Hydrolysis constant
The word hydrolysis is applied to chemical reactions in which a substance reacts with water. In organic chemistry, the products of the reaction are usually molecular, being formed by combination with H and OH groups (e.g., hydrolysis of an ester to an alcohol and a carboxylic acid). In inorganic chemistry, the word most often applies to cations forming soluble hydroxide or oxide complexes with, in some cases, the formation of hydroxide and oxide precipitates.
Metal hydrolysis and associated equilibrium constant values
The hydrolysis reaction for a hydrated metal ion in aqueous solution can be written as:
:p Mz+ + q H2O ⇌ Mp(OH)q(pz–q) + q H+
and the corresponding formation constant as:
:
and associated equilibria can be written as:
:MOx(OH)z–2x(s) + z H+ ⇌ Mz+ + (z–x) H2O
:MOx(OH)z–2x(s) + x H2O ⇌ Mz+ + z OH−
:p MOx(OH)z–2x(s) + (pz–q) H+ ⇌ Mp(OH)q(pz–q) + (pz–px–q) H2O
= Aluminium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=121}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=757–797}} !Hummel and Thoenen, 2023{{Cite book |last=Hummel |first=W. |title=Technical Report 21-03. The PSI Chemical Thermodynamic Database 2020 |last2=Thoenen |first2=T. |publisher=NAGRA |year=2023 |location=Wettingen |pages=252–259}} |
Al3+ + H2O ⇌ AlOH2+ + H+
|–4.97 |−4.98 ± 0.02 |−4.98 ± 0.02 |
Al3+ + 2 H2O ⇌ Al(OH)2+ + 2 H+
|–9.3 |−10.63 ± 0.09 |−10.63 ± 0.09 |
Al3+ + 3 H2O ⇌ Al(OH)3 + 3 H+
|–15.0 |−15.66 ± 0.23 |−15.99 ± 0.23 |
Al3+ + 4 H2O ⇌ Al(OH)4– + 4 H+
|–23.0 |−22.91 ± 0.10 |−22.91 ± 0.10 |
2 Al3+ + 2 H2O ⇌ Al2(OH)24+ + 2 H+
|–7.7 |−7.62 ± 0.11 |−7.62 ± 0.11 |
3 Al3+ + 4 H2O ⇌ Al3(OH)45+ + 4 H+
|–13.94 |−14.06 ± 0.22 |−13.90 ± 0.12 |
13 Al3+ + 28 H2O ⇌ Al13O4(OH)247+ + 32 H+
|–98.73 |−100.03 ± 0.09 |−100.03 ± 0.09 |
α-Al(OH)3(s) + 3 H+ ⇌ Al3+ + 3 H2O
|8.5 |7.75 ± 0.08 |7.75 ± 0.08 |
γ-AlOOH(s) + 3 H+ ⇌ Al3+ + 2 H2O
| |7.69 ± 0.15 |9.4 ± 0.4 |
= Americium(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=407–414}} |
Am3+ + H2O ⇌ Am(OH)2+ + H+
|–6.5 ± 0.1 |–7.22 ± 0.03 |–7.2 ± 0.5 |
Am3+ + 2 H2O ⇌ Am(OH)2+ + 2 H+
|–14.1 ± 0.3 |–14.9 ± 0.2 |–15.1 ± 0.7 |
Am3+ + 3 H2O ⇌ Am(OH)3 + 3 H+
|–25.7 |–26.0 ± 0.2 |–26.2 ± 0.5 |
Am3+ + 3 H2O ⇌ Am(OH)3(am) + 3 H+
|–16.9 ± 0.1 |–16.9 ± 0.8 |–16.9 ± 0.8 |
Am3+ + 3 H2O ⇌ Am(OH)3(cr) + 3 H+
|–15.2 |–15.62 ± 0.04 |–15.6 ± 0.6 |
= Americium(V) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=414}} |
AmO2+ + H2O ⇌ AmO2(OH) + H+
|–10.7 ± 0.2 | |
AmO2+ + 2 H2O ⇌ AmO2(OH)2– + 2 H+
|–22.9 ± 0.7 | |
AmO2+ + H2O ⇌ AmO2(OH)(am) + H+
|–5.4 ± 0.4 |–5.3 ± 0.5 |
= Antimony(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=375}} |
Sb(OH)3 + H+ ⇌ Sb(OH)2+ + H2O
|1.41 | 1.30 | 1.371 |
Sb(OH)3 + H2O ⇌ Sb(OH)4‒ + H+
|‒11.82 |‒11.93 |‒11.70 |
0.5 Sb2O3(s) + 1.5 H2O ⇌ Sb(OH)3
|‒4.24 | | |
Sb2O3(rhombic,s) + 3 H2O ⇌ 2 Sb(OH)3
| |‒8.72 |‒10.00 |
Sb2O3(cubic,s) + 3 H2O ⇌ 2 Sb(OH)3
| | |‒11.40 |
=Antimony(V)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Sb(OH)5 + H2O ⇌ Sb(OH)6‒ + H+
|‒2.72 | ‒2.72 |
12 Sb(OH)5 + 4 H2O ⇌ Sb12(OH)644‒ + 4 H+
|20.34 |20.34 |
12 Sb(OH)5 + 5 H2O ⇌ Sb12(OH)655‒ + 5 H+
|16.72 |16.72 |
12 Sb(OH)5 + 6 H2O ⇌ Sb12(OH)666‒ + 6 H+
|11.89 |11.89 |
12 Sb(OH)5 + 7 H2O ⇌ Sb12(OH)677‒ + 7 H+
|6.07 |6.07 |
0.5 Sb2O5(s) + 2.5 H2O ⇌ Sb(OH)5
|‒3.7 | |
Sb2O5(am) + 5 H2O ⇌ 2 Sb(OH)5
| |‒7.400 |
=Arsenic(III)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=370}} |
As(OH)4‒ + H+ ⇌ As(OH)3 + H2O
|9.29 | 9.17 | 9.24 ± 0.02 |
=Arsenic(V)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
H2AsO4‒ + H+ ⇌ H3AsO4
|2.24 |2.21 | 2.26 ± 0.078 | 2.25 ± 0.04 |
HAsO42‒ + H+ ⇌ H2AsO4‒
| |6.93 |6.99 ± 0.1 |6.98 ± 0.11 |
AsO43‒ + H+ ⇌ HAsO42‒
| |11.51 |11.80 ± 0.1 |11.58 ± 0.05 |
HAsO42‒ + 2 H+ ⇌H3AsO4
|9.20 | | | |
AsO43‒ + 3 H+ ⇌ H3AsO4
|20.70 | | | |
=Barium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=103}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |location=New York |pages=213–217}} |
Ba2+ + H2O ⇌ BaOH+ + H+
| –13.47 | –13.47 | –13.32 ± 0.07 |
= Berkelium(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=419–422}} |
Bk3+ + 3 H2O ⇌ Bk(OH)3(s) + 3 H+
| –13.5 ± 1.0 |
= Beryllium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=95}} |
Be2+ + H2O ⇌ BeOH+ + H+
| –5.10 |
Be2+ + 2 H2O ⇌ Be(OH)2 + 2 H+
|–23.65 |
Be2+ + 3 H2O ⇌ Be(OH)3– + 3 H+
|–23.25 |
Be2+ + 4 H2O ⇌ Be(OH)42– + 4 H+
|–37.42 |
2 Be2+ + H2O ⇌ Be2OH3+ + H+
|–3.97 |
3 Be2+ + 3 H2O ⇌ Be3(OH)33+ + 3 H+
|–8.92 |
6 Be2+ + 8 H2O ⇌ Be6(OH)84+ + 8 H+
|–27.2 |
α-Be(OH)2(cr) + 2 H+ ⇌ Be2+ + 2 H2O
|6.69 |
=Bismuth=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=383}} !Lothenbach et !Kitamura et !Brown and |
Bi3+ + H2O ⇌ BiOH2+ + H+
| –1.0 |–0.92 |–1.1 |–0.920 |–0.92 ± 0.15 |
Bi3+ + 2 H2O ⇌ Bi(OH)2+ + 2 H+
|(–4) |–2.56 |–4.5 |–2.560 ± 1.000 |–2.59 ± 0.26 |
Bi3+ + 3 H2O ⇌ Bi(OH)3 + 3 H+
|–8.86 |–5.31 |–9.0 |–8.940 ± 0.500 |–8.78 ± 0.20 |
Bi3+ + 4 H2O ⇌ Bi(OH)4– + 4 H+
|–21.8 |–18.71 |–21.2 |–21.660 ± 0.870 |–22.06 ± 0.14 |
3 Bi3+ + 4 H2O ⇌ Bi3(OH)45+ + 4 H+
| |–0.80 | |–0.800 | |
6 Bi3+ + 12 H2O ⇌ Bi6(OH)126+ + 12 H+
| |1.34 | |1.340 |0.98 ± 0.13 |
9 Bi3+ + 20 H2O = Bi9(OH)207+ + 20 H+
| |–1.36 | |–1.360 | |
9 Bi3+ + 21 H2O = Bi9(OH)216+ + 21 H+
| |–3.25 | |–3.250 | |
9 Bi3+ + 22 H2O = Bi9(OH)225+ + 22 H+
| |–4.86 | |–4.860 | |
Bi(OH)3(am) + 3 H+ = Bi3+ + 3 H2O
| | | |31.501 ± 0.927 | |
α-Bi2O3(cr) + 6 H+ = 2 Bi3+ + 3 H2O
| |0.76 | | | |
BiO1.5(s, α) + 3 H+ = Bi3+ + 1.5 H2O
|3.46 | | |31.501 ± 0.927 |2.88 ± 0.64 |
=Boron=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=111}} |
B(OH)3 + H2O ⇌ Be(OH)4+ + H+
| –9.236 |–9.236 ± 0.002 |
