Electron affinity (data page)

{{Short description|Chemical data page}}

This page deals with the electron affinity as a property of isolated atoms or molecules (i.e. in the gas phase). Solid state electron affinities are not listed here.

Elements

Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion. The latter can be regarded as the ionization energy of the −1 ion or the zeroth ionization energy.{{cite book |last1=Wulfsberg |first1=G. P.|date=2018 |title=Foundations of Inorganic Chemistry |location= California|publisher= University Science Books|page=362 |isbn=978-1-891389-95-5}} Either convention can be used.{{GoldBookRef |title=Electron affinity |file=E01977}}

Negative electron affinities can be used in those cases where electron capture requires energy, i.e. when capture can occur only if the impinging electron has a kinetic energy large enough to excite a resonance of the atom-plus-electron system. Conversely electron removal from the anion formed in this way releases energy, which is carried out by the freed electron as kinetic energy. Negative ions formed in these cases are always unstable. They may have lifetimes of the order of microseconds to milliseconds, and invariably autodetach after some time.

† A quantum offset of the velocity imaging-based measurements was revealed in 2025, which could make a revision of all electron affinities marked with a dagger necessary. The value of the downward correction to be applied is determined by the intensity of the electric field that was used in the experiment, which was not published with the original measurements, but can be estimated to be of the order of −20 μeV.

class="wikitable sortable"
ZElementNameElectron affinity (eV)Electron affinity (kJ/mol)References
1

|1H

|Hydrogen

data-sort-value="0.754195"|0.754 195(19)data-sort-value="72.769"|72.769(2)
1

|2H

|Deuterium

data-sort-value="0.75467"|0.754 67(4)data-sort-value="72.814"|72.814(4)
2HeHeliumdata-sort-value="-0.5"|−0.5(2)data-sort-value="-48"|−48(20)est.
3LiLithiumdata-sort-value="0.61804922"|0.618 049(22)data-sort-value="59.632"|59.632 6(21)
4BeBerylliumdata-sort-value="-0.5"|−0.5(2)data-sort-value="-48"|−48(20)est.
5BBorondata-sort-value="0.27972325"|0.279 723(25)data-sort-value="26.989"|26.989(3)
6

|12C

|Carbon

data-sort-value="1.262122611"|1.262 122 6(11)data-sort-value="121.7763"|121.776 3(1)
6

|13C

|Carbon

data-sort-value="1.2621136"|1.262 113 6(12)data-sort-value="121.7755"|121.775 5(2)
7NNitrogendata-sort-value="-0.07"|−0.07data-sort-value="-6.8"|−6.8
8

|16O

|Oxygen

data-sort-value="1.46111297"|1.461 112 97(9)data-sort-value="140.976"|140.975 970(9)
8

|17O

|Oxygen

data-sort-value="1.461108"|1.461 108(4)data-sort-value="140.9755"|140.975 5(3)
8

|18O

|Oxygen

data-sort-value="1.461105"|1.461 105(3)data-sort-value="140.9752"|140.975 2(3)
9FFluorinedata-sort-value="3.4011898"|3.401 189 8(24)data-sort-value="328.164"|328.164 9(3)
10NeNeondata-sort-value="-1.2"|−1.2(2)data-sort-value="-116"|−116(19)est.
11NaSodiumdata-sort-value="0.547926"|0.547 926(25)data-sort-value="52.867"|52.867(3)
12MgMagnesiumdata-sort-value="-0.4"|−0.4(2)data-sort-value="-40"|−40(19)est.
13AlAluminiumdata-sort-value="0.43283"|0.432 83(5)data-sort-value="41.762"|41.762(5)
14SiSilicondata-sort-value="1.3895212"|1.389 521 2(8)data-sort-value="134.068"|134.068 4(1)
15PPhosphorusdata-sort-value="0.746609"|0.746 609(11)data-sort-value="72.037"|72.037(1)
16

|32S

|Sulfur

data-sort-value="2.0771042"|2.077 104 2(6)data-sort-value="200.410"|200.410 1(1)
16

|34S

|Sulfur

data-sort-value="2.0771045"|2.077 104 5(12)data-sort-value="200.410"|200.410 1(2)
17ClChlorinedata-sort-value="3.612725"|3.612 725(28)data-sort-value="348.575"|348.575(3)
18ArArgondata-sort-value="-1.0"|−1.0(2)data-sort-value="-96"|−96(20)est.
19KPotassiumdata-sort-value="0.501459"|0.501 459(13)data-sort-value="48.383"|48.383(2)
20CaCalciumdata-sort-value="0.02455"|0.024 55(10)data-sort-value="2.37"|2.37(1)
21ScScandiumdata-sort-value="0.17938"|0.179 380(23)data-sort-value="17.3076"|17.307 6(22)
22TiTitaniumdata-sort-value="0.07554"|0.075 54(5)data-sort-value="7.289"|7.289(5)
23VVanadiumdata-sort-value="0.52766"|0.527 66(20)data-sort-value="50.911"|50.911(20)
24CrChromiumdata-sort-value="0.67593"|0.675 928(27)data-sort-value="65.2172"|65.217 2(26)
25MnManganesedata-sort-value="-0.5"|−0.5(2)data-sort-value="-50"|−50(19)est.
26FeIrondata-sort-value="0.153236"|0.153 236(35)data-sort-value="14.785"|14.785(4)
27CoCobaltdata-sort-value="0.662255"|0.662 255(47)data-sort-value="63.8979"|63.897 9(45)
28NiNickeldata-sort-value="1.15716"|1.157 16(12)data-sort-value="111.65"|111.65(2)
29CuCopperdata-sort-value="1.23578"|1.235 78(4)data-sort-value="119.235"|119.235(4)
30ZnZincdata-sort-value="-0.6"|−0.6(2)data-sort-value="-58"|−58(20)est.
31GaGalliumdata-sort-value="0.301166"|0.301 166(15)data-sort-value="29.0581"|29.058 1(15)
32GeGermaniumdata-sort-value="1.2326764"|1.232 676 4(13)data-sort-value="118.935"|118.935 2(2)
3375AsArsenicdata-sort-value="0.804486"|0.804 486(3)data-sort-value="77.62"|77.621 1(3)
34SeSeleniumdata-sort-value="2.0206047"|2.020 604 7(12)data-sort-value="194.958"|194.958 7(2)
35BrBrominedata-sort-value="3.363588"|3.363 588(3)data-sort-value="324.536"|324.536 9(3)
36KrKryptondata-sort-value="-1.0"|−1.0(2)data-sort-value="-96"|−96(20)est.
37RbRubidiumdata-sort-value="0.485916"|0.485 916(21)data-sort-value="46.884"|46.884(3)
38SrStrontiumdata-sort-value="0.05206"|0.052 06(6)data-sort-value="5.023"|5.023(6)
39YYttriumdata-sort-value="0.31129"|0.311 29(22)data-sort-value="30.035"|30.035(21)
40ZrZirconiumdata-sort-value="0.43328"|0.433 28(9)data-sort-value="41.806"|41.806(9)
41NbNiobiumdata-sort-value="0.91740"|0.917 40(7)data-sort-value="88.516"|88.516(7)
42MoMolybdenumdata-sort-value="0.74723"|0.747 23(8)data-sort-value="72.097"|72.097(8)
43TcTechnetiumdata-sort-value="0.55"|0.55(20)data-sort-value="53"|53(20)est.
44RuRutheniumdata-sort-value="1.04627"|1.046 27(2)data-sort-value="100.95"|100.950(3)
45RhRhodiumdata-sort-value="1.14289"|1.142 89(20)data-sort-value="110.27"|110.27(2)
46PdPalladiumdata-sort-value="0.56214"|0.562 14(12)data-sort-value="54.24"|54.24(2)
47AgSilverdata-sort-value="1.30447"|1.304 47(3)data-sort-value="125.862"|125.862(3)
48CdCadmiumdata-sort-value="-0.7"|−0.7(2)data-sort-value="-68"|−68(20)est.
49InIndiumdata-sort-value="0.38392"|0.299data-sort-value="28.9" |28.9
50SnTindata-sort-value="1.112070"|1.112 070(2)data-sort-value="107.298"|107.298 4(3)
51SbAntimonydata-sort-value="1.047401"|1.047 401(19)data-sort-value="101.059"|101.059(2)
52TeTelluriumdata-sort-value="1.970875"|1.970 875(7)data-sort-value="190.161"|190.161(1)
53127IIodinedata-sort-value="3.0590465"|3.059 046 5(37)data-sort-value="295.1531"|295.153 1(4)
53128IIodinedata-sort-value="3.059052"|3.059 052(38)data-sort-value="295.154"|295.154(4)
54XeXenondata-sort-value="-0.8"|−0.8(2)data-sort-value="-77"|−77(20)est.
55CsCaesiumdata-sort-value="0.4715983"|0.4715983(38)data-sort-value="45.5023"|45.5023(4){{cite journal | last=Navarro Navarrete | first=José E. | last2=Nichols | first2=Miranda | last3=Ringvall-Moberg | first3=Annie | last4=Welander | first4=Jakob | last5=Lu | first5=Di | last6=Leimbach | first6=David | last7=Kristiansson | first7=Moa K. | last8=Eklund | first8=Gustav | last9=Raveesh | first9=Meena | last10=Chulkov | first10=Ruslan | last11=Zhaunerchyk | first11=Vitali | last12=Hanstorp | first12=Dag | title=High-resolution measurement of the electron affinity of cesium | journal=Physical Review A | volume=109 | issue=2 | date=2024-02-21 | issn=2469-9926 | doi=10.1103/PhysRevA.109.022812| doi-access=free }}
56BaBariumdata-sort-value="0.14462"|0.144 62(6)data-sort-value="13.954"|13.954(6)
57LaLanthanumdata-sort-value="0.557546"|0.557 546(20)data-sort-value="53.795"|53.795(2)
58CeCeriumdata-sort-value="0.60016"|0.600 160(27)data-sort-value="57.9067"|57.906 7(26)
59PrPraseodymiumdata-sort-value="0.10923"|0.109 23(46)data-sort-value="10.539"|10.539(45)
60NdNeodymiumdata-sort-value="0.09749"|0.097 49(33)data-sort-value="9.406"|9.406(32)
61PmPromethiumdata-sort-value="0.129"|0.129data-sort-value="12.45"|12.45
62SmSamariumdata-sort-value="0.162"|0.162data-sort-value="15.63"|15.63
63EuEuropiumdata-sort-value="0.116"|0.116(13)data-sort-value="11.2"|11.2(13)
64GdGadoliniumdata-sort-value="0.212"|0.212(30)data-sort-value="20.5"|20.5(29)
65TbTerbiumdata-sort-value="0.13131"|0.131 31(80)data-sort-value="12.670"|12.670(77)
66DyDysprosiumdata-sort-value="0.015"|0.015(3)data-sort-value="1.45"|1.45(30)
67HoHolmiumdata-sort-value="0.338"|0.338data-sort-value="32.61"|32.61
68ErErbiumdata-sort-value="0.312"|0.312data-sort-value="30.10"|30.10
69TmThuliumdata-sort-value="1.029"|1.029(22)data-sort-value="99"|99(3)
70YbYtterbiumdata-sort-value="-0.02"|−0.02data-sort-value="-1.93"|−1.93est.
71LuLutetiumdata-sort-value="0.2388"|0.238 8(7)data-sort-value="23.04"|23.04(7)
72HfHafniumdata-sort-value="0.1780"|0.178 0(7)data-sort-value="17.18"|17.18(7)

