J. J. Thomson#Discovery of the electron

{{Short description|English physicist (1856–1940)}}

{{About|the Nobel laureate and physicist|the moral philosopher|Judith Jarvis Thomson}}

{{Use British English|date=October 2013}}

{{Use dmy dates|date=December 2024}}

{{Infobox officeholder

| honorific_prefix = Sir

| name = J. J. Thomson

| honorific_suffix = {{Post-nominals|country=GBR|OM|FRS|size=100%}}

| image = J.J Thomson.jpg

| caption = Thomson in 1915

| order1 = 30th

| title1 = Master of Trinity College, Cambridge

| term_start1 = 1918

| term_end1 = 1940

| predecessor1 = Henry Montagu Butler

| successor1 = George Macaulay Trevelyan

| order2 = 42nd

| office2 = President of the Royal Society

| term_start2 = 1915

| term_end2 = 1920

| predecessor2 = William Crookes

| successor2 = Charles Scott Sherrington

| birth_name = Joseph John Thomson

| birth_date = {{Birth date|1856|12|18|df=yes}}

| birth_place = Manchester, Lancashire, England

| death_date = {{Death date and age|1940|08|30|1856|12|18|df=yes}}

| death_place = Cambridge, England

{{Infobox scientist

| embed = yes

| alma_mater = {{Plain list|

}}

| known_for = {{Plain list|

}}

| spouse = {{Marriage|Rose Elisabeth Paget|1890}}

| children = 2, including George

| relatives = George Edward Paget (father-in-law)

| awards = {{Plain list|

}}

| honours = {{Plain list|

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| fields = Physics

| work_institutions = Cavendish Laboratory

| doctoral_advisor =

| academic_advisors = Lord Rayleigh{{Cite web|title=Joseph Thomson|url=https://www.genealogy.math.ndsu.nodak.edu/id.php?id=50701|website=Mathematics Genealogy Project}}

| doctoral_students = {{Plain list|

}}

| notable_students = {{Collapsible list|title={{Nobold|See list}}

| Francis William Aston

| Charles Glover Barkla

| Niels Bohr

| Max Born

| Lawrence Bragg

| William Henry Bragg

| T. H. Laby

| Paul Langevin

| Owen Willans Richardson

| Ernest Rutherford

| Geoffrey Ingram Taylor

| George Paget Thomson

| John Sealy Townsend

| C. T. R. Wilson

}}

{{Infobox officeholder

| embed = yes

| order3 = 3rd

| office3 = Cavendish Professor of Physics

| term_start3 = 1884

| term_end3 = 1919

| predecessor3 = Lord Rayleigh

| successor3 = Ernest Rutherford

}}

| signature = Jjthomson sig.svg

}}

}}

Sir Joseph John Thomson (18 December 1856 – 30 August 1940) was an English physicist who received the Nobel Prize in Physics in 1906 "in recognition of the great merits of his theoretical and experimental investigations on the conduction of electricity by gases."{{Cite web |title=Nobel Prize in Physics 1906 |url=https://www.nobelprize.org/prizes/physics/1906/summary/ |access-date=2025-02-20 |website=NobelPrize.org |language=en-US}}

In 1897, Thomson showed that cathode rays were composed of previously unknown negatively charged particles (now called electrons), which he calculated must have bodies much smaller than atoms and a very large charge-to-mass ratio. Thomson is also credited with finding the first evidence for isotopes of a stable (non-radioactive) element in 1913, as part of his exploration into the composition of canal rays (positive ions). His experiments to determine the nature of positively charged particles, with Francis William Aston, were the first use of mass spectrometry and led to the development of the mass spectrograph.

