Cadmium bromide

{{Chembox

| Watchedfields = changed

| verifiedrevid = 405682296

| Name = Cadmium bromide

| ImageFile =Cadmium-chloride-3D-balls.png

| ImageFile2 = Cadmium bromide tetrahydrate.jpg

| ImageName = Cadmium bromide

| IUPACName = Cadmium(II) bromide

| OtherNames = Cadmium dibromide

|Section1={{Chembox Identifiers

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 23011

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = 7726AXS0WH

| EINECS = 232-165-1

| InChI = 1/2BrH.Cd/h2*1H;/q;;+2/p-2

| SMILES = Br[Cd]Br

| InChIKey = KPWJBEFBFLRCLH-NUQVWONBAB

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/2BrH.Cd/h2*1H;/q;;+2/p-2

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = KPWJBEFBFLRCLH-UHFFFAOYSA-L

| CASNo = 7789-42-6

| CASNo_Ref = {{cascite|correct|CAS}}

| CASNo_Comment =

| CASNo2 = 13464-92-1

| CASNo2_Comment = (tetrahydrate)

| CASNo2_Ref = {{cascite|correct|CAS}}

| RTECS = EU9935000

| PubChem = 24609

}}

|Section2={{Chembox Properties

| Formula = CdBr2

| MolarMass = 272.22 g/mol

| Appearance = white solid

| Density = 5.192 g/cm3, solid

| Solubility = 56.3 g/100 mL (0 °C)
98.8 g/100 mL (20 °C)
160 g/100 mL (100 °C)

| SolubleOther = soluble in alcohol, ether, acetone and liquid ammonia.

| MeltingPtC = 568

| MeltingPt_notes =

| BoilingPtC = 844

| BoilingPt_notes =

| MagSus = −87.3·10−6 cm3/mol

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|Section3={{Chembox Structure

| CrystalStruct = Rhombohedral, hr9, SpaceGroup = R-3m, No. 166

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|Section7={{Chembox Hazards

| ExternalSDS =

| GHSPictograms = {{GHS07}}{{GHS09}}

| GHSSignalWord = Warning

| HPhrases = {{H-phrases|302|312|332|410}}

| PPhrases = {{P-phrases|220|273|280|501}}

| NFPA-H = 3

| NFPA-F = 0

| NFPA-R = 0

| LD50 = 225 mg/kg, oral (rat)

| REL = Ca{{PGCH|0087}}

| PEL = [1910.1027] TWA 0.005 mg/m3 (as Cd)

| IDLH = Ca [9 mg/m3 (as Cd)]

}}

|Section8={{Chembox Related

| OtherAnions = Cadmium chloride,
Cadmium iodide

| OtherCations = Zinc bromide,
Calcium bromide,
Magnesium bromide

}}

}}

Cadmium bromide is the inorganic compound with the formula CdBr2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate. It has few applications.

Preparation and structure

Cadmium bromide is prepared by heating cadmium with bromine vapor.{{cite book|author1=F. Wagenknecht|author2=R. Juza|chapter=Cadmium bromide|title=Handbook of Preparative Inorganic Chemistry, 2nd Ed. |editor=G. Brauer|publisher=Academic Press|year=1963|place=NY, NY|volume=2|pages=1096}} The tetrahydrate has been obtained by crystallization of the dibromide from aqueous solution. At 3.04 g/cm3, it is much less dense than the anhydrous material. According to X-ray crystallography, the tetrahydrate is a polymer of CdBr2(H2O)2 with bridging bromide ligands. There are two interstitial water molecules{{cite journal |doi=10.1107/S0567740878002186 |title=Structure Cristalline de CdBr2.4H2O |date=1978 |last1=Leligny |first1=H. |last2=Monier |first2=J. C. |journal=Acta Crystallographica Section B |volume=34 |issue=1 |pages=5–8 |bibcode=1978AcCrB..34....5L }}

References

{{Cadmium compounds}}

{{bromine compounds}}

Category:Cadmium compounds

Category:Bromides

Category:Metal halides

Category:Photographic chemicals

{{inorganic-compound-stub}}