73TaTantalumdata-sort-value="0.328859"|0.328 859(23)data-sort-value="31.7301"|31.730 1(22)
74WTungstendata-sort-value="0.81626"|0.816 500(82)data-sort-value="78.78"|78.780 3(80)
75ReRheniumdata-sort-value="0.060396"|0.060 396(64)data-sort-value="5.8273"|5.827 3(62)
76OsOsmiumdata-sort-value="1.077661"|1.077 661(24)data-sort-value="103.9785"|103.978 5(24)
77IrIridiumdata-sort-value="1.564057"|1.564 057(12)data-sort-value="150.909"|150.908 6(12)
78PtPlatinumdata-sort-value="2.12510"|2.125 10(5)data-sort-value="205.041"|205.041(5)
79AuGolddata-sort-value="2.308610"|2.308 610(25)data-sort-value="222.747"|222.747(3)
80HgMercurydata-sort-value="-0.5"|−0.5(2)data-sort-value="-48"|−48(20)est.
81TlThalliumdata-sort-value="0.320053"|0.320 053(19)data-sort-value="30.8804"|30.880 4(19)
82PbLeaddata-sort-value="0.356721"|0.356 721(2)data-sort-value="34.4183"|34.418 3(3)
83BiBismuthdata-sort-value="0.942362"|0.942 362(13)data-sort-value="90.924"|90.924(2)
84PoPoloniumdata-sort-value="1.40"|1.40(7)data-sort-value="136"|136(7)calc.
85AtAstatinedata-sort-value="2.41578"|2.415 78(7)data-sort-value="233.087"|233.087(8)
86RnRadondata-sort-value="-0.7"|−0.7(2)data-sort-value="-68"|−68(20)est.
87FrFranciumdata-sort-value="0.486"|0.486data-sort-value="46.89"|46.89est.
88RaRadiumdata-sort-value="0.10"|0.10data-sort-value="9.6485"|9.648 5est.
89AcActiniumdata-sort-value="0.35"|0.35data-sort-value="33.77"|33.77est.
90ThThoriumdata-sort-value="0.60769"|0.607 69(6)data-sort-value="58.633"|58.633(6)
91PaProtactiniumdata-sort-value="0.55"|0.55data-sort-value="53.03"|53.03est.
92UUraniumdata-sort-value="0.31497"|0.314 97(9)data-sort-value="30.39"|30.390(9)
93NpNeptuniumdata-sort-value="0.48"|0.48data-sort-value="45.85"|45.85est.
94PuPlutoniumdata-sort-value="-0.50"|−0.50data-sort-value="-48.33"|−48.33est.
95AmAmericiumdata-sort-value="0.10"|0.10data-sort-value="9.93"|9.93est.
96CmCuriumdata-sort-value="0.28"|0.28data-sort-value="27.17"|27.17est.
97BkBerkeliumdata-sort-value="-1.72"|−1.72data-sort-value="-165.24"|−165.24est.
98CfCaliforniumdata-sort-value="-1.01"|−1.01data-sort-value="-97.31"|−97.31est.
99EsEinsteiniumdata-sort-value="-0.30"|−0.30data-sort-value="-28.60"|−28.60est.
100FmFermiumdata-sort-value="0.35"|0.35data-sort-value="33.96"|33.96est.
101MdMendeleviumdata-sort-value="0.98"|0.98data-sort-value="93.91"|93.91est.
102NoNobeliumdata-sort-value="-2.33"|−2.33data-sort-value="-223.22"|−223.22est.
103LrLawrenciumdata-sort-value="-0.31"|−0.31data-sort-value="-30.04"|−30.04est.
111RgRoentgeniumdata-sort-value="1.565"|1.565data-sort-value="151.0"|151.0calc.{{cite journal |last1=Eliav |first1=Ephraim |last2=Fritzsche |first2=Stephan |first3=Uzi |last3=Kaldor |date=2015 |title=Electronic structure theory of the superheavy elements |journal=Nucl. Phys. A |volume=944 |pages=518–550 |doi=10.1016/j.nuclphysa.2015.06.017|bibcode=2015NuPhA.944..518E }}
113NhNihoniumdata-sort-value="0.69"|0.69data-sort-value="66.6"|66.6calc.
115McMoscoviumdata-sort-value="0.366"|0.366data-sort-value="35.3"|35.3calc.
116LvLivermoriumdata-sort-value="0.776"|0.776data-sort-value="74.9"|74.9calc.
117TsTennessinedata-sort-value="1.719"|1.719data-sort-value="165.9"|165.9calc.{{cite web |url=http://www.kernchemie.uni-mainz.de/downloads/che_7/presentations/borschevsky.pdf |archive-url=https://web.archive.org/web/20180115184921/http://www.kernchemie.uni-mainz.de/downloads/che_7/presentations/borschevsky.pdf |archive-date=15 January 2018 |title=Fully relativistic ab initio studies of superheavy elements |last1=Borschevsky |first1=Anastasia |first2=Valeria |last2=Pershina |first3=Uzi |last3=Kaldor |first4=Ephraim |last4=Eliav |website=www.kernchemie.uni-mainz.de |publisher=Johannes Gutenberg University Mainz |access-date=15 January 2018}}
118OgOganessondata-sort-value="0.080"|0.080(6)data-sort-value="7.72"|7.72(58)calc.{{cite book |first1=Yangyang |last1=Guo |first2=Lukáš F. |last2=Pašteka |first3=Ephraim |last3=Eliav |first4=Anastasia |last4=Borschevsky |date=2021 |editor1-first=Monika |editor1-last=Musiał |editor2-first=Philip E. |editor2-last=Hoggan |title=Advances in Quantum Chemistry |volume=83 |pages=107–123 |chapter=Chapter 5: Ionization potentials and electron affinity of oganesson with relativistic coupled cluster method |isbn=978-0-12-823546-1}}
119UueUnunenniumdata-sort-value="0.662"|0.662data-sort-value="63.87"|63.87calc.
120UbnUnbiniliumdata-sort-value="0.021"|0.021data-sort-value="2.03"|2.03calc.{{cite journal |last1=Borschevsky |first1=A. |last2=Pershina |first2=V. |last3=Eliav |first3=E. |last4=Kaldor |first4=U. |date=2013 |title=Ab initio predictions of atomic properties of element 120 and its lighter group-2 homologues |journal=Phys. Rev. A |volume=87|issue=2|pages=022502–1–8 |doi=10.1103/PhysRevA.87.022502|bibcode=2013PhRvA..87b2502B }}
121UbuUnbiuniumdata-sort-value="0.57"|0.57data-sort-value="55"|55calc.