2 B(OH)3 ⇌ B2(OH)5– + H+
|–9.36 |–9.306 |
3 B(OH)3 ⇌ B3O3(OH)4– + H+ + 2 H2O
|–7.03 |–7.306 |
4 B(OH)3 ⇌ B4O5(OH)42– + 2 H+ + 3 H2O
|–16.3 |–15.032 |
=Cadmium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=301}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=730–738}} |
Cd2+ + H2O ⇌ CdOH+ + H+
| −10.08 | –9.80 ± 0.10 | −9.81 ± 0.10 |
Cd2+ + 2 H2O ⇌ Cd(OH)2 + 2 H+
|–20.35 |–20.19 ± 0.13 |−20.6 ± 0.4 |
Cd2+ + 3 H2O ⇌ Cd(OH)3– + 3 H+
|<–33.3 |–33.5 ± 0.5 |−33.5 ± 0.5 |
Cd2+ + 4 H2O ⇌ Cd(OH)42– + 4 H+
|–47.35 |–47.28 ± 0.15 |−47.25 ± 0.15 |
2 Cd2+ + H2O ⇌ Cd2OH3+ + H+
|–9.390 |–8.73 ± 0.01 |−8.74 ± 0.10 |
4 Cd2+ + 4 H2O ⇌ Cd4(OH)44+ + H+
|–32.85 | | |
Cd(OH)2(s) ⇌ Cd2+ + 2 OH–
| |–14.28 ± 0.12 | |
Cd(OH)2(s) + 2 H+ ⇌ Cd2+ + 2 H2O
|13.65 |13.72 ± 0.12 |13.71 ± 0.12 |
=Calcium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |location=Weinheim, Germany |pages=195–210}} |
Ca2+ + H2O ⇌ CaOH+ + H+
| –12.85 | –12.78 | –12.57 ± 0.03 |
Ca(OH)2(cr) + 2 H+ ⇌ Ca2+ + 2 H2O
|22.80 |22.8 |22.75 ± 0.02 |
= Californium(III) =
= Cerium(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=137}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=135–145}} |
Ce3+ + H2O ⇌ CeOH2+ + H+
| –8.3 | –8.3 | –8.31 ± 0.03 |
2 Ce3+ + 2 H2O ⇌ Ce2(OH)24+ + 2 H+
| | |–16.0 ± 0.2 |
3 Ce3+ + 5 H2O ⇌ Ce3(OH)54+ + 5 H+
| | |–34.6 ± 0.3 |
Ce(OH)3(s) + 3 H+ ⇌ Ce3+ + 3 H2O
| | |18.5 ± 0.5 |
Ce(OH)3(s) ⇌ Ce3+ + 3 OH–
| |–22.1 ± 0.9 | |
=Chromium(II)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K (The divalent state is unstable in water, producing hydrogen whilst being oxidised to a higher valency state (Baes and Mesmer, 1976). The reliability of the data is in doubt.):
class="wikitable"
|+ !Reaction |
Cr2+ + H2O ⇌ CrOH+ + H+
| –5.5 | |
Cr(OH)2(s) ⇌ Cr2+ + 2 OH–
| |–17 ± 0.02 |
= Chromium(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=220}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=541–555}} |
Cr3+ + H2O ⇌ CrOH2+ + H+
| –4.0 | –3.57 ± 0.08 | | –3.60 ± 0.07 |
Cr3+ + 2 H2O ⇌ Cr(OH)2+ + 2 H+
|–9.7 |–9.84 | |–9.65 ± 0.20 |
Cr3+ + 3 H2O ⇌ Cr(OH)3 + 3 H+
|–18 |–16.19 | |–16.25 ± 0.19 |
Cr3+ + 4 H2O ⇌ Cr(OH)4− + 4 H+
|–27.4 |–27.65 ± 0.12 | |–27.56 ± 0.21 |
2 Cr3+ + 2 H2O ⇌ Cr2(OH)24+ + 2 H+
|–5.06 |–5.0 | |–5.29 ± 0.16 |
3 Cr3+ + 4 H2O ⇌ Cr3(OH)45+ + 4 H+
|–8.15 |–10.75 ± 0.15 | |–9.10 ± 0.14 |
Cr(OH)3(s) + 3 H+ ⇌ Cr3+ + 3 H2O
|12 | |9.35 |9.41 ± 0.17 |
Cr2O3(s) + 6 H+ ⇌ 2 Cr3+ + 3 H2O
| | |8.52 | |
CrO1.5(s) + 3 H+ ⇌ Cr3+ + 1.5 H2O
| | | |7.83 ± 0.10 |
= Chromium(VI) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=216}} |
CrO42– + H+ ⇌ HCrO4–
| 6.51 | 6.55 ± 0.04 |
HCrO4– + H+ ⇌ H2CrO4
|–0.20 | |
CrO42– + 2 H+ ⇌ H2CrO4
| |6.31 |
2 HCrO4– ⇌ Cr2O72– + H2O
|1.523 | |
2 CrO42– + 2 H+ ⇌ Cr2O72– + H2O
| |14.7 ± 0.1 |
= Cobalt(II) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=241}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=620–628}} |
Co2+ + H2O ⇌ CoOH+ + H+
| –9.65 | −9.61 ± 0.17 |
Co2+ + 2 H2O ⇌ Co(OH)2 + 2 H+
|–18.8 |−19.77 ± 0.11 |
Co2+ + 3 H2O ⇌ Co(OH)3– + 3 H+
|–31.5 |−32.01 ± 0.33 |
Co2+ + 4 H2O ⇌ Co(OH)42– + 4 H+
|–46.3 | |
2 Co2+ + H2O ⇌ Co2(OH)3+ + H+
|–11.2 | |
4 Co2+ + 4 H2O ⇌ Co4(OH)44+ + 4H+
|–30.53 | |
Co(OH)2(s) + 2 H+ ⇌ Co2+ + 2 H2O
|12.3 |13.24 ± 0.12 |
CoO(s) + 2 H+ ⇌ Co2+ + H2O
| |13.71 ± 0.10 |
= Cobalt(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=628−632}} |
Co3+ + H2O ⇌ CoOH2+ + H+
| −1.07 ± 0.11 |
= Copper(I) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=650–702}} |
Cu+ + H2O ⇌ CuOH + H+
| –7.8 ± 0.4 |
Cu+ + 2 H2O ⇌ Cu(OH)2– + 2 H+
|–18.6 ± 0.6 |
= Copper(II) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Messmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=274}} |
Cu2+ + H2O ⇌ CuOH+ + H+
|< –8 |–7.7 |–7.97 ± 0.09 |–7.95 ± 0.16 | –7.64 ± 0.17 |
Cu2+ + 2 H2O ⇌ Cu(OH)2 + 2 H+
|(< –17.3) |–17.3 |–16.23 ± 0.15 |–16.2 ± 0.2 |–16.24 ± 0.03 |
Cu2+ + 3 H2O ⇌ Cu(OH)3– + 3 H+
|(< –27.8) |–27.8 |–26.63 ± 0.40 |–26.60 ± 0.09 |–26.65 ± 0.13 |
Cu2+ + 4 H2O ⇌ Cu(OH)42– + 4 H+
|–39.6 |–39.6 |–39.73 ± 0.17 |–39.74 ± 0.18 |–39.70 ± 0.19 |
2 Cu2+ + H2O ⇌ Cu2(OH)3+ + H+
| | |–6.71 ± 0.30 |–6.40 ± 0.12 |–6.41 ± 0.17 |
2 Cu2+ + 2 H2O ⇌ Cu2(OH)22+ + 2 H+
|–10.36 |–10.3 |–10.55 ± 0.17 |–10.43 ± 0.07 |–10.55 ± 0.02 |
3 Cu2+ + 4 H2O ⇌ Cu3(OH)42+ + 4 H+
| | |–20.95 ± 0.30 |–21.1 ± 0.2 |–21.2 ± 0.4 |
CuO(s) + 2 H+ ⇌ Cu2+ + H2O
|7.62 | |7.64 ± 0.06 |7.64 ± 0.06 |7.63 ± 0.05 |
Cu(OH)2(s) + 2 H+ ⇌ Cu2+ + 2 H2O
| | | |8.67 ± 0.05 |8.68 ± 0.10 |
= Curium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=415−420}} |
Cm3+ + H2O ⇌ Cm(OH)2+ + H+
|−7.66 ± 0.07 |
Cm3+ + 2 H2O ⇌ Cm(OH)2+ + 2 H+
|−15.9 ± 0.1 |
Cm3+ + 3 H2O ⇌ Cm(OH)3(s) + 3 H+
|−13.9 ± 0.4 |
= Dysprosium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=247, 250−251 and 290−292}} |
Dy3+ + H2O ⇌ DyOH2+ + H+
|−8.0 |−7.53 ± 0.14 |
Dy3+ + 2 H2O ⇌ Dy(OH)2+ + 2 H+
|(–16.2) | |
Dy3+ + 3 H2O ⇌ Dy(OH)3 + 3 H+
|(–24.7) | |
Dy3+ + 4 H2O ⇌ Dy(OH)4− + 4 H+
|–33.5 | |
2 Dy3+ + 2 H2O ⇌ Dy2(OH)24+ + 2 H+
| |−13.76 ± 0.20 |
3 Dy3+ + 5 H2O ⇌ Dy3(OH)54+ + 5 H+
| |−30.6 ± 0.3 |
Dy(OH)3(s) + 3 H+ ⇌ Dy3+ + 3 H2O
|15.9 |16.26 ± 0.30 |
Dy(OH)3(c) + OH− ⇌ Dy(OH)4−
|−3.6 | |
Dy(OH)3(c) ⇌ Dy(OH)3
|−8.8 | |
= Erbium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=247, 250−251 and 295−297}} |
Er3+ + H2O ⇌ ErOH2+ + H+
|−7.9 |−7.46 ± 0.09 |
Er3+ + 2 H2O ⇌ Er(OH)2+ + 2 H+
|(−15.9) | |
Er3+ + 3 H2O ⇌ Er(OH)3 + 3 H+
|(−24.2) | |
Er3+ + 4 H2O ⇌ Er(OH)4− + 4 H+
|−32.6 | |
2 Er3+ + 2 H2O ⇌ Er2(OH)24+ + 2 H+
|−13.65 |−13.50 ± 0.20 |
3 Er3+ + 5 H2O ⇌ Er3(OH)54+ + 5 H+
|<−29.3 |−31.0 ± 0.3 |
Er(OH)3(s) + 3 H+ ⇌ Er3+ + 3 H2O
