Iodocyclohexane
{{Chembox
| Name = Iodocyclohexane
| ImageFile = Cyclohexyl iodide.png
| ImageSize = 100px
| ImageAlt =
| PIN = Iodocyclohexane
| OtherNames = Cyclohexyl iodide
|Section1={{Chembox Identifiers
| CASNo = 626-62-0
| CASNo_Ref = {{cascite|correct|CAS}}
| ChemSpiderID = 11786
| DTXSID = DTXSID3060821
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII =
| EINECS = 210-957-8
| PubChem = 12289
| StdInChI= 1S/C6H11I/c7-6-4-2-1-3-5-6/h6H,1-5H2
| StdInChIKey = FUCOMWZKWIEKRK-UHFFFAOYSA-N
| SMILES = IC1CCCCC1
}}
|Section2={{Chembox Properties
| C=6 | H=11 | I=1
| MolarMass =
| Appearance = colorless to slightly reddish yellow liquid
| Density = 1.624 g/mL
| MeltingPtC =
| BoilingPtC = 180
| Solubility = Insoluble }}
|Section3={{Chembox Hazards
| MainHazards =
| GHS_ref=
| GHSPictograms =
| GHSSignalWord =
| HPhrases =
| PPhrases =
| FlashPtC = 71
| AutoignitionPt = }}
|Section6={{Chembox Related
| OtherCompounds = Chlorocyclohexane
Bromocyclohexane
Fluorocyclohexane
}}
}}
Iodocyclohexane is an organoiodine compound with the chemical formula {{chem2|C6H11I}}.{{cite web |title=B24840 Iodocyclohexane, 98%, stab. with copper |url=https://www.alfa.com/en/catalog/B24840/ |publisher=Alfa Aesar |access-date=21 June 2023}}{{cite web |title=Iodocyclohexane |url=https://www.sigmaaldrich.com/RU/en/product/aldrich/238244 |publisher=Sigma Aldrich |access-date=21 June 2023}}
Synthesis
Iodocyclohexane has been prepared by the addition of hydrogen iodide to cyclohexene.{{cite journal |first1=Herman|last1=Stone|first2=Harold|last2=Shechter
|title=Iodocyclohexane |journal=Organic Syntheses |date=1951 |volume=31 |pages=66 |doi=10.15227/orgsyn.031.0066}}
Alternatively, it can be prepared by the reaction of cyclohexane and iodoform.{{cite web |title=Synthesis of iodocyclohexane from cyclohexane and iodoform |url=https://www.oc-praktikum.de/nop/en/instructions/pdf/3015_en.pdf |publisher=oc-praktikum.de |access-date=21 June 2023}}
Physical properties
Uses
The compound has been used as reagent in demethylation of aryl methyl ethers in DMF under reflux condition.
See also
References
{{Reflist}}
{{Iodine compounds}}