Molecules

The electron affinities Eea of some molecules are given in the table below, from the lightest to the heaviest. Many more have been listed by {{harvp|Rienstra-Kiracofe|Tschumper|Schaefer|Nandi|2002}}. The electron affinities of the radicals OH and SH are the most precisely known of all molecular electron affinities.

class="wikitable"
MoleculeNameEea (eV)Eea (kJ/mol)References
colspan=5 align=center |Diatomics
16OHHydroxyl1.827 6488(11)176.3413(2){{harvp|Goldfarb|Drag|Chaibi|Kröger|2005}}
16OD1.825 53(4)176.137(5){{harvp|Schulz|Mead|Jones|Lineberger|1982}}
C2Dicarbon3.269(6)315.4(6){{harvp|Ervin|Lineberger|1991}}
BOBoron oxide2.508(8)242.0(8){{harvp|Wenthold|Kim|Jonas|Lineberger|1997}}
NONitric oxide0.026(5)2.5(5){{harvp|Travers|Cowles|Ellison|1989}}
O2Dioxygen0.450(2)43.42(20){{harvp|Schiedt|Weinkauf|1995}}
32SHSulfhydryl2.314 7283(17)223.3373(2){{harvp|Chaibi|Delsart|Drag|Blondel|2006}}
F2Difluorine3.08(10)297(10){{harvp|Janousek|Brauman|1979}}
Cl2Dichlorine2.35(8)227(8){{harvp|Janousek|Brauman|1979}}
Br2Dibromine2.53(8)244(8){{harvp|Janousek|Brauman|1979}}
I2Diiodine2.524(5)243.5(5){{harvp|Zanni|Taylor|Greenblatt|Soep|1997}}
IBrIodine monobromide2.512(3)242.4(4){{harvp|Sheps|Miller|Lineberger|2009}}
LiClLithium chloride0.593(10)57.2(10){{harvp|Miller|Leopold|Murray|Lineberger|1986}}
FeOIron(II) oxide1.4950(5)144.25(6){{harvp|Kim|Weichman|Neumark|2015}}
CNCyano radical3.862(4)372.6263Calculated on basis of the values for sulhydryl and the eV value of the cyano radical as the kJ/Mol value was missing from the list on march 18, 2025.{{cite journal | last=Bradforth | first=Stephen E. | last2=Kim | first2=Eun Ha | last3=Arnold | first3=Don W. | last4=Neumark | first4=Daniel M. | title=Photoelectron spectroscopy of CN−, NCO−, and NCS− | journal=The Journal of Chemical Physics | publisher=AIP Publishing | volume=98 | issue=2 | date=1993-01-15 | issn=0021-9606 | doi=10.1063/1.464244 | pages=800–810}}{{cite journal | last=Bradforth | first=Stephen E. | last2=Kim | first2=Eun Ha | last3=Arnold | first3=Don W. | last4=Neumark | first4=Daniel M. | title=Photoelectron spectroscopy of CN−, NCO−, and NCS− | journal=The Journal of Chemical Physics | publisher=AIP Publishing | volume=98 | issue=2 | date=1993-01-15 | issn=0021-9606 | doi=10.1063/1.464244 | pages=800–810}}
colspan=5 align=center |Triatomics
NO2Nitrogen dioxide2.273(5)219.3(5){{harvp|Ervin|Ho|Lineberger|1988}}
O3Ozone2.1028(25)202.89(25){{harvp|Novick|Engelking|Jones|Futrell|1979}}
SO2Sulfur dioxide1.107(8)106.8(8){{harvp|Nimlos|Ellison|1986}}
colspan=5 align=center |Larger polyatomics
CH2CHOVinyloxy1.8248(+2-6)176.07(+3-7){{harvp|Rienstra-Kiracofe|Tschumper|Schaefer|Nandi|2002}} after {{harvp|Mead|Lykke|Lineberger|Marks|1984}}
C6H6Benzene−0.70(14)−68(14){{harvp|Ruoff|Kadish|Boulas|Chen|1995}}
C6H4O2p-Benzoquinone1.860(5)179.5(6){{harvp|Schiedt|Weinkauf|1999}}
BF3Boron trifluoride2.65(10)256(10){{harvp|Page|Goode|1969}}
HNO3Nitric acid0.57(15)55(14){{harvp|Janousek|Brauman|1979}}
CH3NO2Nitromethane0.172(6)16.6(6){{harvp|Adams|Schneider|Ervin|Weber|2009}}
POCl3Phosphoryl chloride1.41(20)136(20){{harvp|Mathur|Rothe|Tang|Reck|1976}}
SF6Sulfur hexafluoride1.03(5)99.4(49){{harvp|Troe|Miller|Viggiano|2012}}
C2(CN)4Tetracyanoethylene3.17(20)306(20){{harvp|Chowdhury|Kebarle|1986}}
WF6Tungsten hexafluoride3.5(1)338(10){{harvp|George|Beauchamp|1979}}
UF6Uranium hexafluoride5.06(20)488(20)[http://webbook.nist.gov/cgi/cbook.cgi?ID=C7783815&Units=SI&Mask=18A1#Ion-Energetics NIST chemistry webbook] after {{harvp|Borshchevskii|Boltalina|Sorokin|Sidorov|1988}}
C60Buckminsterfullerene2.6835(6)258.92(6){{harvp|Huang|Dau|Liu|Wang|2014}}

Second and third electron affinity

class="wikitable sortable"
ZElementNameElectron affinity (eV)Electron affinity (kJ/mol)References
7NNitrogendata-sort-value="-6.98"|−6.98data-sort-value="-0.0000048"|−673

Rayner-Canham Appendix 5: Data summarised from, and see also, J. E. Huheey et al., Inorganic Chemistry, 4th ed. (New York:

HarperCollins, 1993) [https://bcs.whfreeman.com/WebPub/Chemistry/raynercanham6e/Appendices/Rayner-Canham%205e%20Appendix%205%20-%20Electron%20Affi%20nities%20of%20Selected%20Nonmetals.pdf]

