Ethyl azide
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 429889878
| ImageFile = Ethyl azide.svg
| ImageSize = 190
| ImageAlt = Skeletal formula of ethyl azide
| ImageFile1 = Ethyl-azide-3D-balls.png
| ImageSize1 = 180
| ImageAlt1 = Ball-and-stick model of the ethyl azide molecule
| PIN =Azidoethane
| OtherNames = Ethane, azido-; 1-Azidoethane
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|changed|??}}
| CASNo = 871-31-8
| UNNumber =
| PubChem =79118
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 71449
| SMILES = [N-]=[N+]=N/CC
| InChI = 1/C2H5N3/c1-2-4-5-3/h2H2,1H3
| InChIKey = UCSVJZQSZZAKLD-UHFFFAOYAG
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/C2H5N3/c1-2-4-5-3/h2H2,1H3
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = UCSVJZQSZZAKLD-UHFFFAOYSA-N
}}
|Section2={{Chembox Properties
| Formula = {{chem2|CH3CH2N3}}
| C=2|H=5|N=3
| Appearance = liquid
| Density =
| MeltingPt =
| BoilingPt = 50
| Solubility =
| SolubleOther =
}}
|Section3={{Chembox Explosive
| ShockSens = High
| FrictionSens = High
| DetonationV =
| REFactor = }}
|Section4={{Chembox Thermochemistry
| DeltaHc =
| DeltaHf = 266.872
| Entropy =
| HeatCapacity = }}
|Section5={{Chembox Hazards
| MainHazards = Harmful, Explosive
| FlashPt =
| AutoignitionPt = }}
|Section8={{Chembox Related
| OtherAnions =
| OtherCations =
| OtherFunction =
| OtherFunction_label =
| OtherCompounds = Hydrazoic acid, Chlorine azide, Methyl azide }}
}}
Ethyl azide ({{chem2|CH3CH2N3}}) is an explosive compound sensitive to rapid heating, shock or impact. It has exploded when heated to room temperature.{{cite journal | last1 = Campbell | first1 = H. C. | last2 = Rice | first2 = O. K. | title = The Explosion of Ethyl Azide | journal = Journal of the American Chemical Society | year = 1935 | volume = 57 | issue = 6 | pages = 1044–1050 | doi = 10.1021/ja01309a019 }}{{ cite journal | last1 = Rice | first1 = O. K. | last2 = Campbell | first2 = H. C. | title = The Explosion of Ethyl Azide in the Presence of Diethyl Ether | journal = The Journal of Chemical Physics | year = 1939 | volume = 7 | issue = 8 | pages = 700–709 | doi = 10.1063/1.1750516 | bibcode = 1939JChPh...7..700R | doi-access = free }} When heated to decomposition it emits toxic fumes of NOx.{{cite journal | last1 = Rice | first1 = O. K. | title = The Role of Heat Conduction in Thermal Gaseous Explosions | journal = The Journal of Chemical Physics | year = 1940 | volume = 8 | issue = 9 | pages = 727–733 | doi = 10.1063/1.1750808 | bibcode = 1940JChPh...8..727R }}{{cite journal | last1 = Costa Cabral | first1 = B. J. | last2 = Costa | first2 = M. L. | last3 = Almoster Ferreira | first3 = M. A. | title = ChemInform Abstract: Molecular Structure and Ionization Energies of Azides: An ab initio Study of Hydrazoic Acid, Methyl Azide and Ethyl Azide | journal = ChemInform | year = 2010 | volume = 24 | issue = 37 | pages = no | doi = 10.1002/chin.199337053 }}
It is irritating to eyes, respiratory system and skin.
Uses
Ethyl azide is used for organic synthesis.