Thomson was awarded the 1906 Nobel Prize in Physics for his work on the conduction of electricity in gases.{{cite web|title=J.J. Thomson – Biographical|url=https://www.nobelprize.org/nobel_prizes/physics/laureates/1906/thomson-bio.html|website=The Nobel Prize in Physics 1906|publisher=The Nobel Foundation|access-date=11 February 2015}} Thomson was also a teacher, and seven of his students went on to win Nobel Prizes: Ernest Rutherford (Chemistry 1908), Lawrence Bragg (Physics 1915), Charles Barkla (Physics 1917), Francis Aston (Chemistry 1922), Charles Thomson Rees Wilson (Physics 1927), Owen Richardson (Physics 1928) and Edward Victor Appleton (Physics 1947).{{cite web |last1=Sengupta |first1=Sudipto |title=Extraordinary Professor: JJ Thomson and his Nobel Prize Factory |url=https://probashionline.com/jj-thomson-nobel-prize-factory/ |website=Probashi |publisher=Durga Puja & Cultural Association (India) |access-date=7 August 2022 |date=6 April 2015 |quote=His Nobel Laureate students include Rutherford, Aston, Wilson, Bragg, Barkla, Richardson, and Appleton}} Only Arnold Sommerfeld's record of mentorship offers a comparable list of high-achieving students.

Education and personal life

Joseph John Thomson was born on 18 December 1856 in Cheetham Hill, Manchester, Lancashire, England. His mother, Emma Swindells, came from a local textile family. His father, Joseph James Thomson, ran an antiquarian bookshop founded by Thomson's great-grandfather. He had a brother, Frederick Vernon Thomson, who was two years younger than he was.Davis & Falconer, J.J. Thomson and the Discovery of the Electron J. J. Thomson was a reserved yet devout Anglican.Peter J. Bowler, Reconciling Science and Religion: The Debate in Early-Twentieth-Century Britain (2014). University of Chicago Press. p. 35. {{ISBN|9780226068596}}. "Both Lord Rayleigh and J. J. Thomson were Anglicans."Seeger, Raymond. 1986. "J. J. Thomson, Anglican", in "Perspectives on Science and Christian Faith", 38 (June 1986): 131–132. The Journal of the American Scientific Affiliation. "As a Professor, J. J. Thomson did attend the Sunday evening college chapel service, and as Master, the morning service. He was a regular communicant in the Anglican Church. In addition, he showed an active interest in the Trinity Mission at Camberwell. With respect to his private devotional life, J. J. Thomson would invariably practice kneeling for daily prayer, and read his Bible before retiring each night. He truly was a practicing Christian!" (Raymond Seeger 1986, 132).Richardson, Owen. 1970. "Joseph J. Thomson", in Dictionary of National Biography, 1931–1940. L. G. Wickham Legg, editor. Oxford University Press.

His early education was in small private schools where he demonstrated outstanding talent and interest in science. In 1870, he was admitted to Owens College in Manchester (now University of Manchester) at the unusually young age of 14 and came under the influence of Balfour Stewart, Professor of Physics, who initiated Thomson into physical research.{{cite journal|author=Robert John Strutt|title=Joseph John Thomson, 1856–1940|journal=Biographical Memoirs of Fellows of the Royal Society|year=1941|volume=3|issue=10|pages=587–609|doi=10.1098/rsbm.1941.0024|doi-access=free}} Thomson began experimenting with contact electrification and soon published his first scientific paper.{{cite journal|author=Joseph Thomson|title=XX. Experiments on contact electricity between non-conductors|journal=Proceedings of the Royal Society|year=1876|volume=25|issue=171–178|pages=169–171|doi=10.1098/rspl.1876.0039|doi-access=free}} His parents planned to enroll him as an apprentice engineer to Sharp, Stewart & Co, a locomotive manufacturer, but these plans were cut short when his father died in 1873.