7N2−Nitrogendata-sort-value="-11.09"|−11.09data-sort-value="-0.0000076"|−1070
8OOxygendata-sort-value="-7.71"|−7.71data-sort-value="-0.0000053"|−744
15PPhosphorusdata-sort-value="-4.85"|−4.85data-sort-value="-0.0000033"|−468
15P2−Phosphorusdata-sort-value="-9.18"|−9.18data-sort-value="-0.0000063"|−886
16SSulfurdata-sort-value="-4.73"|−4.73data-sort-value="-0.0000032"|−456
33AsArsenicdata-sort-value="-4.51"|−4.51data-sort-value="-0.0000031"|−435
33As2−Arsenicdata-sort-value="-8.31"|−8.31data-sort-value="-0.0000057"|−802
34SeSeleniumdata-sort-value="-4.25"|−4.25data-sort-value="-0.0000029"|−410

Bibliography

  • {{citation|last1=Janousek|first1=Bruce K.|last2=Brauman|first2=John I.|year=1979|title=Gas Phase Ion Chemistry|chapter=Electron affinities|editor=Bowers, M. T.|volume=2|place=New York|publisher=Academic Press|page=53|chapter-url={{Google books|N5j-BAAAQBAJ|page=53|plainurl=yes}}}}.
  • {{citation|first1=J.C.|last1=Rienstra-Kiracofe|first2=G.S.|last2=Tschumper|first3=H.F.|last3=Schaefer|first4=S.|last4=Nandi|first5=G.B.|last5=Ellison|title=Atomic and molecular electron affinities: Photoelectron experiments and theoretical computations|periodical=Chem. Rev.|volume=102|pages=231–282|year=2002|issue=1|doi=10.1021/cr990044u|pmid=11782134}}.
  • Updated values can be found in the [http://webbook.nist.gov/chemistry/ NIST chemistry webbook] for around three dozen elements and close to 400 compounds.

= Specific molecules =

  • {{citation|last1=Adams|first1=C.L.|last2=Schneider|first2=H.|last3=Ervin|first3=K.M.|last4=Weber|first4=J.M.|journal=J. Chem. Phys.|volume=130|issue=7|page=074307|title=Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state|year=2009|doi=10.1063/1.3076892|pmid=19239294|bibcode=2009JChPh.130g4307A|url=https://zenodo.org/record/1232039}}
  • {{citation|last1=Borshchevskii|first1=A.Ya.|last2=Boltalina|first2=O.V.|last3=Sorokin|first3=I.D.|last4=Sidorov|first4 =L.N.|title=Thermochemical quantities for gas-phase iron, uranium, and molybdenum fluorides, and their negative ions|journal=J. Chem. Thermodyn.|volume=20|issue=5|year=1988|page=523|doi=10.1016/0021-9614(88)90080-8}}
  • {{citation|last1=Chaibi|first1=W.|last2=Delsart|first2=C.|last3=Drag|first3=C.|last4=Blondel|first4=C.|title=High precision measurement of the 32SH electron affinity by laser detachment microscopy|journal=J. Mol. Spectrosc.|volume=239|issue=1|page=11|year=2006|doi=10.1016/j.jms.2006.05.012|bibcode=2006JMoSp.239...11C}}
  • {{citation|last1=Chowdhury|first1=S.|last2=Kebarle|first2=P.|title=Electron affinities of di- and tetracyanoethylene and cyanobenzenes based on measurements of gas-phase electron-transfer equilibria|journal=J. Am. Chem. Soc.|volume=108|issue=18|page=5453|year=1986|doi=10.1021/ja00278a014}}
  • {{citation|first1=K.M.|last1=Ervin|first2=J.|last2=Ho|first3=W.C.|last3=Lineberger|title=Ultraviolet photoelectron spectrum of nitrite anion|journal=J. Phys. Chem.|year=1988|volume=92|issue=19|page=5405|doi=10.1021/j100330a017}}
  • {{citation|last1=Ervin|first1=K.M.|author-link2=W. Carl Lineberger|last2=Lineberger|first2=W.C.|title=Photoelectron spectra of C{{su|b=2|p=−}} and C2H|journal=J. Phys. Chem.|volume=95|issue=3|page=1167|year=1991|doi=10.1021/j100156a026}}
  • {{citation|last1=George|first1=P.M.|last2=Beauchamp|first2=J.L.|title=The electron and fluoride affinities of tungsten hexafluoride by ion cyclotron resonance spectroscopy|journal=Chem. Phys.|volume=36|issue=3|page=345|year=1979|doi =10.1016/0301-0104(79)85018-1|bibcode=1979CP.....36..345G}}
  • {{citation|last1=Goldfarb|first1=F.|last2=Drag|first2=C.|last3=Chaibi|first3=W.|last4=Kröger|first4=S.|last5 =Blondel|first5=C.|last6=Delsart|first6=C.|journal=J. Chem. Phys.|volume=122|issue=1|page=014308|year=2005|title=Photodetachment microscopy of the P, Q, and R branches of the OH(v=0) to OH(v=0) detachment threshold|doi=10.1063/1.1824904 |pmid=15638660|bibcode=2005JChPh.122a4308G}}
  • {{citation|last1=Huang|first1=Dao-Ling|last2=Dau|first2=Phuong Diem|last3=Liu|first3=Hong-Tao|last4=Wang|first4=Lai-Sheng|s2cid=1061364|title=High-resolution photoelectron imaging of cold C{{su|b=60|p=−}} anions and accurate determination of the electron affinity of C60|journal=J. Chem. Phys.|volume=140|issue=22|page=224315|year=2014|doi=10.1063/1.4881421|pmid=24929396|bibcode=2014JChPh.140v4315H}}
  • {{citation|last1=Kim|first1=J.B.|last2=Weichman|first2=M.L.|last3=Neumark|first3=D.M.|title=Low-lying states of FeO and FeO by slow photoelectron spectroscopy|journal=Mol. Phys.|volume=113|issue=15–16|page=2105|year=2015|doi=10.1080/00268976.2015.1005706|bibcode=2015MolPh.113.2105K|s2cid=13868986 }}
  • {{citation|last1=Mathur|first1=B.P.|last2=Rothe|first2=E.W.|last3=Tang|first3=S.Y.|last4=Reck|first4=G.P.|journal=J. Chem. Phys.|volume=65|issue=2|page=565|year=1976|title=Negative ions from phosphorus halides due to cesium charge exchange|doi=10.1063/1.433109|bibcode=1976JChPh..65..565M}}
  • {{citation|last1=Mead|first1=R.D.|last2=Lykke|first2=K.R.|last3=Lineberger|first3=W.C.|last4=Marks|first4=J.|last5 =Brauman|first5=J.I.|title=Spectroscopy and dynamics of the dipole-bound state of acetaldehyde enolate|journal=J. Chem. Phys.|volume=81|issue=11|page=4883|year=1984|doi=10.1063/1.447515|bibcode=1984JChPh..81.4883M}}
  • {{citation|last1=Miller|first1=T.M.|last2=Leopold|first2=D.G.|last3=Murray|first3=K.K.|last4=Lineberger|first4 =W.C.|title=Electron affinities of the alkali halides and the structure of their negative ions|journal=J. Chem. Phys.|volume=85|issue=5|page=2368|year=1986|doi=10.1063/1.451091|bibcode=1986JChPh..85.2368M}}
  • {{citation|first1=Mark R.|last1=Nimlos|first2=G. Barney|last2=Ellison|title=Photoelectron spectroscopy of sulfur-containing anions (SO{{su|b=2|p=−}}, S{{su|b=3|p=−}}, and S2O)|journal=J. Phys. Chem.|year=1986|volume=90|issue=12|page=2574|doi=10.1021/j100403a007}}
  • {{citation|last1=Novick|first1=S.E.|last2=Engelking|first2=P.C.|last3=Jones|first3=P.L.|last4=Futrell|first4=J.H.|first5 =W.C.|last5=Lineberger|title=Laser photoelectron, photodetachment, and photodestruction spectra of O{{su|b=3|p=−}}|journal=J. Chem. Phys.|volume=70|issue=6|page=2652|year=1979|doi=10.1063/1.437842|bibcode=1979JChPh..70.2652N}}
  • {{citation|last1=Page|first1=F. M.|last2=Goode|first2=G. C.|title=Negative ions and the magnetron|publisher=John Wiley & Sons|year=1969}}According to NIST as concerns [http://webbook.nist.gov/cgi/cbook.cgi?ID=C7637072&Mask=20#ref-1 Boron trifluoride], the Magnetron method, lacking mass analysis, is not considered reliable.
  • {{citation|last1=Ruoff|first1=R.S.|last2=Kadish|first2=K.M.|last3=Boulas|first3=P.|last4=Chen|first4=E.C.M.|journal=J. Phys. Chem.|volume=99|issue=21|page=8843|title=Relationship between the Electron Affinities and Half-Wave Reduction Potentials of Fullerenes, Aromatic Hydrocarbons, and Metal Complexes|year=1995|doi=10.1021/j100021a060}}
  • {{citation|last1=Schiedt|first1=J.|first2=R.|last2=Weinkauf|title=Spin-orbit coupling in the O{{su|b=2|p=−}} anion|journal=Z. Naturforsch. A|volume=50|issue=11|page=1041|year=1995|bibcode=1995ZNatA..50.1041S|doi=10.1515/zna-1995-1110|s2cid=197275321 |doi-access=free}}
  • {{citation|last1=Schiedt|first1=J.|last2=Weinkauf|first2=R.|title=Resonant photodetachment via shape and Feshbach resonances: p-benzoquinone anions as a model system|journal=J. Chem. Phys.|volume=110|issue=1|page=304|year=1999|doi=10.1063/1.478066|bibcode=1999JChPh.110..304S}}
  • {{citation|last1=Schulz|first1=P.A.|last2=Mead|first2=R.D.|last3=Jones|first3=P.L.|last4=Lineberger|first4=W.C.|journal=J. Chem. Phys.|volume=77|issue=3|page=1153|title=OH and OD threshold photodetachment|year=1982|doi=10.1063/1.443980|bibcode=1982JChPh..77.1153S}}
  • {{citation|last1=Sheps|first1=L.|last2=Miller|first2=E.M.|last3=Lineberger|first3=W.C.|title=Photoelectron spectroscopy of small IBr(CO2)n(n=0–3) cluster anions|journal=J. Chem. Phys.|volume=131|issue=6|page=064304|year=2009|bibcode=2009JChPh.131f4304S|doi=10.1063/1.3200941|pmid=19691385}}
  • {{citation|first1=M.J.|last1=Travers|first2=D.C.|last2=Cowles|first3=G.B.|last3=Ellison|title=Reinvestigation of the electron affinities of O2 and NO|journal=Chem. Phys. Lett.|volume=164|issue=5|page=449|year=1989|doi=10.1016/0009-2614(89)85237-6|bibcode=1989CPL...164..449T}}
  • {{citation|last1=Troe|first1=J.|last2=Miller|first2=T.M.|last3=Viggiano|first3=A.A.|title=Communication:Revised electron affinity of SF6 from kinetic data|journal=J. Chem. Phys. |volume=136|issue=2|page=121102|year=2012|doi=10.1063/1.3698170|pmid=22462826|bibcode=2012JChPh.136l1102T|doi-access=free|hdl=11858/00-001M-0000-000F-A0CD-D|hdl-access=free}}
  • {{citation|last1=Wenthold|first1=P.G.|last2=Kim|first2=J.B.|last3=Jonas|first3=K.-L.|last4=Lineberger|first4=W.C.|title=An Experimental and Computational Study of the Electron Affinity of Boron Oxide|journal=J. Phys. Chem. A|year=1997|volume=101|issue=24|page=4472|doi=10.1021/jp970645u|bibcode=1997JPCA..101.4472W|citeseerx=10.1.1.497.1352}}
  • {{citation|last1=Zanni|first1=M.T.|last2=Taylor|first2=T.R.|last3=Greenblatt|first3=B.J.|last4=Soep|first4=B.|last5 =Neumark|first5=D.M.|title=Characterization of the I{{su|b=2|p=−}} anion ground state using conventional and femtosecond photoelectron spectroscopy|journal=J. Chem. Phys.|volume=107|issue=19|page=7613|year=1997|doi=10.1063/1.475110|bibcode=1997JChPh.107.7613Z}}

