Hemihedrite

{{Short description|Rare lead zinc chromate silicate mineral}}

{{infobox mineral

| name = Hemihedrite

| image = Hemihedrite-phoenicochroite-537207.jpg

| imagesize = 260px

| alt =

| caption = Red phoenicochroite and orange hemihedrite microcrystals richly cover the matrix

| category = Chromate mineral

| formula = Pb10Zn(CrO4)6(SiO4)2(F,OH)2

| IMAsymbol = Hhe{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}

| molweight =

| strunz = 7.FC.15

| dana =

| system = Triclinic

| symmetry = P{{overline|1}} (No. 2)

| unit cell = a = 9.49, b = 11.44
c = 10.84 [Å]; α = 120.5°
β = 92.1°, γ = 55.83°; Z = 1

| color = Bright orange, henna-brown, to almost black

| colour =

| habit = Euhedral crystals with hemihedral morphology

| twinning = Present

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| mohs = 3

| luster = Vitreous

| streak = Saffron-yellow

| diaphaneity = Translucent to transparent

| gravity = 6.42

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| opticalprop = Biaxial (+)

| refractive = nα = 2.105 nβ = 2.320 nγ = 2.650

| birefringence = δ = 0.545

| pleochroism = Feeble, yellow to orange

| 2V = 88° (measured)

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| references = [http://rruff.info/doclib/hom/hemihedrite.pdf Handbook of Mineralogy][http://www.mindat.org/min-1859.html Hemihedrite on Mindat.org][http://www.webmineral.com/data/Hemihedrite.shtml Hemihedrite data on Webmineral][https://www.mineralienatlas.de/lexikon/index.php/MineralData?mineral=Hemihedrite Mineralienatlas]{{cite journal |last1=McLean |first1=W.J. |last2=Anthony |first2=J.W. |journal=American Mineralogist |volume=55 |year=1970 |pages=1103–1114 |title=The crystal structure of hemihedrite}}

}}

Hemihedrite is a rare lead zinc chromate silicate mineral with formula Pb10Zn(CrO4)6(SiO4)2(F,OH)2. It forms a series with the copper analogue iranite.

Discovery and occurrence

Hemihedrite was first described in 1967 for occurrences in the Florence lead silver mine in the Ripsey District, Tortilla Mountains, Pinal County, Arizona, US. It was named for the hemihedral morphology of its crystals.

It occurs in oxidized veins containing galena, sphalerite and pyrite. Associated secondary minerals include cerussite, phoenicochroite, vauquelinite, willemite, wulfenite, galena, sphalerite, pyrite, tennantite and chalcopyrite. It has been reported from several mining districts in Arizona and one in Nevada. It has also been reported from the Antofagasta Region of Chile and the Anarak District of Esfahan Province, Iran.

References