Gallium acetate
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| Name = Gallium acetate
| ImageFile = Gallium acetate.png
| ImageCaption =
| ImageName = Gallium acetate
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| IUPACNames = Tetra-μ2-acetatodiaquadigallium(III), diacetyloxygallanyl acetate
gallium(3+) triacetate
| OtherNames = {{Unbulleted list
| Gallium ethanoate
| Gallium triacetate
| Gallium(III) acetate
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| Section1 = {{Chembox Identifiers
| ChemSpiderID = 144647
| EC_number = 219-915-3
| CASNo = 2571-06-4
| PubChem = 16704853
| UNII =
| StdInChI=1S/3C2H4O2.Ga/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3
| StdInChIKey = FYWVTSQYJIPZLW-UHFFFAOYSA-K
| SMILES = CC(=O)O[Ga](OC(=O)C)OC(=O)C
}}
| Section2 = {{Chembox Properties
| Formula = Ga(O2C2H3)3
| MolarMass = 246.85{{Cite web | url=https://pubchem.ncbi.nlm.nih.gov/compound/Gallium-acetate | title=Gallium acetate }}
| Appearance = white crystals
| Density = 1.57 g/cm/3
| MeltingPt = N/A
| BoilingPt = 117.1C
| Solubility =
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| Section3 = {{Chembox Structure
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| Section4 = {{Chembox Hazards
| GHSPictograms = {{GHS05}}{{GHS07}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|314|335}}
| PPhrases = {{P-phrases|261|280|305+351+338|304+340|405|501}}
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Gallium acetate is a salt composed of a gallium atom trication and three acetate groups as anions where gallium exhibits the +3 oxidation state. It has a chemical formula of Ga(CH3COO)3 although it can be informally referred to as GaAc{{dubious|date=May 2025}} because Ac is an informal symbol for acetate. Gallium is moderately water-soluble and decomposes to gallium oxide when heated to around 70 °C. Gallium acetate, like other acetate compounds, is a good precursor to ultra-pure compounds, catalysts and nanoscale materials.{{Cite web |last=Elements |first=American |title=Gallium Acetate |url=https://www.americanelements.com/gallium-acetate-2571-06-4 |access-date=2022-05-05 |website=American Elements |language=en}} Gallium acetate is being considered as a substitute in de-icing compounds like calcium chloride and magnesium chloride.{{Cite web |title=Gallium acetate, 99.9% 2571-06-4 - Manufacturers & Suppliers in India with worldwide shipping. |url=https://www.ottokemi.com/gallium-compounds/gallium-acetate-pure.aspx |access-date=2022-05-05 |website=www.ottokemi.com}}
Preparation
Gallium acetate can be formed using a neutralization reaction (acetic acid reacts with gallium oxide or gallium hydroxide):
:6CH3COOH + Ga2O3 → 2Ga(CH3COO)3 + 3H2O
:3CH3COOH + Ga(OH)3 → Ga(CH3COO)3 + 3H2O
Gallium can also be refluxed in acetic acid for several weeks to produce gallium acetate.Funk, H.; Paul, A. Chemistry of gallium. II. Reactions between gallium and organic compounds. Zeitschrift für Anorganische und Allgemeine Chemie (1965), 337(3-4), 142-4.
Applications
It can also be used in conjunction with acetylacetonate bis(thiosemicarbazone) to create radiogallium-acetylacetonate bis(thiosemicarbazone) complex. It can be used in tumor imaging.{{Cite journal |last=Jalilian |first=Amir R. |last2=Yousefnia |first2=Hassan |last3=Garousi |first3=Javad |last4=Novinrouz |first4=Aytak |last5=Rajamand |first5=Amir A. |last6=Shafaee |first6=Kamaledin |date=2009 |title=The development of radiogallium-acetylacetonate bis(thiosemicarbazone) complex for tumour imaging |url=https://journals.viamedica.pl/nuclear_medicine_review/article/view/15208 |journal=Nuclear Medicine Review |volume=12 |issue=2 |pages=65–71 |issn=1644-4345}}
See also
References
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{{Gallium compounds}}
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{{Acetates}}