Gold(I) sulfide
{{chembox
| Watchedfields = changed
| verifiedrevid = 437209378
| Name = Gold(I) sulfide
| ImageFile = Gold(I)-sulfide-xtal-1995-unit-cell-CM-3D-balls.png
| ImageSize = 150px
| ImageName = Gold(I) sulfide unit cell
| IUPACName = Gold(I) sulfide
| OtherNames = Aurous sulfide
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 14028556
| InChI = 1S/2Au.S/q2*+1;-2
| SMILES = [S-2].[Au+].[Au+]
| InChIKey = YVIYNOINIIHOCG-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 1303-60-2
| PubChem = 22904715
| RTECS =
| EINECS = 215-123-7
| UNII = 03VC3O9F7W
}}
|Section2={{Chembox Properties
| Formula = {{chem2|Au2S}}
| MolarMass = 425.998 g/mol
| Appearance =
| Density = 11 g/cm3{{cite book |editor1-last=Perry |editor1-first=Dale |title=Handbook of Inorganic Compounds |date=1995 |isbn=9780849386718 |page=184 |language=English}}
| Solubility = Insoluble
| SolubleOther =
| Solvent =
| MeltingPtC = 240
| BoilingPtC =
| BandGap =
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|Section3={{Chembox Structure
| Coordination =
| CrystalStruct =
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|Section7={{Chembox Hazards
| ExternalSDS =
| NFPA-H =
| NFPA-F =
| NFPA-R =
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|Section8={{Chembox Related
| OtherAnions = Copper(I) sulfide
| OtherCations =
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Gold(I) sulfide is the inorganic compound with the formula {{chem2|Au2S}}. It is the principal sulfide of gold. It decomposes to gold metal and elemental sulfur, illustrating the "nobility" of gold.
Structure and preparation
The compound crystallizes in the motif seen for cuprous oxide: gold is 2-coordinate, sulfur 4-coordinate, and the S-Au-S linkage is linear.Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. {{ISBN|0-19-855370-6}}. Linear coordination geometry is typical of gold(I) compounds, e.g. the coordination complex chloro(dimethyl sulfide)gold(I). The structure is similar to the α form of silver sulfide (argentite), which only exists at high temperatures.
It can be prepared by treating gold chloride with hydrogen sulfideN. N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997. It also arises by sulfiding dicyanoaurate:
:{{chem2|H2S + 2 K[Au(CN)2] → Au2S + 2 KCN + 2 HCN}}
This product is described as "initially dark reddish-brown" solid that turns "steel-gray".{{cite journal|doi=10.1063/1.1673931|title=Mössbauer Spectroscopy of Gold Compounds|year=1970|last1=Faltens|first1=Marjorie O.|journal=The Journal of Chemical Physics|volume=53|issue=11|pages=4249–4264|bibcode=1970JChPh..53.4249F}}{{cite journal|doi=10.1016/0167-2738(95)00030-A|title=Structure and Electrical Properties of Au2S|journal=Solid State Ionics|volume=79|pages=60–66|year=1995|last1=Ishikawa|first1=K.}}
References
{{reflist}}
{{Gold compounds}}
{{Sulfides}}