|15.0 |15.79 ± 0.30 |
Er(OH)3(c) + OH− ⇌ Er(OH)4−
|−3.6 | |
Er(OH)3(c) ⇌ Er(OH)3
|~ −9.2 | |
=Europium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Eu3+ + H2O ⇌ EuOH2+ + H+
| –7.8 | |–7.64 ± 0.04 | –7.66 ± 0.05 |
Eu3+ + 2 H2O ⇌ Eu(OH)2+ + 2 H+
| | |–15.1 ± 0.2 | |
Eu3+ + 3 H2O ⇌ Eu(OH)3 + 3 H+
| | |–23.7 ± 0.1 | |
Eu3+ + 4 H2O ⇌ Eu(OH)4− + 4 H+
| | |–36.2 ± 0.5 | |
2 Eu3+ + 2 H2O ⇌ Eu2(OH)24+ + 2 H+
| | | - |–14.1 ± 0.2 |
3 Eu3+ + 5 H2O ⇌ Eu3(OH)54+ + 5 H+
| | | - | –32.0 ± 0.3 |
Eu(OH)3(s) + 3 H+ ⇌ Eu3+ + 3 H2O
| 17.5 | |17.6 ± 0.8 (am) 14.9 ± 0.3 (cr) | 16.48 ± 0.30 |
Eu(OH)3(s) ⇌ Eu3+ + 3 OH–
| |–24.5 ± 0.7 (am) –26.5 (cr) | | |
= Gadolinium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=284–287}} |
Gd3+ + H2O ⇌ GdOH2+ + H+
| –8.0 | –7.87 ± 0.05 |
Gd3+ + 2 H2O ⇌ Gd(OH)2+ + 2 H+
| (–16.4) | |
Gd3+ + 3 H2O ⇌ Gd(OH)3 + 3 H+
| (–25.2) | |
Gd3+ + 4 H2O ⇌ Gd(OH)4– + 4 H+
| –34.4 | |
2 Gd3+ + 2 H2O ⇌ Gd2(OH)24+ + 2 H+
| |–14.16 ± 0.20 |
3 Gd3+ + 5 H2O ⇌ Gd3(OH)54+ + 5 H+
| | –33.0 ± 0.3 |
Gd(OH)3(s) + 3 H+ ⇌ Gd3+ + 3 H2O
| 15.6 | 17.20 ± 0.48 |
Gd(OH)3(c) + OH– ⇌ Gd(OH)4–
| –4.8 | |
Gd(OH)3(c) ⇌ Gd(OH)3
| –9.6 | |
= Gallium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=319}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |location=Weinheim, Germany |pages=797–812}} |
Ga3+ + H2O ⇌ GaOH2+ + H+
| –2.6 | –2.897 | –2.74 |
Ga3+ + 2 H2O ⇌ Ga(OH)2+ + 2 H+
| –5.9 | –6.694 | –7.0 |
Ga3+ + 3 H2O ⇌ Ga(OH)3 + 3 H+
| –10.3 | | –11.96 |
Ga3+ + 4 H2O ⇌ Ga(OH)4– + 4 H+
| –16.6 | –16.588 | –15.52 |
Ga(OH)3(s) ⇌ Ga3+ + 3 OH–
|–37 | –37.0 | |
GaO(OH)(s) + H2O ⇌ Ga3+ + 3 OH–
| –39.06 | –39.1 | –40.51 |
=Germanium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=349}} |
Ge(OH)4 ⇌ GeO(OH)3− + H+
| –9.31 | –9.32 ± 0.05 | –9.099 |
Ge(OH)4 ⇌ GeO2(OH)22+ + 2 H+
| –21.9 | | |
GeO2(OH)22– + H+ ⇌ GeO(OH)3–
| | | 12.76 |
8 Ge(OH)4 ⇌ Ge8O16(OH)33- + 13 H2O + 3 H+
| –14.24 | | |
8 Ge(OH)4 + 3 OH– ⇌ Ge8(OH)353–
| | |28.33 |
GeO2(s, hexa) + 2 H2O ⇌ Ge(OH)4
| | –1.35 | –1.373 |
GeO2(s, tetra) + 2 H2O ⇌ Ge(OH)4
| -4.37 |–5.02 |–4.999 |
=Gold(III)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=279–285}} |
Au(OH)3 +2 H+ ⇌ AuOH2+ + 2 H2O
| 1.51 |
Au(OH)3 + H+ ⇌ Au(OH)2+ + H2O
| < 1.0 |
Au(OH)3 + H2O ⇌ Au(OH)4– + H+
|–11.77 |
Au(OH)3 + 2 H2O ⇌ Au(OH)52– + 2 H+
| –25.13 |
Au(OH)52– + 3 H2O ⇌ Au(OH)63– + 3 H+
|< –41.1 |
Au(OH)3(c) ⇌ Au(OH)3
| –5.51 |
= Hafnium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=158}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=460–463}} |
Hf4+ + H2O ⇌ HfOH3+ + H+
| –0.25 | −0.26 ± 0.10 |
Hf4+ + 2 H2O ⇌ Hf(OH)22+ + 2 H+
| (–2.4) | |
Hf4+ + 3 H2O ⇌ Hf(OH)3+ + 3 H+
|(–6.0) | |
Hf4+ + 4 H2O ⇌ Hf(OH)4 + 4 H+
| –10.7* |−3.75 ± 0.34* |
Hf4+ + 5 H2O ⇌ Hf(OH)5– + 5 H+
|–17.2 | |
3 Hf4+ + 4 H2O ⇌ Hf3(OH)48+ + 4 H+
| | 0.55 ± 0.30 |
4 Hf4+ + 8 H2O ⇌ Hf4(OH)88+ + 8 H+
| |6.00 ± 0.30 |
HfO2(s) + 4 H+ ⇌ Hf4+ + 2 H2O
|–1.2* |–5.56 ± 0.15* |
HfO2(am) + 4 H+ ⇌ Hf4+ + 2 H2O
| |–3.11 ± 0.20 |
= Holmium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=247, 250−251 and 293−295}} |
Ho3+ + H2O ⇌ HoOH2+ + H+
|−8.0 |−7.43 ± 0.05 |
2 Ho3+ + 2 H2O ⇌ Ho2(OH)24+ + 2 H+
| |−13.5 ± 0.2 |
3 Ho3+ + 5 H2O ⇌ Ho3(OH)54+ + 5 H+
| |−30.9 ± 0.3 |
Ho(OH)3(s) + 3 H+ ⇌ Ho3+ + 3 H2O
|15.4 |15.60 ± 0.30 |
=Indium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cation |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=327}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=812–817}} |
In3+ + H2O ⇌ InOH2+ + H+
| –4.00 | –3.927 | –3.96 |
In3+ + 2 H2O ⇌ In(OH)2+ + 2 H+
| –7.82 |–7.794 |–9.16 |
In3+ + 3 H2O ⇌ In(OH)3 + 3 H+
|–12.4 |–12.391 | |
In3+ + 4 H2O ⇌ In(OH)4– + 4 H+
| –22.07 |–22.088 |–22.05 |
In(OH)3(s) ⇌ In3+ + 3 OH–
|–36.92 |–36.9 |–36.92 |
1/2 In2O3(s) + 3/2 H2O ⇌ In3+ + 3 OH–
| | | –35.24 |
= Iridium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=736‒739}} |
Ir3+ + H2O ⇌ IrOH2+ + H+
| ‒3.77 ± 0.10 |
Ir3+ + 2 H2O ⇌ Ir(OH)2+ + 2 H+
|‒8.46 ± 0.20 |
Ir(OH)3(s) + 3 H+ ⇌ Ir3+ + 3 H2O
|8.88 ± 0.20 |
=Iron(II)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=235}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.I. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=573−585}} |
Fe2+ + H2O ⇌ FeOH+ + H+
| –9.3 | –9.5 |–9.5 |–9.1 ± 0.4 | −9.43 ± 0.10 |
Fe2+ + 2 H2O ⇌ Fe(OH)2 + 2 H+
|–20.5 | | | |−20.52 ± 0.08 |
Fe2+ + 3 H2O ⇌ Fe(OH)3− + 3 H+
|–29.4 | | | |−32.68 ± 0.15 |
Fe(OH)2(s) +2 H+ ⇌ Fe2+ + 2 H2O
| | | | |12.27 ± 0.88 |
= Iron(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=585–620}} |
Fe3+ + H2O ⇌ FeOH2+ + H+
| –2.19 |−2.15 ± 0.07 | –2.20 ± 0.02 |
Fe3+ + 2 H2O ⇌ Fe(OH)2+ + 2 H+
|–5.67 |−4.8 ± 0.4 |–5.71 ± 0.10 |
Fe3+ + 3 H2O ⇌ Fe(OH)3 + 3 H+
|<–12 |<–14 |–12.42 ± 0.20 |
Fe3+ + 4 H2O ⇌ Fe(OH)4– + 4 H+
|–21.6 |−21.5 ± 0.5 |–21.60 ± 0.23 |
2 Fe3+ + 2 H2O ⇌ Fe2(OH)24+ + 2 H+
|–2.95 |–2.91 ± 0.07 |–2.91 ± 0.07 |
3 Fe3+ + 4 H2O ⇌ Fe3(OH)45+ + 4 H+
|–6.3 | |−6.3 ± 0.1 |
Fe(OH)3(s) +3 H+ ⇌ Fe3+ + 3 H2O
2-line ferrihydrite |2.5 |3.5 |3.50 ± 0.20 |
Fe(OH)3(s) ⇌ Fe3+ + 3 OH−
6-line ferrihydrite | |−38.97 ± 0.64 | |
α-FeOOH(s)+ 3 H+ ⇌ Fe3+ + 2 H2O
goethite |0.5 | |0.33 ± 0.10 |
α-FeOOH + H2O ⇌ Fe3+ + 3 OH−
goethite | |−41.83 ± 0.37 | |
0.5 α-Fe2O3(s)+ 3 H+ ⇌ Fe3+ + 1.5 H2O
hematite | | |0.36 ± 0.40 |
0.5 α-Fe2O3 + 1.5 H2O ⇌ Fe3+ + 3 OH−
hematite | |−42.05 ± 0.26 | |
0.5 γ-Fe2O3(s) + 3 H+ ⇌ Fe3+ + 1.5 H2O
maghemite | | |1.61 ± 0.61 |
0.5 γ-Fe2O3 + 1.5 H2O ⇌ Fe3+ + 3 OH−
maghemite | |−40.59 ± 0.29 | |
α-FeOOH(s)+ 3 H+ ⇌ Fe3+ + 2 H2O
goethite | | |1.85 ± 0.37 |
γ-FeOOH + H2O ⇌ Fe3+ + 3 OH−
lepidocrocite | |−40.13 ± 0.37 | |
Fe(OH)3(s) + 3 H+ ⇌ Fe3+ + 3 H2O
