Cobalt(II) oxalate

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| ImageFile1 = Cobalt(II)-oxalate-dihydrate-from-xtal-2005-CM-3D-balls.png

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| Section1 = {{Chembox Identifiers

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| CASNo = 814-89-1

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| UNII = R028MNY8UA

| PubChem = 69946

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| ChemSpiderID = 63139

| SMILES = C(=O)(C(=O)[O-])[O-].[Co+2]

| InChI = 1/C2H2O4.Co/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2

| InChIKey = MULYSYXKGICWJF-NUQVWONBAF

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| StdInChI = 1S/C2H2O4.Co/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2

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| StdInChIKey = MULYSYXKGICWJF-UHFFFAOYSA-L}}

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| Formula = CoC2O4

| MolarMass = 146.9522 g/mol

| Appearance = gray/pink powder

| Odor = odorless

| Density = 3.01 g/cm3

| MeltingPtC = 250

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Cobalt(II) oxalate is the inorganic compound with the formula of CoC2O4. Like other simple inorganic oxalates, it is a coordination polymer. The oxalate ligands bridge of Co(OH2)2 centres. Each cobalt adopts octahedral coordination geometry.{{ cite journal | journal = Acta Crystallogr. C | volume = 61 | year = 2005 | pages = m58–m60 | title = catena-Poly[[diaquacobalt(II)]-μ-oxalato] | first1 = J. | last1 = Bacsa | first2 = D. | last2 = Eve | first3 = K. R. | last3 = Dunbar | issue = Pt 1 | doi = 10.1107/S0108270104030409 | pmid = 15640580 }}

It is used in the preparation of cobalt catalysts, and cobalt metal powder for powder-metallurgical applications. It is made in process of recycling lithium-ion batteries, where the cobalt is obtained from cathode material (LiCoO2) by leaching with sulfuric acid and then precipitated with ammonium oxalate.{{cn|date=September 2023}}

Related compounds

Many cobalt(III) oxalate complexes are known, including [Co(C2O4)3]3- and [Co(C2H4(NH2)2)C2O4)2].{{cite journal |doi=10.1002/9780470132395.ch55|title=Resolution of the Trioxalatocobaltate(III) Ion|journal=Inorganic Syntheses|year=1966|last1=Kauffman|first1=George B.|last2=Takahashi|first2=Lloyd T.|last3=Sugisaka|first3=Nobuyuki|volume=8|pages=207–211}}

{{cite journal |doi=10.1002/9780470132449.ch40|title=Resolution of the (Ethylenediamine)bis(oxalato)cobaltate(III) Ion|journal=Inorganic Syntheses|year=1972|volume=13|last1=Worrell|first1=J. H.|last2=Kipp|first2=E. B.|pages=195–202}}

References

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{{Cobalt compounds}}

{{Oxalates}}

Category:Cobalt(II) compounds

Category:Oxalates

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