Diarsenic tetraiodide
{{Chembox
| ImageFile = Diphosphorus-tetraiodide-3D-balls.png
| ImageSize =
| IUPACName = Arsenic diiodide
|Section1={{Chembox Identifiers
| CASNo = 13770-56-4
| CASNo_Ref = {{Cascite|correct|CAS}}
| PubChem = 165365657
| SMILES = I[As](I)[As](I)I
| InChI = 1S/As.2HI/h;2*1H/p-2
| InChIKey = YWEMTIDRPOANDU-UHFFFAOYSA-L
}}
|Section2={{Chembox Properties
| Formula = As2I4
| MolarMass = 657.461 g/mol
| Appearance = Red crystalline solid
| BoilingPtC = 380
| MeltingPtC = 137
}}
}}
Diarsenic tetraiodide is an inorganic compound of arsenic and iodine. It is a dark red metastable solid. The compound is a closely related to the better characterized diphosphorus tetraiodide. Identified in the late 19th century with the (accurate) empirical formula AsI2,{{cite journal |first1= Eugen |last1= Bamberger |first2= Julius |last2= Philipp |title= Ueber Verbindungen von Arsen und Jod |journal= Berichte der Deutschen Chemischen Gesellschaft |volume= 14 |issue= 2 |pages= 2643–2648 |year= 1881 |doi= 10.1002/cber.188101402228 |url= https://zenodo.org/record/1425240 }} the compound was assigned the formula (As2I4) several years later.{{cite journal |title= LXXXIX.—Arsenic di-iodide |first1= John Theodore |last1= Hewitt |first2= Thomas Field |last2= Winmill |journal= J. Chem. Soc., Trans. |year= 1907 |volume= 91 |pages= 962–964 |doi= 10.1039/CT9079100962 |url= https://zenodo.org/record/1879397 }}
References
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Further reading
- {{cite journal|doi=10.1016/0022-2364(80)90115-8|title=NQR in metal dihalides MX2|year=1980|last1=Bastow|first1=T.J.|last2=Whitfield|first2=H.J.|journal=Journal of Magnetic Resonance|volume=37|issue=2|pages=269–274|bibcode=1980JMagR..37..269B}}
- {{Cite journal | doi = 10.1002/zaac.19663430504| title = Beiträge zur Chemie des Arsens. I. Darstellung und Eigenschaften von Diarsen-tetrajodid| journal = Zeitschrift für anorganische und allgemeine Chemie| volume = 343| issue = 5–6| pages = 244| year = 1966| last1 = Baudler | first1 = M.| last2 = Stassen | first2 = H. -J. }}
- {{Cite journal | doi = 10.1002/zaac.19663450308| title = Beiträge zur Chemie des Arsens. II. Zur Kenntnis des Reaktiven Verhaltens von Diarsen-tetrajodid| journal = Zeitschrift für anorganische und allgemeine Chemie| volume = 345| issue = 3–4| pages = 182| year = 1966| last1 = Baudler | first1 = M.| last2 = Stassen | first2 = H. -J. }}
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