Iron(III) chromate

{{Chembox

| Verifiedfields = changed

| verifiedrevid = 414434912

| Reference =

{{cite book | last = Lide | first = David R. | year = 1998

| title = Handbook of Chemistry and Physics

| edition = 87 | volume =

| location = Boca Raton, Florida

| publisher = CRC Press

| isbn = 0-8493-0594-2 | pages = 4–63}}

| IUPACName = iron(III) chromate

| OtherNames =

|Section1={{Chembox Identifiers

| CASNo_Ref = {{cascite|correct|??}}

| CASNo = 10294-52-7

| ChemSpiderID = 10653099

| EC_number = 233-661-0

| UNII_Ref = {{fdacite|changed|FDA}}

| UNII = O2123EJH4E

| PubChem = 21902690

| InChI = 1S/3Cr.2Fe.12O/q;;;2*+3;;;;;;;6*-1

| InChIKey = OXLBLZDGMWMXSM-UHFFFAOYSA-N

| SMILES = [O-][Cr](=O)(=O)[O-].[O-][Cr](=O)(=O)[O-].[O-][Cr](=O)(=O)[O-].[Fe+3].[Fe+3]}}

|Section2={{Chembox Properties

| Formula = Fe2(CrO4)3

| MolarMass = 459.6808 g/mol

| Appearance = yellow powder

| Solubility = reacts, see also solubility chart}}

|Section3={{Chembox Hazards

| MainHazards = toxic (contain Cr(VI))}}

|Section4={{Chembox Thermochemistry}}}}

Iron(III) chromate is the iron(III) salt of chromic acid with the chemical formula Fe2(CrO4)3.

Discovery

Iron(III) chromate was discovered by Samuel Hibbert-Ware in 1817 while visiting Shetland.{{Cite web|url=http://archives.li.man.ac.uk/ead/search?operation=summary&rsid=998&firstrec=1&numreq=20&highlight=1&hitposition=0|title = Search - Archives Hub}}(full citation required)

Production

It may be formed by the salt metathesis reaction of potassium chromate and iron(III) nitrate, which gives potassium nitrate as byproduct.

:2 Fe(NO3)3 + 3 K2CrO4 → Fe2(CrO4)3 + 6 KNO3

It also can be formed by the oxidation by air of iron and chromium oxides in a basic environment:

:4 Fe2O3 + 6 Cr2O3 + 9 O2 → 4 Fe2(CrO4)3

References

{{Reflist}}

{{Iron compounds}}

{{Chromates and dichromates}}

{{DEFAULTSORT:Iron(Iii) Chromate}}

Category:Chromates

Category:Iron(III) compounds

Category:Oxidizing agents

{{inorganic-compound-stub}}