magnetite | | |−12.26 ± 0.26 |
= Lanthanum =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baer |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=137}} |
La3+ + H2O ⇌ LaOH2+ + H+
| –8.5 | –8.89 ± 0.10 |
2 La3+ + 2 H2O ⇌ La2(OH)24+ + 2 H+
|≤ –17.5 |–17.57 ± 0.20 |
3 La3+ + 5 H2O ⇌ La3(OH)54+ + 5 H+
|≤ –38.3 |–37.8 ± 0.3 |
5 La3+ + 9 H2O ⇌ La5(OH)96+ + 9 H+
|–71.2 | |
La(OH)3(s) + 3 H+ ⇌ La3+ + 3 H2O
|20.3 |19.72 ± 0.34 |
=Lead(II)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=365}} |
Pb2+ + H2O ⇌ PbOH+ + H+
| –7.71 | –7.6 |–7.46 ± 0.06 | –7.49 ± 0.13 |–6.47± 0.03 |
Pb2+ + 2 H2O ⇌ Pb(OH)2 + 2 H+
|–17.12 |–17.1 |–16.94 ± 0.09 |–16.99 ± 0.06 |–16.12 ± 0.01 |
Pb2+ + 3 H2O ⇌ Pb(OH)3- + 3 H+
|–28.06 |–28.1 |–28.03± 0.06 |–27.94 ± 0.21 |–28.4 ± 0.1 |
Pb2+ + 4 H2O ⇌ Pb(OH)42- + 4 H+
| | |–40.8 | | |
2 Pb2+ + H2O ⇌ Pb2(OH)3+ + H+
|–6.36 |–6.4 |–7.28± 0.09 |–6.73 ± 0.31 | |
3 Pb2+ + 4 H2O ⇌ Pb3(OH)42+ + 4 H+
|–23.88 |–23.9 |–23.01 ± 0.07 |–23.43 ± 0.10 | |
3 Pb2+ + 5 H2O ⇌ Pb3(OH)5+ + 5 H+
| | | |–31.11 ± 0.10 | |
4 Pb2+ + 4 H2O ⇌ Pb4(OH)44+ + 4 H+
|–20.88 |–20.9 |–20.57± 0.06 |–20.71 ± 0.18 | |
6 Pb2+ + 8 H2O ⇌ Pb6(OH)84+ + 8 H+
|–43.61 |–43.6 |–42.89± 0.07 |–43.27 ± 0.47 | |
PbO(s) + 2 H+ ⇌ Pb2+ + H2O
| | |12.62 (red) 12.90 (yellow) | | |
PbO(s) +H2O ⇌ Pb2+ + 2 OH–
|–15.28 (red) | -15.3 |–15.3 (red) –15.1 (yellow) |–15.37 ± 0.04 (red) –15.1 ± 0.08 (yellow) | |
Pb2O(OH)2(s) +H2O ⇌ 2 Pb2+ + 4 OH–
| | |–14.9 | | |
PbO(s) +H2O ⇌ Pb(OH)2
| | |–4.4 (red) –4.2 (yellow) | | |
Pb2O(OH)2(s) +H2O ⇌ 2 Pb(OH)2
| | |–4.0 | | |
PbO(s) + 2 H2O ⇌ Pb(OH)3– + H+
| | |–1.4 (red) –1.2 (yellow) | | |
Pb2O(OH)2(s) + 2 H2O ⇌ 2 Pb(OH)3– + 2 H+
| | |–1.0 | | |
=Lead(IV)=
= Lithium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=86}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |location=Weinheim, Germany |pages=136–141}} |
Li+ + H2O ⇌ LiOH + H+
| –13.64 | –13.64 | –13.84 ± 0.14 |
= Magnesium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=89}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |location=Weinheim, Germany |pages=178–195}} |
Mg2+ + H2O ⇌ MgOH+ + H+
| –11.44 | –11.44 | –11.70 ± 0.04 |
4 Mg2+ + 4 H2O ⇌ Mg4(OH)44+ + 4 H+
|–39.71 | | |
Mg(OH)2(cr) + 2 H+ ⇌ Mg2+ + 2 H2O
|16.84 |16.84 |17.11 ± 0.04 |
=Manganese(II)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=226}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=557−561}} |
Mn2+ + H2O ⇌ MnOH+ + H+
|–10.59 |–10.59 | –10.59 | –10.59 | −10.58 ± 0.04 |
Mn2+ + 2 H2O ⇌ Mn(OH)2 + 2 H+
| |–22.2 | | |−22.18 ± 0.20 |
Mn2+ + 3 H2O ⇌ Mn(OH)3– + 3 H+
| |–34.8 | | |−34.34 ± 0.45 |
Mn2+ + 4 H2O ⇌ Mn(OH)42– + 4 H+
| |–48.3 | | |−48.28 ± 0.40 |
2 Mn2+ + H2O ⇌ Mn2OH3+ + H+
| |–10.56 | | | |
2 Mn2+ + 3 H2O ⇌ Mn2(OH)3+ + 6 H+
| |–23.90 | | | |
Mn(OH)2(s) + 2 H+ ⇌ Mn2+ + 2 H2O
|15.2 |15.2 |15.2 | |15.19 ± 0.10 |
MnO(s) + 2 H+ ⇌ Mn2+ + H2O
| | | | |17.94 ± 0.12 |
=Manganese(III)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C |publisher=Wiley |year=2016 |pages=568–570}} |
Mn3+ + H2O ⇌ MnOH2+ + H+
| –11.70 ± 0.04 |
=Mercury(I)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cation |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=302}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=741–755}} |
Hg22+ + H2O ⇌ Hg2OH+ + H+
|−5.0a | −4.45 ± 0.10 |
(a) 0.5 M HClO4
=Mercury(II)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=312}} |
Hg2+ + H2O ⇌ HgOH+ + H+
|−3.40 |–3.40 ± 0.08 | –3.40 ± 0.08 |
Hg2+ + 2 H2O ⇌ Hg(OH)2 + 2 H+
| -6.17 |–5.98 ± 0.06 |−5.96 ± 0.07 |
Hg2+ + 3 H2O ⇌ Hg(OH)3– + 3 H+
|–21.1 |–21.1 ± 0.3 | |
HgO(s) + 2 H+ ⇌ Hg2+ + H2O
|2.56 |2.37 ± 0.08 |2.37 ± 0.08 |
=Molybdenum(VI)=
Hydrolysis constants (log values) in critical compilations at infinite dilution, T = 298.15 K and I = 3 M NaClO4 (a) or 0.1 M Na+ medium, Data at I = 0 are not available (b):
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=256}} |
MoO42– + H+ ⇌ HMoO4–
|3.89a | | 4.24 | 4.47 ± 0.02 |
MoO42– + 2 H+ ⇌ H2MoO4
|7.50a | | |8.12 ± 0.03 |
HMoO4– + H+ ⇌ H2MoO4
| | |4.0 | |
Mo7O246– + H+ ⇌ HMo7O245–
| |4.4 | | |
HMo7O245– + H+ ⇌ H2Mo7O244–
| |3.5 | | |
H2Mo7O244– + H+ ⇌ H3Mo7O243–
| |2.5 | | |
7 MoO42-+ 8 H+ ⇌ Mo7O246– + 4 H2O
|57.74a | |52.99b |51.93 ± 0.04 |
7 MoO42– + 9 H+ ⇌ Mo7O23(OH)5– + 4 H2O
|62.14a | | |58.90 ± 0.02 |
7 MoO42– + 10 H+ ⇌ Mo7O22(OH)24– + 4 H2O
|65.68a | | |64.63 ± 0.05 |
7 MoO42– + 11 H+ ⇌ Mo7O21(OH)33– + 4 H2O
|68.21a | | |68.68 ± 0.06 |
19 MoO42- + 34 H+ ⇌ Mo19O594– + 17 H2O
|196.3a | |196a | |
MoO3(s) + H2O ⇌ MoO42– + 2 H+
|–12.06a | | | |
= Neodymium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Nd3+ + H2O ⇌ NdOH2+ + H+
|–8.0 |–8.0 |–7.4 ± 0.4 |–8.13 ± 0.05 |
Nd3+ + 2 H2O ⇌ Nd(OH)2+ + 2 H+
|(–16.9) | |–15.7 ± 0.7 | |
Nd3+ + 3 H2O ⇌ Nd(OH)3(aq) + 3 H+
|(–26.5) | |–26.2 ± 0.5 | |
Nd3+ + 4 H2O ⇌ Nd(OH)4− + 4 H+
|(–37.1) |–37.4 |–40.7 ± 0.7 | |
2 Nd3+ + 2 H2O ⇌ Nd2(OH)24+ + 2 H+
|–13.86 |–13.9 | |–15.56 ± 0.20 |
3 Nd3+ + 5 H2O ⇌ Nd3(OH)54+ + 5 H+
|< –28.5 | | |–34.2 ± 0.3 |
Nd(OH)3(s) + 3 H+ ⇌ Nd3+ + 3 H2O
|18.6 | |17.2 ± 0.4 |17.89 ± 0.09 |
Nd(OH)3(s) ⇌ Nd3+ + 3 OH–
| |–23.2 ± 0.9 |–21.5 (act) –23.1(inact) | |
= Neptunium(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=380}} |
Np3+ + H2O ⇌ NpOH2+ + H+
| -7.3 ± 0.5 |–6.8 ± 0.3 |
= Neptunium(IV) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=183}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=380–384}} |
Np4+ + H2O ⇌ NpOH3+ + H+
|–1.49 |–1.5 |–1.31 ± 0.05 |0.5 ± 0.2 |
Np4+ + 2 H2O ⇌ Np(OH)22+ + 2 H+
| | |–3.7 ± 0.3 |0.3 ± 0.3 |
Np4+ + 4 H2O ⇌ Np(OH)4 + 4 H+
| | |–10.0 ± 0.9 |–8 ± 1 |
Np4+ + 4 OH− ⇌ NpO2(am, hyd) + 2 H2O
