Golyshevite
{{Short description|Rare cyclosilicate mineral}}
{{infobox mineral
| name = Golyshevite
| category = Silicate mineral, cyclosilicate
| image = Golyshevite.jpg
| imagesize =
| alt =
| caption = Golyshevite crystals in matrix, some of them showing a pseudohexagonal section, with the typical yellowish-brown zircon-like colour. Locality: Kovdor Phlogopite Mine, Kovdor Massif, Northern Region, Russian Federation
Size: 2.3 × 2.1 × 1.5 cm
| formula = (Na,Ca)10Ca9(Fe3+,Fe2+)2Zr3NbSi25O72(CO3)(OH)3·H2O (original form)
| strunz = 9.CO.10
| dana = 64.1.6
| system = Trigonal
| class = Ditrigonal pyramidal (3m)
(same H-M symbol)
| symmetry = R3m
| unit cell = a = 14.23
c = 29.98 [Å] (approximated); Z = 3
| color = Brown to reddish-brown
| colour =
| habit = Grains and crystals
| twinning =
| cleavage = No
| fracture =
| tenacity = Brittle
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| gravity = 2.89 (measured)
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| opticalprop = Uniaxial (−)
| refractive = nω = 1.62, nε = 1.61 (approximated)
| birefringence =
| pleochroism = Green to pale yellow
| 2V =
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}}
Golyshevite is a rare mineral of the eudialyte group,Mindat, Golyshevite, http://www.mindat.org/min-27418.html with the formula Na10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3•H2O. The original formula was extended to show both the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of the eudialyte group.Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785-794 The characteristic feature of golyshevite is calcium-rich composition, with calcium at two main sites instead of one site.Chukanov, N.V., Moiseyev, M.M., Rastsvetayeva, R.K., Rozenberg, K.A., and Zadov, A.E., 2005. Golyshevite (Na,Ca)10Ca9(Fe3+,Fe2+)2Zr3NbSi25O72(CO3)(OH)3·H2O, and Mogovidite, Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si25O72(CO3)(OH,H2O)4, new eudialyte-group minerals from calcium-rich agpaitic pegmatites of the Kovdor massif, Kola Peninsula. Zapiski Rossiyskogo Mineralogicheskogo Obshchestva 134(6), 36-47 (in Russian, with English abstract) Together with feklichevite, fengchengite, ikranite and mogovidite it is a ferric-iron-dominant representative of the group. It is chemically similar to mogovidite. Golyshevite was named after Russian crystallographer Vladimir Mikhailovich Golyshev.
Occurrence and association
Golyshevite and mogovidite were found in calcium-bearing peralkaline pegmatites of the Kovdor massif, Kola Peninsula, Russia. Minerals associated with golyshevite are aegirine-augite, calcite, cancrinite, hedenbergite, orthoclase, pectolite, tacharanite, and thomsonite-Ca.