References

{{reflist|33em|refs=

{{cite journal | last1 = Andersen | first1 = H.H. | last2 = Petrunin | first2 = V.V. | last3 = Kristensen | first3 = P. | last4 = Andersen | first4 = T. | year = 1997 | title = Structural properties of the negative strontium ion: Binding energy and fine-structure splitting | journal = Phys. Rev. A | volume = 55 | issue = 4| pages = 3247–49 | doi = 10.1103/PhysRevA.55.3247 | bibcode = 1997PhRvA..55.3247A }}

{{cite journal | last1 = Andersen | first1 = T. | last2 = Haugen | first2 = H.K. | last3 = Hotop | first3 = H. | year = 1999 | title = Binding Energies in Atomic Negative Ions: III | journal = J. Phys. Chem. Ref. Data | volume = 28 | issue = 6| page = 1511 | doi = 10.1063/1.556047 | bibcode = 1999JPCRD..28.1511A }}

{{Cite journal|last1=Andersen|first1 = T.|title=Atomic negative ions: Structure, dynamics and collisions|doi = 10.1016/j.physrep.2004.01.001 | journal=Physics Reports|volume = 394| issue = 4–5|pages=157–313|year=2004|bibcode=2004PhR...394..157A}}

{{cite journal | last1 = Andersson | first1 = K.T. | last2 = Sandstrom | first2 = J. | last3 = Kiyan | first3 = I.Y. | last4 = Hanstorp | first4 = D. | last5 = Pegg | first5 = D.J. | year = 2000 | title = Measurement of the electron affinity of potassium | journal = Phys. Rev. A | volume = 62 | issue = 2| page = 022503 | doi = 10.1103/PhysRevA.62.022503 | bibcode = 2000PhRvA..62b2503A }}

{{cite journal | last1 = Berzinsh | first1 = U. | last2 = Gustafsson | first2 = M. | last3 = Hanstorp | first3 = D. | last4 = Klinkmüller | first4 = A. | last5 = Ljungblad | first5 = U. | last6 = Martensson-Pendrill | first6 = A.M. | author6-link=Ann-Marie Pendrill | year = 1995 | title = Isotope shift in the electron affinity of chlorine | journal = Phys. Rev. A | volume = 51 | issue = 1| pages = 231–238 | doi = 10.1103/PhysRevA.51.231 | pmid = 9911578 | arxiv = physics/9804028 | bibcode = 1995PhRvA..51..231B | s2cid = 3225884 }}

Beyer M. & Merkt F. (2018). "Communication: Heavy-Rydberg states of HD and the electron affinity of the deuterium atom". J. Chem. Phys. 149, 031102 {{doi|10.1063/1.5043186}}

{{cite journal | last1 = Bilodeau | first1 = R.C. | last2 = Scheer | first2 = M. | last3 = Haugen | first3 = H.K. | year = 1998 | title = Infrared Laser Photodetachment of Transition Metal Negative Ions: Studies on Cr, Mo, Cu, and Ag | journal = Journal of Physics B | volume = 31 | pages = 3885–91 | doi = 10.1088/0953-4075/31/17/013 | s2cid = 250869727 }}

{{cite journal | last1 = Bilodeau | first1 = R.C. | last2 = Scheer | first2 = M. | last3 = Haugen | first3 = H.K. | last4 = Brooks | first4 = R.L. | year = 1999 | title = Near-threshold Laser Spectroscopy of Iridium and Platinum Negative Ions: Electron Affinities and the Threshold Law | journal = Phys. Rev. A | volume = 61 | issue = 1 | page = 012505 | doi = 10.1103/PhysRevA.61.012505 | bibcode = 1999PhRvA..61a2505B }}

