Clarkeite
{{Short description|Uranium oxide mineral}}
{{Infobox mineral
| name = Clarkeite
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| formula = {{chem|(Na|,Ca|,Pb)|2|(U|O|2|)|2|(O|,OH)|3}} or {{chem|(Na|,Ca|,Pb)|(U|O|2|)O|(OH)|•0-1H|2|O}}
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| strunz = 4.GC.05
| dana = 5.4.1.1
| system = Trigonal
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| symmetry = R{{overline|3}}m (No. 166)
| unit cell = 239.11 Å3 (Calculated from unit cell)
| colour = Dark red-brown, dark brown
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| cleavage = None observed
| fracture = Conchoidal, sub-conchoidal
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| mohs = 4–4.5
| luster = Resinous, waxy, greasy
| streak = Yellow-brown
| diaphaneity = Translucent
| gravity = 6.39
| density = 6.39 g/cm3 (Measured)
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| birefringence = 0.111
| pleochroism = Weak
| 2V = Measured 30° to 50°, Calculated 32°
| dispersion = Relatively weak
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| other = 25px Radioactive
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Clarkeite is a uranium oxide mineral with the chemical formula{{chem|(Na|,Ca|,Pb)|2|(U|O|2|)|2|(O|,OH)|3}} or {{chem|(Na|,Ca|,Pb)|(U|O|2|)O|(OH)|·0-1H|2|O}}.
Its color varies from dark brown to reddish orange. Clarkeite forms by oxidation and replacement of uraninite late during pegmatite crystallization. Although uraninite-bearing granite pegmatites are common, clarkeite is rare and occurs intimately intergrown with other uranium minerals.
It is known from only two localities; the Spruce Pine pegmatite district in western North Carolina, US, and Rajputana, in the Ajmer district, India. Clarkeite is the only known naturally occurring high-temperature uranate. The general formula for ideal clarkeite is {{chem|Na|[(U|O|2|)O|(OH)]|(H|2|O)|0–1}}.
It was named for Frank Wigglesworth Clarke (1847–1931), American mineral chemist, and former chief chemist of the United States Geological Survey.
See also
References
{{Reflist}}
- [http://www.minsocam.org/MSA/AmMin/TOC/Articles_Free/1997/Finch_p607-619_97.pdf Clarkeite: New chemical and structural data]
- [http://www.mindat.org/min-1059.html Clarkeite: Clarkeite mineral information and data]
- [http://www.webmineral.com/data/Clarkeite.shtml WebMineral]
Category:Minerals in space group 166
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