He moved on to Trinity College, Cambridge, in 1876. In 1880, he obtained his Bachelor of Arts degree in mathematics (Second Wrangler in the Tripos{{cite web|last=Grayson|first=Mike|title=The Early Life of J. J. Thomson: Computational Chemistry and Gas Discharge Experiments|url=https://www.youtube.com/watch?v=WH-U_qCEzT0|website=Profiles in Chemistry|publisher=Chemical Heritage Foundation|access-date=11 February 2015|date=22 May 2013}} and 2nd Smith's Prize). He applied for and became a fellow of Trinity College in 1881.{{cite book|title=The Victoria University Calendar for the Session 1881–2|date=1882|page=184|url=https://books.google.com/books?id=3d8NAAAAQAAJ&pg=PA184|access-date=11 February 2015|last1=Univ|first1=Manchester}} {{ISBN missing}} He received his Master of Arts degree (with Adams Prize) in 1883.{{acad|id=THN876JJ|name=Thomson, Joseph John}}

Family

In 1890, Thomson married Rose Elisabeth Paget at the church of St. Mary the Less. Rose, who was the daughter of Sir George Edward Paget, a physician and then Regius Professor of Physic at Cambridge, was interested in physics. Beginning in 1882, women could attend demonstrations and lectures at the University of Cambridge. Rose attended demonstrations and lectures, among them Thomson's, leading to their relationship.{{Cite book|url=https://books.google.com/books?id=d_QgAwAAQBAJ&q=Rose+Paget,&pg=PA71|title=A History of the Electron: J. J. and G. P. Thomson|last=Navarro|first=Jaume|date=2012|publisher=Cambridge University Press|isbn=978-1-139-57671-0|language=en}}

They had two children: George Paget Thomson, who was also awarded a Nobel Prize for his work on the wave properties of the electron, and Joan Paget Thomson (later Charnock),{{cite web |title=Joan Paget Thomson (later Charnock), daughter |url=https://discovery.nationalarchives.gov.uk/details/r/1f6db32f-8bf0-4446-8883-5b8d29cbe74e |website=The National Archives |publisher=Cambridge University: Trinity College Library |access-date=22 March 2020}} who became an author, writing children's books, non-fiction and biographies.{{Cite book|url=https://books.google.com/books?id=Hi-xCwAAQBAJ&q=Joan+charnock+cambridge&pg=PA215|title=Writers Directory|last=NA|first=NA|date=2016|publisher=Springer|isbn=978-1-349-03650-9|language=en}}

Career and research

=Overview=

On 22 December 1884, Thomson was appointed Cavendish Professor of Physics at the University of Cambridge.{{cite web|title=Joseph John "J. J." Thomson|url=https://www.sciencehistory.org/historical-profile/joseph-john-j-j-thomson|publisher=Science History Institute|access-date=20 March 2018|date=June 2016}} The appointment caused considerable surprise, given that candidates such as Osborne Reynolds or Richard Glazebrook were older and more experienced in laboratory work. Thomson was known for his work as a mathematician, where he was recognised as an exceptional talent.{{cite book|last1=Kim|first1=Dong-Won|title=Leadership and creativity : a history of the Cavendish Laboratory, 1871–1919|date=2002|publisher=Kluwer Acad. Publ.|location=Dordrecht|isbn=978-1402004759|url=https://books.google.com/books?id=iN13QvH8vnwC&pg=PA51|access-date=11 February 2015}}

He was awarded a Nobel Prize in 1906, "in recognition of the great merits of his theoretical and experimental investigations on the conduction of electricity by gases." He was knighted in 1908 and appointed to the Order of Merit in 1912. In 1914, he gave the Romanes Lecture in Oxford on "The atomic theory". In 1918, he became Master of Trinity College, Cambridge, where he remained until his death. He died on 30 August 1940; his ashes rest in Westminster Abbey,'The Abbey Scientists' Hall, A.R. p. 63: London; Roger & Robert Nicholson; 1966 near the graves of Sir Isaac Newton and his former student Ernest Rutherford.{{cite web|last=Westminster Abbey| title= Sir Joseph John Thomson| url=http://www.westminster-abbey.org/our-history/people/sir-joseph-john-thomson}}