{{cite journal | last1 = Bilodeau | first1 = R.C. | last2 = Haugen | first2 = H.K. | year = 2001 | title = Electron affinity of Bi using infrared laser photodetachment threshold spectroscopy | journal = Phys. Rev. A | volume = 64 | issue = 2| page = 024501 | doi = 10.1103/PhysRevA.64.024501 | bibcode = 2001PhRvA..64b4501B }}

{{cite journal | last1 = Blondel | first1 = C. | last2 = Delsart | first2 = C. | last3 = Valli | first3 = C. | last4 = Yiou | first4 = S. | last5 = Godefroid | first5 = M.R. | last6 = Van Eck | first6 = S. | year = 2001 | title = Electron affinities of 16 O, 17 O, 18 O, the fine structure of 16O, and the hyperfine structure of 17O. | journal = Phys. Rev. A | volume = 64 | issue = 5| page = 052504 | doi = 10.1103/PhysRevA.64.052504 | bibcode = 2001PhRvA..64e2504B }}

{{cite journal | last1 = Blondel | first1 = C. | last2 = Delsart | first2 = C. | last3 = Goldfarb | first3 = F. | year = 2001 | title = Electron spectrometry at the μeV level and the electron affinities of Si and F | journal = Journal of Physics B | volume = 34 | pages = L281–88 | doi = 10.1088/0953-4075/34/9/101 | s2cid = 250875182 }}

{{cite journal | last1 = Blondel | first1 = C. | last2 = Cacciani | first2 = P. | last3 = Delsart | first3 = C. | last4 = Trainham | first4 = R. | year = 1989 | title = High Resolution Determination of the Electron Affinity of Fluorine and Bromine using Crossed Ion and Laser Beams | journal = Phys. Rev. A | volume = 40 | issue = 7| pages = 3698–3701 | doi = 10.1103/PhysRevA.40.3698 | pmid = 9902584 | bibcode = 1989PhRvA..40.3698B }}

{{cite journal|last1=Blondel|first1=C.|year=2020|title=Comment on "Measurement of the electron affinity of the lanthanum atom"|journal=Phys. Rev. A|volume=101|issue=1|pages=016501|doi=10.1103/PhysRevA.101.016501|bibcode=2020PhRvA.101a6501B|s2cid=213221561|url=https://hal.archives-ouvertes.fr/hal-02928751/file/AKK1015_rev.pdf}}

{{cite journal|last1=Blondel|first1=C.|last2=Drag|first2=C.|title=Quantum Offset of Velocity Imaging-Based Electron Spectrometry and the Electron Affinity of Arsenic|journal=Phys. Rev. Lett.|volume=134|year=2025|pages=043001|doi=10.1103/PhysRevLett.134.043001}}

{{cite journal | last1 = Bratsch | first1 = S.G. | last2 = Lagowski | first2 = J.J. | year = 1986 | title = Predicted stabilities of monatomic anions in water and liquid ammonia at 298.15 K. | journal = Polyhedron | volume = 5 | issue = 11| pages = 1763–1770 | doi = 10.1016/S0277-5387(00)84854-8 }}

{{cite journal|last1=Bresteau|first1=D.|last2=Babilotte|first2=Ph.|last3=Drag|first3=C.|last4=Blondel|first4 =C.|year=2015|title=Intra-cavity photodetachment microscopy and the electron affinity of germanium|journal=J. Phys. B: At. Mol. Opt. Phys.|volume=48|issue=12|page=125001|doi=10.1088/0953-4075/48/12/125001|bibcode=2015JPhB...48l5001B}}

{{cite journal| last1 = Bresteau | first1 = D.| last2 = Drag | first2 = C. | last3 = Blondel | first3 = C. | year = 2016 | title = Isotope shift of the electron affinity of carbon measured by photodetachment microscopy | journal = Phys. Rev. A | volume = 93 | issue = 1| page = 013414 | doi = 10.1103/PhysRevA.93.013414 | bibcode = 2016PhRvA..93a3414B}}

{{cite journal| last1 = Bresteau | first1 = D.| last2 = Drag | first2 = C. | last3 = Blondel | first3 = C. | year = 2019 | title = Electron affinity of lead | journal = J. Phys. B: At. Mol. Opt. Phys. | volume = 52 | issue = 6| page = 065001 | doi = 10.1088/1361-6455/aaf685 | bibcode = 2019JPhB...52f5001B| s2cid = 125298267}}

{{cite journal| last1 = Carette | first1 = T.| last2 = Drag | first2 = C. | last3 = Scharf | first3 = O. | last4 = Blondel | first4 = C. | last5 = Delsart | first5 = C. | last6 = Fischer | first6 = C. | year = 2000| title = F. & Godefroid M. (2010). Isotope shift in the sulfur electron affinity: Observation and theory | journal = Phys. Rev. A | volume = 81 | page = 042522 | doi = 10.1103/PhysRevA.81.042522 | arxiv = 1002.1297 | s2cid = 54056163}}

{{cite journal|last1=Chaibi|first1=W.|last2=Peláez|first2=R.J.|last3=Blondel|first3=C.|last4=Drag|first4=C.|last5=Delsart|first5=C.|title=Effect of a magnetic field in photodetachment microscopy|doi=10.1140/epjd/e2010-00086-7|journal=Eur. Phys. J. D|volume=58|issue=1|pages=29|year=2010|bibcode=2010EPJD...58...29C |s2cid=17677037 }}

{{cite journal | last1 = Chen | first1 = X. | last2 = Luo | first2 = Z. | last3 = Li | first3 = J. | last4 = Ning | first4 = C. | year = 2016 | title = Accurate Electron Affinity of Iron and Fine Structures of Negative Iron ions | journal = Sci. Rep. | volume = 6 | page = 24996 | doi = 10.1038/srep24996 | pmid = 27138292 | pmc = 4853736 | bibcode = 2016NatSR...624996C | doi-access = free }}

{{cite journal | last1 = Chen | first1 = X. | last2 = Ning | first2 = C. | year = 2016 | title = Accurate electron affinity of Co and fine-structure splittings of Co via slow-electron velocity-map imaging | journal = Phys. Rev. A | volume = 93 | issue = 5| page = 052508 | doi = 10.1103/PhysRevA.93.052508 | bibcode = 2016PhRvA..93e2508C }}

{{cite journal|last1=Davis|first1=V.T.|last2=Thompson|first2=J.S.|year=2001|title=Measurement of the electron affinity of thulium|journal=Phys. Rev. A|volume=65|issue = 1|page=010501|doi=10.1103/PhysRevA.65.010501|bibcode=2001PhRvA..65a0501D|url=https://zenodo.org/record/1233713}}

{{cite journal | last1 = Cheng | first1 = S.B. | last2 = Castleman | first2 = A. W. Jr | year = 2015 | title = Direct experimental observation of weakly-bound character of the attached electron in europium anion | journal = Sci. Rep. | volume = 5 | page = 12414 | doi = 10.1038/srep12414 | pmid = 26198741 | pmc = 4510523 | bibcode = 2015NatSR...512414C | doi-access = free }}

{{Cite journal|last1=Felfli|first1=Z.|last2=Msezane|first2=A.|last3=Sokolovski|first3=D.|title=Resonances in low-energy electron elastic cross sections for lanthanide atoms|doi=10.1103/PhysRevA.79.012714|journal=Phys. Rev. A|volume=79|issue=1|year=2009|page=012714|bibcode=2009PhRvA..79a2714F}}

{{cite journal | last1 = Frey | first1 = P. | last2 = Breyer | first2 = F. | last3 = Hotop | first3 = H. | year = 1978 | title = High Resolution Photodetachment from the Rubidium Negative Ion around the Rb(5p1/2) Threshold. Journal of Physics BJ. Phys. B: At. Mol. Phys | volume = 11 | pages = L589–94 | doi = 10.1088/0022-3700/11/19/005 | journal = Chinese Journal of Chemical Physics }}

