Gold(I) fluoride

{{Other uses|Gold fluoride}}

{{redirect|AuF||AUF (disambiguation)}}

{{chembox

| Section1 = {{Chembox Identifiers

| ChemSpiderID = 10605696

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| SMILES = [Au]F

| PubChem = 21225580

| StdInChI = 1S/Au.FH/h;1H/q+1;/p-1

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = SDQPNEPNURFLTA-UHFFFAOYSA-M

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

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| Section2 = {{Chembox Properties

| Au = 1 | F = 1

}}

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Gold(I) fluoride is the inorganic compound with the formula AuF. The solid has eluded isolation, but its existence has been observed by rotational spectroscopy{{cite journal | doi = 10.1021/ja9938985 | title = Confirmation of the Existence of Gold(I) Fluoride, AuF: Microwave Spectrum and Structure | year = 2000 | last1 = Evans | first1 = Corey J. | last2 = Gerry | first2 = Michael C. L. | journal = Journal of the American Chemical Society | volume = 122 | issue = 7 | pages = 1560}} and mass spectrometry as a gas.{{cite journal | doi = 10.1002/anie.199402121 | title = Neutral Gold(I) Fluoride Does Indeed Exist | year = 1994 | last1 = Schröder | first1 = Detlef | last2 = Hrušák | first2 = Jan | last3 = Tornieporth-Oetting | first3 = Inis C. | last4 = Klapötke | first4 = Thomas M. | last5 = Schwarz | first5 = Helmut | journal = Angewandte Chemie International Edition in English | volume = 33 | issue = 2 | pages = 212}}

When stabilized by an NHC ligand, a gold fluoride complex has been characterized.{{cite journal|title=A Carbene-Stabilized Gold(I) Fluoride: Synthesis and Theory|author1=David S. Laitar| author2=Peter Müller|author3=Thomas G. Gray|author4=Joseph P. Sadighi|journal=Organometallics|year=2005|volume=24|issue=19|pages=4503–4505|doi=10.1021/om050619f}}

References

{{reflist}}

{{Gold compounds}}

{{Fluorides}}

Category:Gold(I) compounds

Category:Fluorides

Category:Metal halides

Category:Gold–halogen compounds

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