Dualite
{{Short description|Mineral of the eudialyte group}}
{{Use dmy dates|date=January 2025}}
{{infobox mineral
| name = Dualite
| category = Silicate mineral, cyclosilicate
| image =
| imagesize =
| alt =
| caption =
| formula = {{chem|Na|30|(Ca|,Na|,Ce|,Sr)|12|(Na|,Mn|,Fe|,Ti)|6}}{{chem|Zr|3|Ti|3|Mn|Si|51|O|144|(OH|,H|2|O|,Cl)|9}}
| strunz = 9.CO.10
| dana = 64.1b.1.4
| system = Trigonal
| class = Ditrigonal pyramidal (3m)
H-M symbol: (3m)
| symmetry = R3m
| unit cell = a = 14.15, c = 60.72 [Å] (approximated); Z = 3
| color = Yellow
| colour =
| habit = Anhedral grains
| twinning =
| cleavage = None
| fracture = Conchoidal
| tenacity = Brittle
| mohs = 5
| luster = Vitreous
| streak = White
| diaphaneity = Transparent or translucent
| gravity =
| density = 2.84 (measured), 2.81 (calculated; approximated)
| polish =
| opticalprop = Uniaxial (+)
| refractive = nω = 1.61, nε = 1.61 (approximated)
| birefringence =
| pleochroism = None
| 2V =
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| fluorescence = No
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Dualite is a very rare and complex mineral of the eudialyte group, its complexity being expressed in its formula {{chem|Na|30|(Ca|,Na|,Ce|,Sr)|12|(Na|,Mn|,Fe|,Ti)|6}}{{chem|Zr|3|Ti|3|Mn|Si|51|O|144|(OH|,H|2|O|,Cl)|9}}.Mindat, Dualite, http://www.mindat.org/min-27578.htmlKhomyakov, A.P., Nechelyustov, G.N., and Rastsvetaeva, R.K., 2009: Dualite, Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3MnSi51O144(OH,H2O,Cl)9, a new zircono-titanosilicate with a modular eudialyte-like structure from the Lovozero alkaline Pluton, Kola Peninsula, Russia. Geology of Ore Deposits 50(7), 574-582 The formula is simplified as it does not show the presence of cyclic silicate groups.
The name of the mineral comes from its dual nature: zircono- and titanosilicate at once. Dualite has two modules in its structure: alluaivite one and eudialyte one. After alluaivite and labyrinthite it stands for third representative of the eudialyte group with essential titanium.
Occurrence and association
Dualite was found in peralkaline pegmatoid rock at Mt Alluaiv, Lovozero massif, Kola Peninsula Russia. It associates with aegirine, alkaline amphibole, cancrinite, eudialyte, K-Na feldspar, lamprophyllite, lomonosovite, lovozerite, nepheline, sodalite, sphalerite, villiaumite, and vuonnemite.
Notes on chemistry
Notes on crystal structure
References
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Further reading
- Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785-794
Category:Minerals in space group 160
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