}{{GHS09}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|302|312|332|410}}
| PPhrases = {{P-phrases|220|273|280|501}}
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 0
| LD50 = 225 mg/kg, oral (rat)
| REL = Ca{{PGCH|0087}}
| PEL = [1910.1027] TWA 0.005 mg/m3 (as Cd)
}}
|Section8={{Chembox Related
| OtherAnions = Cadmium chloride,
Cadmium iodide
| OtherCations = Zinc bromide,
Calcium bromide,
Magnesium bromide
}}
}}
Cadmium bromide is the inorganic compound with the formula CdBr2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate. It has few applications.
Preparation and structure
Cadmium bromide is prepared by heating cadmium with bromine vapor.{{cite book|author1=F. Wagenknecht|author2=R. Juza|chapter=Cadmium bromide|title=Handbook of Preparative Inorganic Chemistry, 2nd Ed. |editor=G. Brauer|publisher=Academic Press|year=1963|place=NY, NY|volume=2|pages=1096}} The tetrahydrate has been obtained by crystallization of the dibromide from aqueous solution. At 3.04 g/cm3, it is much less dense than the anhydrous material. According to X-ray crystallography, the tetrahydrate is a polymer of CdBr2(H2O)2 with bridging bromide ligands. There are two interstitial water molecules{{cite journal |doi=10.1107/S0567740878002186 |title=Structure Cristalline de CdBr2.4H2O |date=1978 |last1=Leligny |first1=H. |last2=Monier |first2=J. C. |journal=Acta Crystallographica Section B |volume=34 |issue=1 |pages=5–8 |bibcode=1978AcCrB..34....5L }}
References
{{Cadmium compounds}}
{{bromine compounds}}
Category:Photographic chemicals
{{inorganic-compound-stub}}