|52 |54.9 ± 0.4 |57.5 ± 0.3 |56.7 ± 0.5 |
= Neptunium(V) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brownº |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=384–394}} |
NpO2+ + + H2O ⇌ NpO2(OH) + H+
|–8.85 |–10.7 ± 0.5 |–11.3 ± 0.7 |
NpO2+ + 2 H2O ⇌ NpO2(OH)2− + 2 H+
| |–22.8 ± 0.7 |–23.6 ± 0.5 |
NpO2+ + H2O ⇌ NpO2(OH)(am, fresh) + H+
|≤ –4.7 |–5.21 ± 0.05 |–5.3 ± 0.2 |
NpO2+ + H2O ⇌ NpO2(OH)(am, aged) + H+
| |–4.53 ± 0.06 |–4.7 ± 0.5 |
= Neptunium(VI) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, !Brown and Ekberg, !Grenthe et |
NpO22+ + H2O ⇌ NpO2(OH)+ + H+
|–5.15 |–5.12 |–5.1 ± 0.2 |–5.1 ± 0.4 |
NpO22+ + 3 H2O ⇌ NpO2(OH)3− + 3 H+
| | |–21 ± 1 | |
NpO22+ + 4 H2O ⇌ NpO2(OH)42- + 4 H+
| | |–32 ± 1 | |
2 NpO22+ + 2 H2O ⇌ (NpO2)2(OH)22+ + 2 H+
|–6.39 |–6.39 |–6.2 ± 0.2 |–6.2 ± 0.2 |
3 NpO22+ + 5 H2O ⇌ (NpO2)3(OH)5+ + 5 H+
|–17.49 |–17.49 |–17.0 ± 0.2 |–17.1 ± 0.2 |
NpO22+ + 2 H2O ⇌ NpO3.H2O(cr) + 2 H+
|≥-6.6 | |–5.4 ± 0.4 |–5.4 ± 0.4 |
= Nickel(II) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Messmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Messmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=246}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=632–649}} |
Ni2+ + H2O ⇌ NiOH+ + H+
| |–9.86 |–9.9 |–9.54 ± 0.14 |–9.54 ± 0.14 |–9.90 ± 0.03 |
Ni2+ + 2 H2O ⇌ Ni(OH)2 + 2 H+
| |–19 |–19 | |< –18 |–21.15 ± 0.0 |
Ni2+ + 3 H2O ⇌ Ni(OH)3– + 3 H+
| |–30 |–30 |–29.2 ± 1.7 |–29.2 ± 1.7 | |
Ni2+ + 4 H2O ⇌ Ni(OH)42– + 4 H+
| |< –44 | | | | |
2 Ni2+ + H2O ⇌ Ni2(OH)3+ + H+
| |–10.7 | |–10.6 ± 1.0 |–10.6 ± 1.0 |–10.6 ± 1.0 |
4 Ni2+ + 4 H2O ⇌ Ni4(OH)44+ + 4 H+
| |–27.74 |–27.7 |–27.52 ± 0.15 |–27.52 ± 0.15 |–27.9 ± 0.6 |
β-Ni(OH)2(s) + 2 H+ ⇌ Ni2+ + 2 H2O
| |10.8 | | |11.02 ± 0.20 |10.96 ± 0.20 11.75 ± 0.13 (microcr) |
Ni(OH)2(s) ⇌ Ni2+ + 2 OH–
|–17.2 (inactive) | |–17.2 |–16.97± 0.20 (β) –17.2 ± 1.3 (cr) | | |
Ni(OH)2(s) + OH– ⇌ Ni(OH)3–
|–4.2 (inactive) | | | | | |
NiO(cr) + 2 H+ ⇌ Ni2+ + H2O
| | | |12.38 ± 0.06 | |12.48 ± 0.15 |
=Niobium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Nb(OH)5 + H+ ⇌ Nb(OH)4+ + H2O
| ~ –0.6 | 1.603 |
Nb(OH)5 + H2O ⇌ Nb(OH)6– + H+
|~ –4.8 |–4.951 |
Nb6O198– + H+ ⇌ HNb6O197–
| |14.95 |
HNb6O197– + H+ ⇌ H2Nb6O196–
| |13.23 |
H2Nb6O196– + H+ ⇌ H3Nb6O195–
| |11.73 |
1/2 Nb2O5(act) + 5/2 H2O ⇌ Nb(OH)5
|~ –7.4 | |
Nb(OH)5(am,s) ⇌ Nb(OH)5
| |–7.510 |
Nb2O5(s) + 5 H2O ⇌ 2 Nb(OH)5
| |–18.31 |
= Osmium(VI) =
Hydrolysis constants (log values) in critical compilations at infinite dilution, I = 0.1 M and T = 298.15 K:
class="wikitable"
|+ !Reaction |
OsO2(OH)42– + H+ ⇌ HOsO2(OH)4–
| 10.4 |
HOsO2(OH)4– + H+ ⇌ H2OsO2(OH)4
|8.5 |
= Osmium(VIII) =
= Palladium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=723−725}} |
Pd2+ + H2O ⇌ PdOH+ + H+
|−0.96 | | −0.65 ± 0.64 |−1.16 ± 0.30 |
Pd2+ + 2 H2O ⇌ Pd(OH)2 + 2 H+
|−2.6 |−4 ± 1 |−3.11 ± 0.63 |−3.07 ± 0.16 |
Pd2+ + 3 H2O ⇌ Pd(OH)3− + 3 H+
| |−15.5 ± 1 |−14.20 ± 0.63 | |
Pd(OH)2(am) + 2 H+ ⇌ Pd2+ + 2 H2O
| |−3.3 ± 1 | |−3.4 ± 0.2 |
= Plutonium(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=186–187}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=396–397}} |
Pu3+ + H2O ⇌ PuOH2+ + H+
| |–7.0 |–6.9 ± 0.2 |–6.9 ± 0.3 |
Pu3+ + 3 H2O ⇌ Pu(OH)3(cr) + 3 H+
|–19.65 | |–15.8 ± 0.8 |–15 ± 1 |
= Plutonium(IV) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=187–189}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=397–401}} |
Pu4+ + H2O ⇌ PuOH 3+ + H+
|–0.5 |–0.5 |–0.7 ± 0.1 |0.6 ± 0.2 |
Pu4+ + 2 H2O ⇌ Pu(OH)22+ + 2 H+
|(–2.3) | | |0.6 ± 0.3 |
Pu4+ + 3 H2O ⇌ Pu(OH)3+ + 3 H+
|(–5.3) | | |–2.3 ± 0.4 |
Pu4+ + 4 H2O ⇌ Pu(OH)4 + 4 H+
|–9.5 | |–12.5 ± 0.7 |–8.5 ± 0.5 |
Pu4+ + 4 OH− ⇌ PuO2(am, hyd) + 2 H2O
|49.5 | |47.9 ± 0.4 (0w) 53.8 ± 0.5 (1w) |58.3 ± 0.5 |
= Plutonium(V) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=189–190}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=401–403}} |
PuO2+ + H2O ⇌ PuO2(OH) + H+
|–1.49 |–1.5 |–1.31 ± 0.05 |0.5 ± 0.2 |
PuO2+ + H2O ⇌ PuO2(OH)(am) + H+
| | |–3.7 ± 0.3 |0.3 ± 0.3 |
= Plutonium(VI) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, !Brown and Ekberg, !Grenthe et |
PuO22+ + H2O ⇌ PuO2(OH)+ + H+
|–5.6 |–5.6 |–5.36 ± 0.09 |–5.5 ± 0.5 |
PuO22+ + 2 H2O ⇌ PuO2(OH)2 + 2 H+
| | |–12.9 ± 0.2 |–13 ± 1 |
PuO22+ + 3 H2O ⇌ PuO2(OH)3− + 3 H+
| | | |–24 ± 1 |
2 PuO22+ + 2 H2O ⇌ (PuO2)2(OH)22+ + 2 H+
|–8.36 |–8.36 |–7.8 ± 0.5 |–7 ± 1 |
3 PuO22+ + 5 H2O ⇌ (PuO2)3(OH)5+ + 5 H+
|–21.65 |–21.65 | | |
PuO22+ + 2 OH− ⇌ PuO2(OH)2(am, hyd)
| | | |22.8 ± 0.6 |
= Potassium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=148–150}} |
K+ + H2O ⇌ KOH + H+
|–14.46 | –14.46 |–14.5 ± 0.4 |
= Praseodymium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Pr3+ + H2O ⇌ PrOH2+ + H+
|–8.1 | |–8.30 ± 0.03 |
2 Pr3+ + 2 H2O ⇌ Pr2(OH)24+ + 2 H+
| | |–16.31 ± 0.20 |
3 Pr3+ + 5 H2O ⇌ Pr3(OH)54+ + 5 H+
| | |–35.0 ± 0.3 |
Pr(OH)3(s) + 3 H+ ⇌ Pr3+ + 3 H2O
|19.5 | |18.57 ± 0.20 |
Pr(OH)3(s) ⇌ Pr3+ + 3 OH–
| |–22.3 ± 1.0 | |
= Radium =
=Rhodium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=263}} !Brown and Ekberg{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=722}} |
Rh3+ + H2O ⇌ RhOH2+ + H+
| ‒3.43 |‒3.4 |‒3.09 ± 0.1 |
Rh(OH)3(c) + OH‒ ⇌ Rh(OH)4‒
| |‒3.9 | |
= Samarium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Sm3+ + H2O ⇌ SmOH2+ + H+
|–7.9 | –7.9 |–7.84 ± 0.11 |
2 Sm3+ + 2 H2O ⇌ Sm2(OH)24+ + 2 H+
| | |–14.75 ± 0.20 |
3 Sm3+ + 5 H2O ⇌ Sm3(OH)54+ + 5 H+
| | |–33.9 ± 0.3 |
Sm(OH)3(s) + 3H+ ⇌ Sm3+ + 3H2O
|16.5 | |17.19 ± 0.30 |
Sm(OH)3(s) ⇌ Sm3+ + 3 OH−
| |–23.9 ± 0.9 (am) –25.9 (cr) | |