{{cite journal|first1=X.-X.|last1=Fu|first2=R.-L.|last2=Tang|first3=Y.-Z.|last3=Lu|first4=C.-G.|last4=Ning|title=Accurate electron affinity of atomic cerium and excited states of its anion|journal=Chin. Phys. B|volume=29|page=073201|year=2020|issue=7 |doi=10.1088/1674-1056/ab90e9|bibcode=2020ChPhB..29g3201F |s2cid=250763618 }}

{{cite journal|last1=Fu|first1=X.X.|last2=Tang|first2=R.L.|last3=Lu|first3=Y.Z.|last4=Ning|first4=C.G.|year=2019|title=Measurement of electron affinity of atomic lutetium via the cryo-SEVI Method|journal=Chinese Journal of Chemical Physics|volume=32|issue=2|page=187|doi=10.1063/1674-0068/cjcp1812293|bibcode=2019ChJCP..32..187F|s2cid=165042639 }}

{{cite journal | last1 = Fu | first1 = X. | last2 = Lu | first2 = Y. | last3 = Tang | first3 = R. | last4 = Ning | first4 = C. | year = 2020 | title = Electron affinity measurements of lanthanide atoms: Pr, Nd, and Tb | journal = Phys. Rev. A | volume = 101 | issue = 2 | page = 022502 | doi = 10.1103/PhysRevA.101.022502 | bibcode = 2020PhRvA.101b2502F | s2cid = 213030610 }}

{{cite journal | last1 = Fu | first1 = X. | last2 = Li | first2 = J. | last3 = Luo | first3 = Z. | last4 = Chen | first4 = X. | last5 = Ning | first5 = C. | year = 2017 | title = Precision measurement of electron affinity of Zr and fine structures of its negative ions. Journal of Chemical Physics J. Chem. Phys | volume = 147 | issue = 6| page = 064306 | doi = 10.1063/1.4986547 | journal = The Journal of Chemical Physics | pmid = 28810756 }}

{{cite journal | last1 = Guo | first1 = Y. | last2 = Whitehead | first2 = M.A. | year = 1989 | title = Electron affinities of alkaline-earth element calculated with the local-spin-density-functional theory. | volume = 40 | issue = 1| pages = 28–34 | doi = 10.1103/PhysRevA.40.28 | journal = Physical Review A | pmid = 9901864 }}

{{cite journal|last1=Haeffler|first1=G.|last2=Hanstorp|first2=D.|last3=Kiyan|first3=I.|last4=Klinkmüller|first4=A.E.|last5=Ljungblad|first5=U.|last6=Pegg|first6=D.J.|year=1996|title=Electron affinity of Li: A state-selective measurement|journal=Phys. Rev. A|volume=53|issue=6|pages=4127–31|doi=10.1103/PhysRevA.53.4127|pmid=9913377|arxiv=physics/9703013|bibcode=1996PhRvA..53.4127H |s2cid=568882 }}

{{cite journal|last1=Haeffler|first1=G.|last2=Klinkmüller|first2=A.E.|last3=Rangell|first3=J.|last4=Berzinsh|first4=U.|last5=Hanstorp|first5=D.|year=1996|title=The electron affinity of tellurium|volume=38|page=211|doi=10.1007/s004600050085|journal=Z. Phys. D|issue=3 |arxiv=physics/9703012|bibcode=1996ZPhyD..38..211H |s2cid=10789594 }}

CRC Handbook of Chemistry and Physics 92nd Edn. (2011–2012); W. M. Haynes. Boca Raton, FL: CRC Press. "Section 10, Atomic, Molecular, and Optical Physics; Electron Affinities".

{{cite journal | last1 = Hotop | first1 = H. | last2 = Lineberger | first2 = W.C. | year = 1985 | title = Binding energies in atomic negative ions. II | journal = J. Phys. Chem. Ref. Data | volume = 14 | issue = 3| page = 731 | doi = 10.1063/1.555735 | bibcode = 1985JPCRD..14..731H }}

{{cite journal|last1=Kristiansson|first1=M.K.|last2=Chartkunchand|first2=K.|last3=Eklund|first3=G.|display-authors=etal|title=High-precision electron affinity of oxygen|journal=Nat Commun|volume=13|page=5906|year=2022|issue=1 |doi=10.1038/s41467-022-33438-y|pmid=36207329 |pmc=9546871 |bibcode=2022NatCo..13.5906K |doi-access=free}}

{{cite journal | last1 = Landau | first1 = A. | last2 = Eliav | first2 = E. | last3 = Ishikawa | first3 = Y. | last4 = Kaldor | first4 = U. | year = 2001 | title = Benchmark calculations of electron affinities of the alkali atoms sodium to eka-francium (element 119) | journal = J. Chem. Phys. | volume = 115 | issue = 6| page = 2389 | doi = 10.1063/1.1386413 | bibcode = 2001JChPh.115.2389L }}

{{cite journal|last1=Leimbach|first1=D.|display-authors=etal|year=2020|title=The electron affinity of astatine|journal=Nat. Commun.|volume=11|issue=1|page=3824|doi=10.1038/s41467-020-17599-2|pmid=32733029|pmc=7393155|arxiv=2002.11418 |bibcode=2020NatCo..11.3824L |doi-access=free}}

{{cite journal | last1 = Junqin | first1 = Li | last2 = Zilong | first2 = Zhao | last3 = Martin | first3 = Andersson | last4 = Xuemei | first4 = Zhang | last5 = Chongyang | first5 = Chen | year = 2012 | title = Theoretical study for the electron affinities of negative ions with the MCDHF method | journal = J. Phys. B: At. Mol. Opt. Phys. | volume = 45 | issue = 16| page = 165004 | doi = 10.1088/0953-4075/45/16/165004 | bibcode = 2012JPhB...45p5004L | s2cid = 121023909 }}

Luo Z., Chen X., Li J. & Ning C. (2016). Precision measurement of the electron affinity of niobium. Phys. Rev. A 93, 020501(R) {{doi|10.1103/PhysRevA.93.020501}}

Lu Y., Zhao J., Tang R., Fu X. & Ning C. (2020). "Measurement of electron affinity of

iridium atom and photoelectron angular distributions of iridium anion". J. Chem. Phys. 152, 034302 {{doi|10.1063/1.5134535}}

{{cite journal | last1 = Fu | first1 = X. | last2 = Luo | first2 = Z. | last3 = Chen | first3 = X. | last4 = Li | first4 = J. | last5 = Ning | first5 = C. | year = 2016 | title = Accurate electron affinity of V and fine-structure splittings of V via slow-electron velocity-map imaging | journal = J. Chem. Phys. | volume = 145 | issue = 16| page = 164307 | doi = 10.1063/1.4965928 | pmid = 27802620 | bibcode = 2016JChPh.145p4307F }}

{{cite journal|last1=Lykke|first1=K.R.|last2=Murray|first2=K.K.|last3=Lineberger|first3=W.C.|year=1991|title=Threshold Photodetachment of H|url=https://zenodo.org/record/1233707|volume=43|issue=11|pages=6104–7|doi=10.1103/PhysRevA.43.6104|journal=Phys. Rev. A|pmid=9904944|bibcode=1991PhRvA..43.6104L }}

{{cite journal|last1=Nadeau|first1=M. J.|last2=Garwan|first2=M. A.|last3=Zhao|first3=X. L.|last4=Litherland|first4=A. E.|year=1997|title=A negative ion survey; towards the completion of the periodic table of the negative ions|journal=Nuclear Instruments and Methods in Physics Research B|volume=123|issue=1–4 |pages=521–526|doi=10.1016/S0168-583X(96)00749-5|bibcode=1997NIMPB.123..521N }}

{{cite journal|last1=Ning|first1=Chuangang|last2=Lu|first2=Yuzhu|year=2022|title=Electron Affinities of Atoms and Structures of Atomic Negative Ions|journal=J. Phys. Chem. Ref. Data|volume=51|issue=2 |page=021502|doi=10.1063/5.0080243|bibcode=2022JPCRD..51b1502N |s2cid=248844032 }}

{{cite journal|title=Pulsed photodetachment microscopy and the electron affinity of iodine|last1=Peláez|first1=R.J.|last2=Blondel|first2=C.|last3=Delsart|first3=C.|last4=Drag|first4=C.|year=2009|journal=J. Phys. B|volume=42|issue=12 |page=125001|doi=10.1088/0953-4075/42/12/125001|bibcode=2009JPhB...42l5001P |s2cid=123302487 }}

