Electrostriction

Electrostriction is a property of all dielectric materials, and is caused by displacement of ions in the crystal lattice upon being exposed to an external electric field. The cause of electrostrictive is linked to anharmonic effects. Positive ions will be displaced in the direction of the field, while negative ions will be displaced in the opposite direction. This displacement will accumulate throughout the bulk material and result in an overall strain (elongation) in the direction of the field. The thickness will be reduced in the orthogonal directions characterized by Poisson's ratio. All insulating materials consisting of more than one type of atom will be ionic to some extent due to the difference of electronegativity of the atoms, and therefore exhibit electrostriction.{{citation needed|date=August 2024}}

The resulting strain (ratio of deformation to the original dimension) is proportional to the square of the polarization. Reversal of the electric field does not reverse the direction of the deformation.{{rp|664}}

More formally, the electrostriction coefficient is a rank four tensor ($Q\_\{ijkl\}$), relating the rank two strain tensor ($\backslash varepsilon\_\{ij\}$) and the electric polarization density vector (i.e. rank one tensor; $P\_k$){{cite journal | last1=Yu | first1=Jiacheng | last2=Janolin | first2=Pierre-Eymeric | title=Defining "giant" electrostriction | journal=Journal of Applied Physics | publisher=AIP Publishing | volume=131 | issue=17 | date=2022-05-05 | issn=0021-8979 | doi=10.1063/5.0079510 | page=| arxiv=2110.11304 | bibcode=2022JAP...131q0701Y }}

:$\backslash varepsilon\_\{ij\}\; =\; Q\_\{ijkl\}P\_k\; P\_l.$

The electrostrictive tensor satisfies{{rp|666}}

:$Q\_\{ijkl\}\; =\; \backslash frac\{1\}\{2\}\backslash frac\{\backslash partial^2\backslash varepsilon\_\{ij\}\}\{\backslash partial\; P\_k\; \backslash partial\; P\_l\}.$

The related piezoelectric effect occurs only in a particular class of dielectrics. Electrostriction applies to all crystal symmetries, while the piezoelectric effect only applies to the 20 piezoelectric point groups. Piezoelectricity is a result of electrostrictive in ferroelectric materials. Electrostriction is a quadratic effect, unlike piezoelectricity, which is a linear effect.{{rp|665}}

Although all dielectrics exhibit some electrostriction, certain engineered ceramics, known as relaxor ferroelectrics, have extraordinarily high electrostrictive constants. The most commonly used are

• lead magnesium niobate (PMN)
• lead magnesium niobate-lead titanate (PMN-PT)
• lead lanthanum zirconate titanate (PLZT)

Electrostriction can produce a strain on the order of 0.1% for some materials.{{rp|662}} This occurs at a field strength of 2 million volts per meter (2 MV/m) for the material PMN-15.{{cite web | title=Electrostrictive Ceramics | website=TRS Ceramics | url=https://www.trstechnologies.com/Materials/Electrostrictive-Ceramics | access-date=2024-08-09}} Electrostriction exists in all materials, but is generally negligible.{{rp|662}}

• Sonar projectors for submarines and surface vessels
• Actuators for small displacements
• Sensors, provided a bias electric field or pre-stress is present.

• Magnetostriction
• Photoelasticity
• Piezomagnetism
• Piezoelectricity
• Relaxor ferroelectric

{{reflist}}

• [http://www.britannica.com/science/electrostriction "Electrostriction." Encyclopædia Britannica.]
• Mini dictionary of physics (1988) Oxford University Press
• [http://www.tf.uni-kiel.de/matwis/amat/elmat_en/kap_3/backbone/r3_6_1.html#_dum_3 "Electronic Materials"] by Prof. Dr. Helmut Föll

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Category:Materials science

Category:Electric and magnetic fields in matter