= Scandium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=128}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=225–236}} |
Sc3+ + H2O ⇌ ScOH2+ + H+
| –4.3 |–4.16 ± 0.05 |
Sc3+ + 2 H2O ⇌ Sc(OH)2+ + 2 H+
|–9.7 |–9.71 ± 0.30 |
Sc3+ + 3 H2O ⇌ Sc(OH)3 + 3 H+
|–16.1 |–16.08 ± 0.30 |
Sc3+ + 4 H2O ⇌ Sc(OH)4–+ 4 H+
|–26 |–26.7 ± 0.3 |
2 Sc3+ + 2 H2O ⇌ Sc2(OH)24+ + 2 H+
|–6.0 |–6.02 ± 0.10 |
3 Sc3+ + 5 H2O ⇌ Sc3(OH)54+ + 5 H+
|–16.34 |–16.33 ± 0.10 |
Sc(OH)3(s) + 3 H+ ⇌ Sc3+ + 3 H2O
| |9.17 ± 0.30 |
ScO1.5(s) + 3 H+ ⇌ Sc3+ + 1.5 H2O
| |5.53 ± 0.30 |
ScO(OH)(c) + 3 H+ ⇌ Sc3+ + 2 H2O
|9.4 | |
Sc(OH)3(c) + OH– ⇌ Sc(OH)4
| |–3.5 ± 0.2 |
= Selenium(–II) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
H2Se(g) ⇌ H2Se(aq)
| –1.10 ± 0.01 |–1.10 ± 0.01 |
H2Se ⇌ HSe– + H+
|–3.85 ± 0.05 |–3.85 ± 0.05 |
HSe– ⇌ Se2– + H+
|–14.91 ± 0.20 | |
= Selenium(IV) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=386}} |
SeO32– + H+ ⇌ HSeO3–
| 8.50 |8.36 ± 0.23 |8.36 ± 0.23 |
HSeO3– + H+ ⇌ H2SeO3
|2.75 |2.64 ± 0.14 |2.64 ± 0.14 |
= Selenium(VI) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=387}} |
SeO42‒ + H+ ⇌ HSeO4‒
| 1.360 |1.75 ± 0.10 |1.75 ± 0.10 |
=Silicon=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=342}} |
Si(OH)4 ⇌ SiO(OH)3– + H+
| –9.86 |–9.81 ± 0.02 |
Si(OH)4 ⇌ SiO2(OH)22– + 2 H+
|–22.92 |–23.14 ± 0.09 |
4 Si(OH)4 ⇌ Si4O6(OH)64– + 2 H+ + 4 H2O
|–13.44 | |
4 Si(OH)4 ⇌ Si4O8(OH)44– + 4 H+ + 4 H2O
|–35.80 |–36.3 ± 0.2 |
SiO2(quartz) + 2 H2O ⇌ Si(OH)4
|–4.0 |–3.739 ± 0.087 |
SiO2(am) + 2 H2O ⇌ Si(OH)4
| |–2.714 |
=Silver=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=278}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=725−730}} |
Ag+ + H2O ⇌ AgOH + H+
|−12.0 |−11.75 ± 0.14 |
Ag+ + 2 H2O ⇌ Ag(OH)2− + 2 H+
|−24.0 |−24.34 ± 0.14 |
0.5 Ag2O(am) + H+ ⇌ Ag+ + 0.5 H2O
|6.29 |6.27 ± 0.05 |
=Sodium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |location=Weinheim, Germany |pages=142–147}} |
Na+ + H2O ⇌ NaOH + H+
| –14.18 | –14.18 | –14.4 ± 0.2 |
=Strontium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |location=Weinheim, Germany |pages=210–213}} |
Sr2+ + H2O ⇌ SrOH+ + H+
| –13.29 | –13.29 | –13.15 ± 0.05 |
=Tantalum=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=252}} |
Ta(OH)5 + H+ ⇌ Ta(OH)4+ + H2O
| ~1 | 0.7007 |
Ta(OH)5 + H2O ⇌ Ta(OH)6– + H+
|~ –9.6 | |
Ta6O198– + H+ ⇌ HTa6O197–
| |16.35 |
HTa6O197– + H+ ⇌ H2Ta6O196–
| |14.00 |
1/2 Ta2O5(act) + 5/2 H2O ⇌ Ta(OH)5
|~ –5.2 | |
Ta(OH)5(s) ⇌ Ta(OH)5
| |–5.295 |
Ta2O5(s) + 5 H2O ⇌ 2 Ta(OH)5
| |–20.00 |
(a) The number of significant figures are retained to minimise propagation of round-off errors; they should not be taken to indicate the relative uncertainty of the values, which is always at least one order of magnitude less than indicated.
=Tellurium(-II)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Te2‒ + H+ ⇌ HTe‒
| 11.81 |
HTe‒ + H+ ⇌ H2Te
|2.476 |
(a) The number of significant figures are retained to minimise propagation of round-off errors; they should not be taken to indicate the relative uncertainty of the values, which is always at least one order of magnitude less than indicated.
=Tellurium(IV)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=395}} |
TeO32‒ + H+ ⇌ HTeO3‒
| | 9.928 |
HTeO3‒ + H+ ⇌ H2TeO3
| |6.445 |
H2TeO3 ⇌ HTeO3‒ + H+
|‒2.68 | |
H2TeO3 ⇌ TeO32‒ + 2 H+
|‒12.5 | |
H2TeO3 + H+ ⇌ Te(OH)3+
|3.13 |2.415 |
TeO2(s) + H2O ⇌ H2TeO3
| |‒4.709 |
(a) The number of significant figures are retained to minimise propagation of round-off errors; they should not be taken to indicate the relative uncertainty of the values, which is always at least one order of magnitude less than indicated.
=Tellurium(VI)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
TeO2(OH)42‒ + H+ ⇌ TeO(OH)5‒
| | 10.83 |
TeO(OH)5‒ + H+ ⇌ Te(OH)6
|7.68 |7.696 |
TeO2(OH)42‒ + 2 H+ ⇌ Te(OH)6
|18.68 | |
TeO3(OH)33‒ + 3 H+ ⇌ Te(OH)6
|34.3 | |
2 Te(OH)6 ⇌ Te2O(OH)11‒ + H+
| |‒6.929 |
(a) The number of significant figures are retained to minimise propagation of round-off errors; they should not be taken to indicate the relative uncertainty of the values, which is always at least one order of magnitude less than indicated.
= Terbium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brwon |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=247, 250−251 and 287−290}} |
Tb3+ + H2O ⇌ TbOH2+ + H+
|−7.9 |−7.60 ± 0.09 |
2 Tb3+ + 2 H2O ⇌ Tb2(OH)24+ + 2 H+
| |−13.9 ± 0.2 |
3 Tb3+ + 5 H2O ⇌ Tb3(OH)54+ + 5 H+
| |−31.7 ± 0.3 |
Tb(OH)3(s) + 3 H+ ⇌ Tb3+ + 3 H2O
|16.5 |16.33 ± 0.30 |
=Thallium(I)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=335}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=817–826}} |
Tl+ + H2O ⇌ TlOH + H+
|–13.21 | |
Tl+ + OH– ⇌ TlOH
| |0.64 ± 0.05 |
Tl+ + 2 OH– ⇌ Tl(OH)2–
| |–0.7 ± 0.7 |
{{sfrac|1|2}} Tl2O(s) + H+ ⇌ Tl+ + {{sfrac|1|2}} H2O
| |13.55 ± 0.20 |
(a) The number of significant figures are retained to minimise propagation of round-off errors; they should not be taken to indicate the relative uncertainty of the values, which is always at least one order of magnitude less than indicated.
=Thallium(III)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Tl3+ + H2O ⇌ TlOH2+ + H+
|–0.62 | –0.22 ± 0.19 |
Tl3+ + 2 H2O ⇌ Tl(OH)2+ + 2 H+
|–1.57 | |
Tl3+ + 3 H2O ⇌ Tl(OH)3 + 3 H+
|–3.3 | |
Tl3+ + 4 H2O ⇌ Tl(OH)4– + 4 H+
|–15.0 | |
{{sfrac|1|2}} Tl2O3(s) + 3 H+ ⇌ Tl3+ + {{sfrac|3|2}} H2O
|–3.90 |–3.90 ± 0.10 |
(a) The number of significant figures are retained to minimise propagation of round-off errors; they should not be taken to indicate the relative uncertainty of the values, which is always at least one order of magnitude less than indicated.
