Dibromodifluoromethane
{{chembox
| Watchedfields = changed
| verifiedrevid = 414418288
| ImageFile_Ref = {{chemboximage|correct|??}}
| ImageFile = Dibromodifluoromethane.png
| ImageSize = 120px
| PIN = Dibromo(difluoro)methane
| OtherNames = Dibromodifluoromethane
Difluorodibromomethane
Carbon dibromide difluoride
Carbon bromide fluoride
Halon 1202
Fluorocarbon 12-B2
FC 12-B2
R 12B2
UN 1941
Freon 12B2
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 6142
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 499553
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/CBr2F2/c2-1(3,4)5
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = AZSZCFSOHXEJQE-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 75-61-6
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 82022727JD
| EINECS = 200-885-5
| UNNumber = 1941
| PubChem = 6382
| SMILES = BrC(F)(F)Br
| InChI = 1/CBr2F2/c2-1(3,4)5
| RTECS = PA7525000
}}
|Section2={{Chembox Properties
| Formula = CBr2F2
| MolarMass = 209.82{{nbsp}}g/mol
| Appearance = Colourless gas/liquid
| Density = {{ubl
| 8.7{{nbsp}}kg/m3 (for gas)
| 2.27{{nbsp}}g/cm3 (for liquid)
}}
| MeltingPtC = -101.1
| BoilingPtC = 22.8
| Solubility = insoluble
| LogP = 1.99
| VaporPressure = 83{{nbsp}}kPa at 20{{nbsp}}°C
}}
|Section3={{Chembox Hazards
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|420}}
| PPhrases = {{P-phrases|502}}
| NFPA-H = 2
| NFPA-F = 0
| NFPA-R = 0
| NFPA-S =
| FlashPt = Non-flammable
| AutoignitionPt =
| PEL = TWA 100{{nbsp}}ppm (860{{nbsp}}mg/m3){{PGCH|0214}}
| REL = TWA 100{{nbsp}}ppm (860{{nbsp}}mg/m3)
}}
}}
Dibromodifluoromethane is a mixed halomethane. It is a colorless non-flammable liquid. Along with Halons 1211, 2402, and 1301, it is one of the most effective fire extinguishers, however, it is also very toxic. It is a class I ozone depleting substance (ODS).
Synthesis
Dibromodifluoromethane can be obtained by vapor phase bromination of difluoromethane.{{HSDB|ID=1335|name=Dibromodifluoromethane|accessdate=2013-03-10}}
It is also formed during the fluorination of carbon tetrabromide.{{citation|author=Alan Roy Katritzky, Otto Meth-Cohn, Thomas Lonsdale Gilchrist, Charles Wayne Rees|date=1995|isbn=0-08-042704-9|pages=226|publisher=Elsevier|title=Comprehensive Organic Functional Group Transformations: Carbon with Three Or ...|url={{Google books|YzBveZGm0GEC||page=226|plainurl=yes}}}}
Table of physical properties
class="wikitable"
! Property ! Value |
Density, ρ, at 15{{nbsp}}°C (liquid)
| 2.3063{{nbsp}}g/cm3 |
Critical temperature, Tc
| 198.3{{nbsp}}°C, 471.3{{nbsp}}K |
Critical pressure, pc
| 4.13{{nbsp}}MPa, 40.8{{nbsp}}bar |
Refractive index, n at 20{{nbsp}}°C, D
| 1.398 |
Dipole moment
| 0.7{{nbsp}}D |
Ozone depletion potential, ODP
| 0.4, CCl3F is 1 |
Global warming potential, GWP
| 231, CO2 is 1Hodnebrog, Ø., M. Etminan, J. S. Fuglestvedt, G. Marston, G. Myhre, C. J. Nielsen, K. P. Shine, and T. J. Wallington (2013), ‘Global warming potentials and radiative efficiencies of halocarbons and related compounds: A comprehensive review,’ Reviews of Geophysics, vol. 51, pp. 300-378, doi:10.1002/rog.20013. |
References
{{reflist}}
External links
- {{ICSC|1419|14}}
- {{PGCH|0214}}
- [http://www.rsc.org/publishing/journals/article.asp?doi=f19726801559 Photolysis of dibromodifluoromethane at 265 nm]
- [https://archive.today/20121210045110/http://www3.interscience.wiley.com/cgi-bin/abstract/110457787/ABSTRACT?CRETRY=1&SRETRY=0 Raman and infrared spectra of solid dibromodifluoromethane]
{{Halomethanes}}
{{fluorine compounds}}