Rutherford succeeded him as Cavendish Professor of Physics. Six of Thomson's research assistants and junior colleagues (Charles Glover Barkla,{{cite web |title=Charles Glover Barkla – Biographical |url=https://www.nobelprize.org/prizes/physics/1917/barkla/biographical/ |website=The Nobel Prize |publisher=Nobel Lectures, Physics 1901–1921, Elsevier Publishing Company |access-date=11 October 2022 |date=1967 |quote=he worked under J. J. Thomson at the Cavendish Laboratory in Cambridge.}} Niels Bohr,{{cite web |title=Niels Bohr – Biographical |url=https://www.nobelprize.org/prizes/physics/1922/bohr/biographical/ |website=The Nobel Prize |publisher=Nobel Lectures, Physics 1922–1941, Elsevier Publishing Company, Amsterdam |access-date=18 October 2022 |date=1965 |quote=he made a stay at Cambridge, where he profited by following the experimental work going on in the Cavendish Laboratory under Sir J.J. Thomson’s guidance}} Max Born,{{cite web |title=Max Born- Biographical |url=https://www.nobelprize.org/prizes/chemistry/1922/aston/biographical/ |website=The Nobel Prize |publisher=Nobel Lectures, Physics 1942–1962, Elsevier Publishing Company |access-date=11 October 2022 |date=1964 |quote=Born next went to Cambridge for a short time, to study under Larmor and J. J. Thomson.}} William Henry Bragg, Owen Willans Richardson{{cite encyclopedia |title=Sir Owen Willans Richardson, British physicist |url=https://www.britannica.com/biography/Owen-Willans-Richardson |encyclopedia=Encyclopædia Britannica |access-date=18 October 2022 |quote=Richardson, a graduate (1900) of Trinity College, Cambridge, and a student of J. J. Thomson at the Cavendish Laboratory}} and Charles Thomson Rees Wilson{{Cite journal | last1 = Rayleigh | doi = 10.1098/rsbm.1941.0024 |title = Joseph John Thomson. 1856–1940 | journal = Obituary Notices of Fellows of the Royal Society | volume = 3 | issue = 10 | pages = 586–609 | year = 1941 | doi-access = free }}) won Nobel Prizes in physics, and two (Francis William Aston{{cite web |title=Francis W. Aston – Biographical |url=https://www.nobelprize.org/prizes/chemistry/1922/aston/biographical// |website=The Nobel Prize |publisher=Nobel Lectures, Physics 1922–1941, Elsevier Publishing Company |access-date=13 October 2022 |date=1966 |quote=At the end of 1909 he accepted the invitation of Sir J. J. Thomson to work as his assistant at the Cavendish Laboratory}} and Ernest Rutherford{{cite web|title=Ernest Rutherford – Biography|url=https://www.nobelprize.org/prizes/chemistry/1908/rutherford/biographical/|publisher=NobelPrize.org|access-date=6 August 2013 |quote=as a research student at the Cavendish Laboratory under J.J. Thomson.}}) won Nobel prizes in chemistry. Thomson's son (George Paget Thomson) also won the 1937 Nobel Prize in physics for proving the wave-like properties of electrons.{{cite web |title=George Paget Thomson Biographical |url=https://www.nobelprize.org/prizes/physics/1937/thomson/biographical/ |website=The Nobel Prize |access-date=8 June 2022 |quote=he carried out experiments on the behaviour of electrons ... which showed that electrons behave as waves ...}}

=Early work=

Thomson's prize-winning master's work, Treatise on the motion of vortex rings, shows his early interest in atomic structure. In it, Thomson mathematically described the motions of William Thomson's vortex theory of atoms.

Thomson published a number of papers addressing both mathematical and experimental issues of electromagnetism. He examined the electromagnetic theory of light of James Clerk Maxwell, introduced the concept of electromagnetic mass of a charged particle, and demonstrated that a moving charged body would apparently increase in mass.

