Dithionic acid
{{Chembox
| Verifiedfields = changed
| verifiedrevid = 477000976
| ImageFile1 = Dithionic-acid-2D.png
| ImageFile2 = Dithionic-acid-3D-balls.png
| ImageAlt2 = Ball-and-stick model of dithionic acid
| IUPACName = dithionic acid{{RedBookRef|page=130}}
| OtherNames = hypodisulfuric acid
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 25128
| InChI = 1/H2O6S2/c1-7(2,3)8(4,5)6/h(H,1,2,3)(H,4,5,6)
| InChIKey = RMGVZKRVHHSUIM-UHFFFAOYAM
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/H2O6S2/c1-7(2,3)8(4,5)6/h(H,1,2,3)(H,4,5,6)
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = RMGVZKRVHHSUIM-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|changed|??}}
| CASNo = 14970-71-9
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 9MP5KH5623
| PubChem = 26985
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 29208
| SMILES = O=S(=O)(O)S(=O)(=O)O
}}
|Section2={{Chembox Properties
| Formula = {{chem2|H2S2O6}}
| MolarMass = 162.14 g mol−1
| ConjugateBase =Dithionate
| pKa = −3.4 (estimated){{cite book|title=Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution|editor-first=D. D.|editor-last=Perrin|edition=2nd|series=IUPAC Chemical Data|issue=29|publisher=Pergamon|location=Oxford|year=1982|publication-date=1984|orig-date=1969|lccn=82-16524|isbn=0-08-029214-3|at=Entry 63}}
}}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}
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Dithionic acid, {{chem2|H2S2O6}}, is the inorganic compound with the formula {{chem2|H2S2O6}}. It is the doubly protonated derivative of dithionate, a well-characterized dianion. Dithionic acid is mainly observed and characterized as an aqueous solution.{{Greenwood&Earnshaw}} pp. 715-716
Synthesis
Dithionates can be made by oxidizing a sulfite (from the +4 to the +5 oxidation state), but on a larger scale they are made by oxidizing a cooled aqueous solution of sulfur dioxide with manganese dioxide:
:{{chem2|2 MnO2 + 3 SO2 -> MnS2O6 + MnSO4}}
The manganese dithionate solution formed can then be converted to dithionate salts of other metals by metathesis reactions:
:{{chem2|Ba^{2+} (aq) + MnS2O6 (aq) + MnSO4 (aq) -> BaSO4 (s)↓ + BaS2O6 * 2 H2O (aq)}}
Concentrated solutions of dithionic acid can subsequently be obtained treating a barium dithionate solution with sulfuric acid:
:{{chem2|BaS2O6 (aq) + H2SO4 (aq) -> H2S2O6 (aq) + BaSO4 (s)↓}}
See also
- Sodium dithionate
- Hypophosphoric acid, the phosphorus equivalent.
References
{{reflist}}
{{Hydrogen compounds}}
{{DEFAULTSORT:Dithionic Acid}}