{{cite journal|last1=Peláez|first1=R.J.|last2=Blondel|first2=C.|last3=Vandevraye|first3=M.|last4=Drag|first4=C.|last5=Delsart|first5=C.|year=2011|title=Photodetachment microscopy to an excited spectral term and the electron affinity of phosphorus|journal=J. Phys. B: At. Mol. Opt. Phys.|volume=44|issue=19|page=195009|doi=10.1088/0953-4075/44/19/195009|bibcode=2011JPhB...44s5009P|hdl=10261/62382|s2cid=12279331|hdl-access=free}}

{{cite journal | last1 = Petrunin | first1 = V.V. | last2 = Volstad | first2 = J.D. | last3 = Balling | first3 = P. | last4 = Kristensen | first4 = K. | last5 = Andersen | first5 = T. | year = 1995 | title = Resonant Ionization Spectroscopy of Ba: Metastable and Stable Ions | journal = Phys. Rev. Lett. | volume = 75 | issue = 10| pages = 1911–14 | doi = 10.1103/PhysRevLett.75.1911 | pmid = 10059160 | bibcode = 1995PhRvL..75.1911P}}

{{cite journal | last1 = Petrunin | first1 = V.V. | last2 = Andersen | first2 = H.H. | last3 = Balling | first3 = P. | last4 = Andersen | first4 = T. | year = 1996 | title = Structural Properties of the Negative Calcium Ion: Binding Energies and Fine-structure Splitting | journal = Phys. Rev. Lett. | volume = 76 | issue = 5| pages = 744–47 | doi = 10.1103/PhysRevLett.76.744 | pmid = 10061539 | bibcode = 1996PhRvL..76..744P }}

{{cite journal | last1 = Rothe | first1 = S. | last2 = Sundberg | first2 = J. | last3 = Welander | first3 = J. | last4 = Chrysalidis | first4 = K. | last5 = Goodacre | first5 = T. | year = 2017| title = D., Fedosseev V., ... & Kron T. (2017). Laser photodetachment of radioactive 128I. | journal = J. Phys. G: Nucl. Part. Phys. | volume = 44 | page = 104003 | doi = 10.1088/1361-6471/aa80aa | doi-access = free }}

{{cite journal | last1 = Scheer | first1 = M. | last2 = Bilodeau | first2 = R.C. | last3 = Haugen | first3 = H.K. | year = 1998 | title = Negative ion of boron: An experimental study of the 3P ground state | journal = Phys. Rev. Lett. | volume = 80 | issue = 12| pages = 2562–65 | doi = 10.1103/PhysRevLett.80.2562 | bibcode = 1998PhRvL..80.2562S }}

{{cite journal|last1=Scheer|first1=M.|last2=Brodie|first2=C.A.|last3=Bilodeau|first3=R.C.|last4=Haugen|first4=H.K.|year=1998|title=Laser spectroscopic measurements of binding energies and fine-structure splittings of Co, Ni, Rh, and Pd.|journal=Phys. Rev. A|volume=58|issue=3|pages=2051–62|doi=10.1103/PhysRevA.58.2051 |bibcode=1998PhRvA..58.2051S }}

{{cite journal | last1 = Scheer | first1 = M. | last2 = Haugen | first2 = H.K. | last3 = Beck | first3 = D.R. | year = 1997 | title = Single- and Multiphoton Infrared Laser Spectroscopy of Sb: A Case Study | journal = Phys. Rev. Lett. | volume = 79 | issue = 21| pages = 4104–7 | doi = 10.1103/PhysRevLett.79.4104 | bibcode = 1997PhRvL..79.4104S }}

{{cite journal|last1=Scheer|first1=M.|last2=Bilodeau|first2=R.C.|last3=Thøgersen|first3=J.|last4=Haugen|first4=H.K.|year=1998|title=Threshold Photodetachment of Al: Electron Affinity and Fine Structure|journal=Phys. Rev. A|volume=57|issue=3|pages=R1493–96|doi=10.1103/PhysRevA.57.R1493|bibcode=1998PhRvA..57.1493S }}

{{cite journal|first1=R.|last1=Tang|first2=X.|last2=Fu|first3=Y.|last3=Lu|first4=C.|last4=Ning|title=Accurate electron affinity of Ga and fine structures of its anions|journal=J. Chem. Phys.|volume=152|page=114303|year=2020|issue=11 |doi=10.1063/1.5144962|pmid=32199425 |bibcode=2020JChPh.152k4303T |s2cid=214617280 }}

Tang R., Chen X., Fu X., Wang H. and Ning C. (2018). Electron affinity of the hafnium atom. Phys. Rev. A 98 020501(R) {{doi|10.1103/PhysRevA.98.020501}}.

Tang R., Si R., Fei Z., Fu X., Lu Y., Brage T., Liu H., Chen C. & Ning C. (2019). "Candidate for Laser Cooling of a Negative Ion:

High-Resolution Photoelectron Imaging of Th". Phys. Rev. Lett. 123, 203002 {{doi|10.1103/PhysRevLett.123.203002}}

{{cite journal | last1 = Tang | first1 = R. | last2 = Fu | first2 = X. | last3 = Ning | first3 = C. | year = 2018 | title = Accurate electron affinity of Ti and fine structures of its anions | journal = J. Chem. Phys. | volume = 149 | issue = 13| page = 134304 | doi = 10.1063/1.5049629 | pmid = 30292212 | bibcode = 2018JChPh.149m4304T | s2cid = 52934687 }}

Tang R., Lu Y., Liu H. & Ning C. (2021). "Electron affinity of uranium and bound states of opposite parity in its anion". Phys. Rev. A 103, L050801 {{doi|10.1103/PhysRevA.103.L050801}}

{{cite journal | last1 = Vandevraye | first1 = M. | last2 = Drag | first2 = C. | last3 = Blondel | first3 = C. | year = 2012 | title = Electron affinity of selenium measured by photodetachment microscopy | journal = Phys. Rev. A | volume = 85 | issue = 1| page = 015401 | doi = 10.1103/PhysRevA.85.015401 | bibcode = 2012PhRvA..85a5401V }}

{{Cite journal|last1=Vandevraye|first1=M.|last2=Drag|first2=C.|last3=Blondel|first3=C.|doi=10.1088/0953-4075/46/12/125002|title= Electron affinity of tin measured by photodetachment microscopy|journal=Journal of Physics B: Atomic, Molecular and Optical Physics|volume=46|issue=12|pages=125002|year=2013|bibcode=2013JPhB...46l5002V|s2cid=121556183 }}

{{cite journal | last1 = Walter | first1 = C.W. | last2 = Gibson | first2 = N.D. | last3 = Carman | first3 = D.J. | last4 = Li | first4 = Y.-G. | last5 = Matyas | first5 = D.J. | year = 2010 | title = Electron affinity of indium and the fine structure of In measured using infrared photodetachment threshold spectroscopy | journal = Phys. Rev. A | volume = 82 | issue = 3| page = 032507 | doi = 10.1103/PhysRevA.82.032507 | bibcode = 2010PhRvA..82c2507W }}

{{cite journal|last1=Walter|first1=C.W.|last2=Gibson|first2=N.D.|last3=Spielman|first3=S.E.|year=2020|title=Electron affinity of thallium measured with threshold spectroscopy|journal=Phys. Rev. A|volume=101|issue=5|page=052511|doi=10.1103/PhysRevA.101.052511|bibcode=2020PhRvA.101e2511W |s2cid=219489520 }}

{{cite journal | last1 = Chen | first1 = X.L. | last2 = Ning | first2 = C.G. | year = 2017 | title = Observation of Rhenium Anion and Electron Affinity of Re. | journal = J. Phys. Chem. Lett. | volume = 8 | issue = 12| pages = 2735–2738 | doi = 10.1021/acs.jpclett.7b01079 | pmid = 28581753 }}

}}

See also