Much of his work in mathematical modelling of chemical processes can be thought of as early computational chemistry. In further work, published in book form as Applications of dynamics to physics and chemistry (1888), Thomson addressed the transformation of energy in mathematical and theoretical terms, suggesting that all energy might be kinetic. His next book, Notes on recent researches in electricity and magnetism (1893), built upon Maxwell's Treatise upon electricity and magnetism, and was sometimes referred to as "the third volume of Maxwell". In it, Thomson emphasized physical methods and experimentation and included extensive figures and diagrams of apparatus, including a number for the passage of electricity through gases. His third book, [http://catalog.hathitrust.org/Record/001985977 Elements of the mathematical theory of electricity and magnetism] (1895){{cite journal|author=Mackenzie, A. Stanley|author-link=Arthur Stanley Mackenzie|title=Review: Elements of the Mathematical Theory of Electricity and Magnetism by J. J. Thomson|journal=Bull. Amer. Math. Soc.|year=1896|volume=2|issue=10|pages=329–333|url=https://www.ams.org/journals/bull/1896-02-10/S0002-9904-1896-00357-8/S0002-9904-1896-00357-8.pdf|doi=10.1090/s0002-9904-1896-00357-8|doi-access=free}} was a readable introduction to a wide variety of subjects, and achieved considerable popularity as a textbook.

File:Thomson-13.jpg

A series of four lectures, given by Thomson on a visit to Princeton University in 1896, were subsequently published as Discharge of electricity through gases (1897). Thomson also presented a series of six lectures at Yale University in 1904.

=Discovery of the electron=

Several scientists, such as William Prout and Norman Lockyer, had suggested that atoms were built up from a more fundamental unit, but they envisioned this unit to be the size of the smallest atom, hydrogen. Thomson in 1897 was the first to suggest that one of the fundamental units of the atom was more than 1,000 times smaller than an atom, suggesting the subatomic particle now known as the electron. Thomson discovered this through his explorations on the properties of cathode rays. Thomson made his suggestion on 30 April 1897 following his discovery that cathode rays (at the time known as Lenard rays) could travel much further through air than expected for an atom-sized particle.{{cite journal |last=Thomson |first=J.J. |year=1897 |url=https://books.google.com/books?id=vBZbAAAAYAAJ&pg=PA104 |title=Cathode Rays |journal=The Electrician |volume=39 |page=104}} He estimated the mass of cathode rays by measuring the heat generated when the rays hit a thermal junction and comparing this with the magnetic deflection of the rays. His experiments suggested not only that cathode rays were over 1,000 times lighter than the hydrogen atom, but also that their mass was the same in whichever type of atom they came from. He concluded that the rays were composed of very light, negatively charged particles which were a universal building block of atoms. He called the particles "corpuscles", but later scientists preferred the name electron which had been suggested by George Johnstone Stoney in 1891, prior to Thomson's actual discovery.{{cite book |last=Falconer |first=Isobel |year=2001 |chapter=Corpuscles to electrons |chapter-url=https://isobelf.files.wordpress.com/2013/08/falconer_corpusclestoelectrons_preprint.pdf |editor1-last=Buchwald |editor1-first=J. Z.|editor2-last=Warwick |editor2-first=A. |title=Histories of the Electron |publisher=MIT Press |pages=77–100 |isbn=978-0262024945}}

In April 1897, Thomson had only early indications that the cathode rays could be deflected electrically (previous investigators such as Heinrich Hertz had thought they could not be). A month after Thomson's announcement of the corpuscle, he found that he could reliably deflect the rays by an electric field if he evacuated the discharge tube to a very low pressure. By comparing the deflection of a beam of cathode rays by electric and magnetic fields he obtained more robust measurements of the mass-to-charge ratio that confirmed his previous estimates.{{cite journal|last1=Thomson|first1=J. J.|title=Cathode Rays|journal=Philosophical Magazine|date=7 August 1897|volume=44|issue=269|page=293|url=https://zenodo.org/records/1431235/files/article.pdf|access-date=4 August 2014|series=5|doi=10.1080/14786449708621070}} This became the classic means of measuring the charge-to-mass ratio of the electron. Later in 1899 he measured the charge of the electron to be of {{val|6.8|e=−10|u=esu}}.{{cite journal |last1=Thomson |first1=J.J. |title=On the masses of the ions in gases at low pressures |journal=The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science |date=1899 |volume=48 |issue=295 |pages=547–567 |doi=10.1080/14786449908621447 |url=https://www.tandfonline.com/doi/abs/10.1080/14786449908621447 |access-date=28 December 2024}}