= Thorium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, !Rand et !Thoenen et !Brown and Ekberg, |
Th4+ + H2O ⇌ ThOH3+ + H+
|–3.20 |–2.5 ± 0.5 |–2.5 ± 0.5 | –2.5 ± 0.5 |
Th4+ + 2 H2O ⇌ Th(OH)22+ + 2 H+
|–6.93 |–6.2 ± 0.5 |–6.2 ± 0.5 |–6.2 ± 0.5 |
Th4+ + 3 H2O ⇌ Th(OH)3+ + 3 H+
|< –11.7 | | | |
Th4+ + 4 H2O ⇌ Th(OH)4 + 4 H+
|–15.9 |–17.4 ± 0.7 |–17.4 ± 0.7 |–17.4 ± 0.7 |
2Th4+ + 2 H2O ⇌ Th2(OH)26+ + 2 H+
|–6.14 |–5.9 ± 0.5 |–5.9 ± 0.5 |–5.9 ± 0.5 |
2Th4+ + 3 H2O ⇌ Th2(OH)35+ + 3 H+
| |–6.8 ± 0.2 |–6.8 ± 0.2 |–6.8 ± 0.2 |
4Th4+ + 8 H2O ⇌ Th4(OH)88+ + 8 H+
|–21.1 |–20.4 ± 0.4 |–20.4 ± 0.4 |–20.4 ± 0.4 |
4Th4+ + 12 H2O ⇌ Th4(OH)124+ + 12 H+
| |–26.6 ± 0.2 |–26.6 ± 0.2 |–26.6 ± 0.2 |
6Th4+ + 15 H2O(l) ⇌ Th6(OH)159+ + 15 H+
|–36.76 |–36.8 ± 1.5 |–36.8 ± 1.5 |–36.8 ± 1.5 |
6Th4+ + 14 H2O(l) ⇌ Th6(OH)1410+ + 14 H+
| |–36.8 ± 1.2 |–36.8 ± 1.2 |–36.8 ± 1.2 |
ThO2(c) + 4 H+ ⇌ Th4+ + 2 H2O
|6.3 | | | |
ThO2(am) + 4 H+ ⇌ Th4+ + 2 H2O
| | | |8.8 ± 1.0 |
ThO2(am,hyd,fresh) + 4 H+ ⇌ Th4+ + 2 H2O
| | |9.3 ± 0.9 | |
ThO2(am,hyd,aged) + 4 H+ ⇌ Th4+ + 2 H2O
| | |8.5 ± 0.9 | |
Th4+ + 4 OH− ⇌ ThO2(am,hyd,fresh) + 2 H2O
| |46.7 ± 0.9 | | |
Th4+ + 4 OH− ⇌ ThO2(am,hyd,aged) + 2 H2O
| |47.5 ± 0.9 | | |
= Thulium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=247, 250−251 and 297−300}} |
Tm3+ + H2O ⇌ TmOH2+ + H+
|−7.7 | −7.34 ± 0.09 |
2 Tm3+ + 2 H2O ⇌ Tm2(OH)24+ + 2 H+
| |−13.2 ± 0.2 |
3 Tm3+ + 5 H2O ⇌ Tm3(OH)54+ + 5 H+
| |−30.5 ± 0.3 |
Tm(OH)3(s) + 3 H+ ⇌ Tm3+ + 3 H2O
|15.0 |15.56 ± 0.40 |
= Tin(II) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=357}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=836–842}} |
Sn2+ + H2O ⇌ SnOH+ + H+
| | –3.40 |–3.8 ± 0.2 |–3.4 |–3.52 ± 0.05 |–3.53 ± 0.40 | –3.53 ± 0.40 |
Sn2+ + 2 H2O ⇌ Sn(OH)2 + 2 H+
| |–7.06 |–7.7 ± 0.2 |–7.1 |–6.26 ± 0.06 |–7.68 ± 0.40 |–7.68 ± 0.40 |
Sn2+ + 3 H2O ⇌ Sn(OH)3– + 3 H+
| |–16.61 |–17.5 ± 0.2 |–16.6 |–16.97 ± 0.17 |–17.00 ± 0.60 |–17.56 ± 0.40 |
2 Sn2+ + 2 H2O ⇌ Sn2(OH)22+ + 2 H+
| |–4.77 | |–4.8 |–4.79 ± 0.05 | | |
3 Sn2+ + 4 H2O ⇌ Sn3(OH)42+ + 4 H+
| |–6.88 |–5.6 ± 1.6 |–6.88 |–5.88 ± 0.05 |–5.60 ± 0.47 |−5.60 ± 0.47 |
Sn(OH)2(s) ⇌ Sn2+ + 2 OH–
| | | |–25.8 |–26.28 ± 0.08 | | |
SnO(s) + 2 H+ ⇌ Sn2+ + H2O
| |1.76 |2.5± 0.5 | | | |1.60 ± 0.15 |
SnO(s) + H2O ⇌ Sn2+ + 2 OH–
|–26.2 | | | | | | |
SnO(s) + H2O ⇌ Sn(OH)2
|–5.3 | | | | | | |
SnO(s) + 2 H2O ⇌ Sn(OH)3– + H+
|–0.9 | | | | | | |
=Tin(IV)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Sn4+ + 4 H2O ⇌ Sn(OH)4 + 4 H+
| | | 7.53 ± 0.12 |
Sn4+ + 5 H2O ⇌ Sn(OH)5– + 5 H+
| | |–1.07 ± 0.42 |
Sn4+ + 6 H2O ⇌ Sn(OH)62– + 6 H+
| | |–1.07 ± 0.42 |
Sn(OH)4 + H2O ⇌ Sn(OH)5– + H+
|–8.0 ± 0.3 |–8.60 ± 0.40 | |
Sn(OH)4 + 2 H2O ⇌ Sn(OH)62– + 2 H+
|–18.4 ± 0.3 |–18.67 ± 0.30 | |
SnO2(cr) + 2 H2O ⇌ Sn(OH)4
|–8.0 ± 0.2 |–8.06 ± 0.11 | |
SnO2(am) + 2 H2O ⇌ Sn(OH)4
|–7.3 ± 0.3 |–7.22 ± 0.08 | |
SnO2(s) + 4 H+ ⇌ Sn4+ + 2 H2O
| | |–15.59 ± 0.04 |
=Tungsten=
= Titanium(III) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=151}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=433–442}} |
Ti3+ + H2O ⇌ TiOH2+ + H+
| –1.29 | –2.2 | –1.65 ± 0.11 |
2 Ti3+ + 2 H2O ⇌ Ti2(OH)24+ + 2 H+
| |–3.6 |–2.64 ± 0.10 |
=Titanium(IV)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Ti(OH)22+ + H2O ⇌ Ti(OH)3+ + H+
| ⩽–2.3 | |
Ti(OH)22+ + 2 H2O ⇌ Ti(OH)4 + 2 H+
|–4.8 | |
TiO2+ + H2O ⇌ TiOOH+ + H+
| |–2.48 ± 0.10 |
TiO2+ + 2 H2O ⇌ TiO(OH)2 + 2 H+
| |–5.49 ± 0.14 |
TiO2+ + 3 H2O ⇌ TiO(OH)3– + 3 H+
| |–17.4 ± 0.5 |
TiO(OH)2 + H2O ⇌ TiO(OH)3– + H+
| |–11.9 ±0.5 |
TiO2(c) +2 H2O ⇌ Ti(OH)4
|~ –4.8 | |
TiO2(s) + H+ ⇌ TiOOH+
| |–6.06 ± 0.30 |
TiO2(s) + H2O ⇌ TiO(OH)2
| |–9.02 ± 0.02 |
TiO2 x H2O ⇌ Ti(OH)22+[OH–]
| | |
TiO2(s) + 4 H+ ⇌ Ti4+ + 2 H2O
| |–3.56 ± 0.10 |
=Uranium(IV)=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, !Thoenen et !Brown and Ekberg, !Grenthe et al., |
U4+ + H2O ⇌ UOH3+ + H+
|–0.65 |– 0.54 ± 0.06 | –0.58 ± 0.08 |– 0.54 ± 0.06 |
U4+ + 2 H2O ⇌ U(OH)22+ + 2 H+
|(–2.6) |–1.1 ± 1.0 |–1.4 ± 0.2 |–1.9 ± 0.2 |
U4+ + 3 H2O ⇌ U(OH)3+ + 3 H+
|(–5.8) |–4.7 ± 1.0 |–5.1 ± 0.3 |–5.2 ± 0.4 |
U4+ + 4 H2O ⇌ U(OH)4 + 4 H+
|(–10.3) |–10.0 ± 1.4 |–10.4 ± 0.5 |–10.0 ± 1.4 |
U4+ + 5 H2O ⇌ U(OH)5− + 5 H+
|–16.0 | | | |
UO2(am, hyd) + 4 H+ ⇌ U4+ + 2 H2O
| |1.5 ± 1.0 | | |
UO2(am,hyd) + 2 H2O ⇌ U4+ + 4 OH–
| | |–54.500 ± 1.000 |–54.500 ± 1.000 |
UO2(c) + 4 H+ ⇌ U4+ + 2 H2O
|–1.8 | | | |
UO2(c) + 2 H2O ⇌ U4+ + 4 OH–
| | | |–60.860 ± 1.000 |
= Uranium(VI) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, !Grenthe et !Brown and Ekberg, !Grenthe et al., |
UO22+ + H2O ⇌ UO2(OH)+ + H+
|–5.8 |–5.2 ± 0.3 |–5.9 ± 0.1 | –5.13 ± 0.04 |–5.25 ± 0.24 |
UO22+ + 2 H2O ⇌ UO2(OH)2 + 2 H+
| |≤-10.3 | |–12.15 ± 0.20 |–12.15 ± 0.07 |
UO22+ + 3 H2O ⇌ UO2(OH)3– + 3 H+
| |–19.2 ± 0.4 | |–20.25 ± 0.42 |–20.25 ± 0.42 |
UO22+ + 4 H2O ⇌ UO2(OH)42– + 4 H+
| |–33 ± 2 | |–32.40 ± 0.68 |–32.40 ± 0.68 |
2 UO22+ + 2 H2O ⇌ (UO2)2(OH)22+ + 2 H+
|–5.62 |–5.62 ± 0.04 |–5.58 ± 0.04 |–5.68 ± 0.05 |–5.62 ± 0.08 |
3 UO22+ + 5 H2O ⇌ (UO2)3(OH)5+ + 5 H+
|–15.63 |–15.55 ± 0.12 |–15.6 |–15.75 ± 0.12 |–15.55 ± 0.12 |
