Enthalpy of sublimation

{{Short description|Heat required to change one mole of substance from solid to gas}}

{{More citations needed|date=January 2021}}

In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid. For elemental metals, it is also equal to the standard enthalpy of formation of the gaseous metal atoms. The heat of sublimation is usually expressed in kJ/mol, although the less customary kJ/kg is also encountered.

Sublimation enthalpies

class="wikitable"

!symbol

!substances

!Sublimation enthalpy (kJ/mol)

Li

|lithium

|159Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113

Na

|sodium

|107

K

|potassium

|89

Rb

|rubidium

|81

Cs

|caesium

|76

Mg

|magnesium

|148

Ca

|calcium

|178

Sr

|strontium

|164

Ba

|barium

|180

Fe

|iron

|416

Ni

|nickel

|430

Cu

|copper

|338

Zn

|zinc

|131

Ag

|silver

|285

W

|tungsten

|849

Au

|gold

|366

C

|graphite

|717

C

|diamond

|715

Si

|silicon

|456

Sn

|tin

|302

Pb

|lead

|195

Fm

|fermium

|141{{Cite journal|last=Haire|first=Richard G.|last2=Gibson|first2=John K.|title=The enthalpy of sublimation and thermodynamic functions of fermium|url=https://pubs.aip.org/aip/jcp/article-abstract/91/11/7085/95919/The-enthalpy-of-sublimation-and-thermodynamic|journal=The Journal of Chemical Physics|language=en|volume=91|pages=7085–7096|doi=10.1063/1.457326|url-access=subscription}}

I2

|iodine

|62.4{{Cite journal|last=Chickos|first=James S.|last2=Acree|first2=William E.|date=2002|title=Enthalpies of Sublimation of Organic and Organometallic Compounds. 1910–2001|url=http://aip.scitation.org/doi/10.1063/1.1475333|journal=Journal of Physical and Chemical Reference Data|language=en|volume=31|issue=2|pages=537–698|doi=10.1063/1.1475333|issn=0047-2689}}

C10H8

|naphthalene

|72.9

CO2

|carbon dioxide

|25

H2O

|water

|51.1

See also

References

{{Reflist|30em}}

{{States of matter}}

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Category:Enthalpy