Thomson believed that the corpuscles emerged from the atoms of the trace gas inside his cathode-ray tubes. He thus concluded that atoms were divisible, and that the corpuscles were their building blocks. In 1904, Thomson suggested a model of the atom, hypothesizing that it was a sphere of positive matter within which electrostatic forces determined the positioning of the corpuscles. To explain the overall neutral charge of the atom, he proposed that the corpuscles were distributed in a uniform sea of positive charge. In this "plum pudding model", the electrons were seen as embedded in the positive charge like raisins in a plum pudding (although in Thomson's model they were not stationary, but orbiting rapidly).{{citation|title=Modern Inorganic Chemistry|first=Joseph William|last=Mellor|publisher=Longmans, Green and Company|year=1917|page=868|url=https://books.google.com/books?id=1iQ7AQAAMAAJ&pg=PA868|quote=According to J. J. Thomson's hypothesis, atoms are built of systems of rotating rings of electrons.}}{{harvtxt|Dahl|1997}}, p. 324: "[https://books.google.com/books?id=xUzaWGocMdMC&pg=PA324 Thomson's model, then, consisted of a uniformly charged sphere of positive electricity (the pudding), with discrete corpuscles (the plums) rotating about the center in circular orbits, whose total charge was equal and opposite to the positive charge.]"

Thomson made the discovery around the same time that Walter Kaufmann and Emil Wiechert discovered the correct mass to charge ratio of these cathode rays (electrons).{{cite journal |last1=Chown |first1=Marcus |title=Forum: Just who did discover the electron? |journal=New Scientist |date=29 March 1997 |issue=2075 |url=https://www.newscientist.com/article/mg15320756-400-forum-just-who-did-discover-the-electron-marcus-chown-says-the-truth-is-not-quite-as-the-history-books-suggest/ |access-date=17 October 2020 |quote=Marcus Chown says the truth is not quite as the history books suggest.}}

The name "electron" was adopted for these particles by the scientific community, mainly due to the advocation by George Francis FitzGerald, Joseph Larmor, and Hendrik Lorentz.

{{cite journal

| last =O'Hara

| first =J. G.