3 UO22+ + 4 H2O ⇌ (UO2)3(OH)42+ + 4 H+
|(–11.75) |–11.9 ± 0.3 | |–11.78 ± 0.05 |–11.9 ± 0.3 |
3 UO22+ + 7 H2O ⇌ (UO2)3(OH)7– + 7 H+
| |–31 ± 2.0 | |–32.2 ± 0.8 |–32.2 ± 0.8 |
4 UO22+ + 7 H2O ⇌ (UO2)4(OH)7+ + 7 H+
| |–21.9 ± 1.0 | |–22.1 ± 0.2 |–21.9 ± 1.0 |
2 UO22+ + H2O ⇌ (UO2)2(OH)3+ + H+
| |–2.7 ± 1.0 | | |–2.7 ± 1.0 |
UO2(OH)2(s) + 2H+ ⇌ UO22+ + 2 H2O
|5.6 | |6.0 |4.81 ± 0.20 | |
UO3·2H2O(cr) + 2H+ ⇌ UO22+ + 3 H2O
| | | | |5.350 ± 0.130 |
= Vanadium(IV) =
= Vanadium(V) =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=209}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=517–541}} |
VO2+ + 2 H2O ⇌ VO(OH)3 + H+
| –3.3 | |
VO2+ + 2 H2O ⇌ VO2(OH)2– + 2 H+
|–7.3 |–7.18 ± 0.12 |
10 VO2+ + 8 H2O ⇌ V10O26(OH)24– + 14 H+
|–10.7 | |
VO2(OH)2– ⇌ VO3(OH)2– + H+
|–8.55 | |
2 VO2(OH)2– ⇌ V2O6(OH)23– + H+ + H2O
|–6.53 | |
VO3(OH)2– ⇌ VO43– + H+
|–14.26 | |
2 VO3(OH)2– ⇌ V2O74– + H2O
|0.56 | |
3 VO3(OH)2– + 3 H+⇌ V3O93– + 3 H2O
|31.81 | |
V10O26(OH)24– ⇌ V10O27(OH)5– + 3 H+
|–3.6 | |
V10O27(OH)5– ⇌ V10O286– + H+
|–6.15 | |
VO2+ + H2O ⇌ VO2OH + H+
| |–3.25 ± 0.1 |
VO2+ + 3 H2O ⇌ VO2(OH)32- + 3 H+
| |–15.74 ± 0.19 |
VO2+ + 4 H2O ⇌ VO2(OH)43- + 4 H+
| |–30.03 ± 0.24 |
2 VO2+ + 4 H2O ⇌ (VO2)2(OH)42- + 4 H+
| |–11.66 ± 0.53 |
2 VO2+ + 5 H2O ⇌ (VO2)2(OH)53- + 5 H+
| |–20.91 ± 0.22 |
2 VO2+ + 6 H2O ⇌ (VO2)2(OH)64- + 6 H+
| |–32.43 ± 0.30 |
4 VO2+ + 8 H2O ⇌ (VO2)4(OH)84- + 8 H+
| |–20.78 ± 0.33 |
4 VO2+ + 9 H2O ⇌ (VO2)4(OH)95- + 9 H+
| |–31.85 ± 0.26 |
4 VO2+ + 10 H2O ⇌ (VO2)4(OH)106- + 10 H+
| |–45.85 ± 0.26 |
5 VO2+ + 10 H2O ⇌ (VO2)5(OH)105- + 10 H+
| |–27.02 ± 0.34 |
10 VO2+ + 14 H2O ⇌ (VO2)10(OH)144- + 14 H+
| |–10.5 ± 0.3 |
10 VO2+ + 15 H2O ⇌ (VO2)10(OH)155- + 15 H+
| |–15.73 ± 0.33 |
10 VO2+ + 16 H2O ⇌ (VO2)10(OH)166- + 16 H+
| |–23.90 ± 0.35 |
{{sfrac|1|2}} V2O5(c) + H+ ⇌ VO2+ + {{sfrac|1|2}} H2O
|–0.66 | |
V2O5(s) + 2 H+ ⇌ 2 VO2+ + H2O
| |–0.64 ± 0.09 |
= Ytterbium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=247, 250−251 and 300−303}} |
Yb3+ + H2O ⇌ YbOH2+ + H+
|−7.7 | −7.31 ± 0.18 |
Yb3+ + 2 H2O ⇌ Yb(OH)2+ + 2 H+
|(−15.8) | |
Yb3+ + 3 H2O ⇌ Yb(OH)3 + 3 H+
|(−24.1) | |
Yb3+ + 4 H2O ⇌ Yb(OH)4− + 4 H+
|−32.7 | |
2 Yb3+ + 2 H2O ⇌ Yb2(OH)24+ + 2 H+
| |−13.76 ± 0.20 |
3 Yb3+ + 5 H2O ⇌ Yb3(OH)54+ + 5 H+
| |−30.6 ± 0.3 |
Yb(OH)3(s) + 3 H+ ⇌ Yb3+ + 3 H2O
|14.7 |15.35 ± 0.20 |
= Yttrium =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction |
Y3+ + H2O ⇌ YOH2+ + H+
|–7.7 | –7.77 ± 0.06 |
Y3+ + 2 H2O ⇌ Y(OH)2+ + 2 H+
|(–16.4) [Estimation] | |
Y3+ + 3 H2O ⇌ Y(OH)3 + 3 H+
|(–26.0) [Estimation] | |
Y3+ + 4 H2O ⇌ Y(OH)4−+ 4 H+
|–36.5 | |
2 Y3+ + 2 H2O ⇌ Y2(OH)24+ + 2 H+
|–14.23 |–14.1 ± 0.2 |
3 Y3+ + 5 H2O ⇌ Y3(OH)54+ + 5 H+
|–31.6 |–32.7 ± 0.3 |
Y(OH)3(s) + 3 H+ ⇌ Y3+ + 3 H2O
|17.5 |17.32 ± 0.30 |
= Zinc =
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Baes and Mesmer, 1976{{Cite book |last=Baes |first=C.F. |title=The Hydrolysis of Cations |last2=Mesmer |first2=R.E. |publisher=Wiley |year=1976 |location=New York |pages=293}} !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C |publisher=Wiley |year=2016 |pages=676−700}} |
Zn2+ + H2O ⇌ ZnOH+ + H+
| −8.96 |−8.96 ± 0.05 |−8.94 ± 0.06 |
Zn2+ + 2 H2O ⇌ Zn(OH)2 + 2 H+
|−16.9 |–17.82 ± 0.08 |−17.89 ± 0.15 |
Zn2+ + 3 H2O ⇌ Zn(OH)3− + 3 H+
|−28.4 |–28.05 ± 0.05 |−27.98 ± 0.10 |
Zn2+ + 4 H2O ⇌ Zn(OH)42- + 4 H+
|−41.2 |–40.41 ± 0.12 |−40.35 ± 0.22 |
2 Zn2+ + H2O ⇌ Zn2OH3+ + H+
|−9.0 |–7.9 ± 0.2 |−7.89 ± 0.31 |
2 Zn2+ + 6 H2O ⇌ Zn2(OH)62- + 6 H+
|−57.8 | | |
ZnO(s) + 2 H+ ⇌ Zn2+ + H2O
|11.14 |11.12 ± 0.05 |11.11 ± 0.10 |
ε-Zn(OH)2(s) + 2 H+ ⇌ Zn2+ + 2 H2O
| |11.38 ± 0.20 |11.38± 0.20 |
β1-Zn(OH)2(s) + 2 H+ ⇌ Zn2+ + 2 H2O
| |11.72 ± 0.04 | |
β2-Zn(OH)2(s) + 2 H+ ⇌ Zn2+ + 2 H2O
| |11.76 ± 0.04 | |
γ-Zn(OH)2(s) + 2 H+ ⇌ Zn2+ + 2 H2O
| |11.70 ± 0.04 | |
δ-Zn(OH)2(s) + 2 H+ ⇌ Zn2+ + 2 H2O
| |11.81 ± 0.04 | |
=Zirconium=
Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K:
class="wikitable"
|+ !Reaction !Brown and Ekberg, 2016{{Cite book |last=Brown |first=P.L. |title=Hydrolysis of Metal Ions |last2=Ekberg |first2=C. |publisher=Wiley |year=2016 |pages=442–460}} |
Zr4+ + H2O ⇌ ZrOH3+ + H+
| 0.32 |0.32 ± 0.22 |0.12 ± 0.12 |
Zr4+ + 2 H2O ⇌ Zr(OH)22+ + 2 H+
|(−1.7)* |0.98 ± 1.06* |−0.18 ± 0.17* |
Zr4+ + 3 H2O ⇌ Zr(OH)3+ + 3 H+
|(−5.1) | | |
Zr4+ + 4 H2O ⇌ Zr(OH)4 + 4 H+
|–9.7* |–2.19 ± 0.70* |−4.53 ± 0.37* |
Zr4+ + 5 H2O ⇌ Zr(OH)5– + 5 H+
|–16.0 | | |
Zr4+ + 6 H2O ⇌ Zr(OH)62– + 6 H+
| |–29± 0.70 |–30.5 ± 0.3 |
3 Zr4+ + 4 H2O ⇌ Zr3(OH)48+ + 4 H+
|–0.6 |0.4 ± 0.3 |0.90 ± 0.18 |
3 Zr4+ + 5 H2O ⇌ Zr3(OH)57+ + 5 H+
|3.70 | | |
3 Zr4+ + 9 H2O ⇌ Zr3(OH)93+ + 9 H+
| |12.19 ± 0.20 |12.19 ± 0.20 |
4 Zr4+ + 8 H2O ⇌ Zr4(OH)88+ + 8 H+
|6.0 |6.52 ± 0.05 |6.52 ± 0.05 |
4 Zr4+ + 15 H2O ⇌ Zr4(OH)15+ + 15 H+
| |12.58± 0.24 | |
4 Zr4+ + 16 H2O ⇌ Zr4(OH)16 + 16 H+
| |8.39± 0.80 | |
ZrO2(s) + 4 H+ ⇌ Zr4+ + 2 H2O
|–1.9* | |–5.37 ± 0.42* |
ZrO2(s, baddeleyite) + 4 H+ ⇌ Zr4+ + 2 H2O
| |–7 ± 1.6 | |
ZrO2(am) + 4 H+ ⇌ Zr4+ + 2 H2O
| |–3.24± 0.10 |–2.97 ± 0.18 |
References
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