Cobalt(II) oxalate
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| ImageFile = Cobalt (II) oxalate.jpg
| ImageFile1 = Cobalt(II)-oxalate-dihydrate-from-xtal-2005-CM-3D-balls.png
| ImageSize = 300
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| Section1 = {{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 814-89-1
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = R028MNY8UA
| PubChem = 69946
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 63139
| SMILES = C(=O)(C(=O)[O-])[O-].[Co+2]
| InChI = 1/C2H2O4.Co/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
| InChIKey = MULYSYXKGICWJF-NUQVWONBAF
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| StdInChI = 1S/C2H2O4.Co/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = MULYSYXKGICWJF-UHFFFAOYSA-L}}
| Section2 = {{Chembox Properties
| Formula = CoC2O4
| MolarMass = 146.9522 g/mol
| Appearance = gray/pink powder
| Odor = odorless
| Density = 3.01 g/cm3
| MeltingPtC = 250
| MeltingPt_notes = (decomposes)
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Cobalt(II) oxalate is the inorganic compound with the formula of CoC2O4. Like other simple inorganic oxalates, it is a coordination polymer. The oxalate ligands bridge of Co(OH2)2 centres. Each cobalt adopts octahedral coordination geometry.{{ cite journal | journal = Acta Crystallogr. C | volume = 61 | year = 2005 | pages = m58–m60 | title = catena-Poly[[diaquacobalt(II)]-μ-oxalato] | first1 = J. | last1 = Bacsa | first2 = D. | last2 = Eve | first3 = K. R. | last3 = Dunbar | issue = Pt 1 | doi = 10.1107/S0108270104030409 | pmid = 15640580 }}
It is used in the preparation of cobalt catalysts, and cobalt metal powder for powder-metallurgical applications. It is made in process of recycling lithium-ion batteries, where the cobalt is obtained from cathode material (LiCoO2) by leaching with sulfuric acid and then precipitated with ammonium oxalate.{{cn|date=September 2023}}
Related compounds
Many cobalt(III) oxalate complexes are known, including [Co(C2O4)3]3- and [Co(C2H4(NH2)2)C2O4)2]−.{{cite journal |doi=10.1002/9780470132395.ch55|title=Resolution of the Trioxalatocobaltate(III) Ion|journal=Inorganic Syntheses|year=1966|last1=Kauffman|first1=George B.|last2=Takahashi|first2=Lloyd T.|last3=Sugisaka|first3=Nobuyuki|volume=8|pages=207–211}}
References
{{Reflist}}
{{Cobalt compounds}}
{{Oxalates}}
{{inorganic-compound-stub}}