| title =George Johnstone Stoney, F.R.S., and the Concept of the Electron

| journal =Notes and Records of the Royal Society of London

| volume =29

| issue =2

| pages =265–276

| publisher =Royal Society

| date =March 1975

| jstor =531468

| doi =10.1098/rsnr.1975.0018

| s2cid =145353314

}}{{rp|273}} The term was originally coined by George Johnstone Stoney in 1891 as a tentative name for the basic unit of electrical charge (which had then yet to be discovered).{{cite journal |author=George Johnstone Stoney |year=1891 |title=On the Cause of Double Lines and of Equidistant Satellites in the Spectra of Gases |journal=The Scientific Transactions of the Royal Dublin Society |volume=4 |pages=583–608 |url=https://digitalarchive.rds.ie/files/show/4769}}{{cite journal |journal=Philosophical Magazine |author=George Johnstone Stoney |date=1894 |title=Of the "Electron", or Atom of Electricity |series=Series 5 |volume=38 |issue=233 |pages=418–420 |url=https://archive.org/details/londonedinburgh5381894lon/page/418/mode/2up}} For some years Thomson resisted using the word "electron" because he didn't like how some physicists talked of a "positive electron" that was supposed to be the elementary unit of positive charge just as the "negative electron" is the elementary unit of negative charge. Thomson preferred to stick with the word "corpuscle" which he strictly defined as negatively charged.{{cite journal |year=1907 |author=J. J. Thomson |title=The Modern Theory of Electrical Conductivity of Metals |journal=Journal of the Institution of Electrical Engineers |volume=38 |issue=183 |pages=455–468|doi=10.1049/jiee-1.1907.0026 |url=https://books.google.com/books?id=Ni9HAQAAMAAJ&pg=PA467}}: "Perhaps I can best show my appreciation by trying to answer the questions which Professor Silvanus Thompson addressed to me. I think his first question was a question rather of notation, as to the difference between the electron and the corpuscle. I prefer the corpuscle for two reasons: first of all, it is my own child, and I have a kind of parental affection for it; and, secondly, I think it has one merit which the term electron has not. We talk about positive and negative electrons, and I think when you use the same term for the two the suggestion is that there is an equality, so to speak, in the properties. From my point of view the difference between the negative and the positive is essential, and much greater than I think would be suggested by the term positive electron and negative electron. Therefore I prefer to use a special term for the negative units and call it a corpuscle. A corpuscle is just a negative electron." He relented by 1914, using the word "electron" in his book The Atomic Theory.{{cite book |author=J. J. Thomson |year=1914 |title=The Atomic Theory |publisher=Oxford Clarendon Press |url=https://archive.org/details/atomictheorythom00thomrich/page/n3/mode/2up}} In 1920, Rutherford and his fellows agreed to call the nucleus of the hydrogen ion "proton", establishing a distinct name for the smallest known positively-charged particle of matter (that can exist independently anyway).{{cite journal |author=Orme Masson |date=1921 |title=The Constitution of Atoms |journal=The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science |volume=41 |issue=242 |pages=281–285 |doi=10.1080/14786442108636219 |url=https://zenodo.org/records/1430963/files/article.pdf%3Fdownload%3D1&ved=2ahUKEwjN-YzeqIiGAxVyUqQEHaM_COwQFnoECBwQAQ&usg=AOvVaw1G76aUFXByKGSDekUwv2sa}}
Footnote by Ernest Rutherford: 'At the time of writing this paper in Australia, Professor Orme Masson was not aware that the name "proton" had already been suggested as a suitable name for the unit of mass nearly 1, in terms of oxygen 16, that appears to enter into the nuclear structure of atoms. The question of a suitable name for this unit was discussed at an informal meeting of a number of members of Section A of the British Association [for the Advancement of Science] at Cardiff this year. The name "baron" suggested by Professor Masson was mentioned, but was considered unsuitable on account of the existing variety of meanings. Finally the name " proton" met with general approval, particularly as it suggests the original term "protyle " given by Prout in his well-known hypothesis that all atoms are built up of hydrogen. The need of a special name for the nuclear unit of mass 1 was drawn attention to by Sir Oliver Lodge at the Sectional meeting, and the writer then suggested the name "proton."'

=Isotopes and mass spectrometry=

File:Discovery of neon isotopes.JPG

In 1912, as part of his exploration into the composition of the streams of positively charged particles then known as canal rays, Thomson and his research assistant F. W. Aston channelled a stream of neon ions through a magnetic and an electric field and measured its deflection by placing a photographic plate in its path. They observed two patches of light on the photographic plate (see image on right), which suggested two different parabolas of deflection, and concluded that neon is composed of atoms of two different atomic masses (neon-20 and neon-22), that is to say of two isotopes.J.J. Thomson (1912) "Further experiments on positive rays," Philosophical Magazine, series 6, 24 (140): 209–253.J. J. Thomson (1913) "Rays of positive electricity", Proceedings of the Royal Society A, 89: 1–20. This was the first evidence for isotopes of a stable element; Frederick Soddy had previously proposed the existence of isotopes to explain the decay of certain radioactive elements.

Thomson's separation of neon isotopes by their mass was the first example of mass spectrometry, which was subsequently improved and developed into a general method by F. W. Aston and by A. J. Dempster.{{cite web |author-first=Mark |author-last=Jones|title=Gas Chromatography-Mass Spectrometry |url=https://www.acs.org/content/acs/en/education/whatischemistry/landmarks/gas-chromatography-mass-spectrometry.html |publisher=American Chemical Society |access-date=19 November 2019}}

{{external media | width = 180px | float = right | headerimage= 180px | video1 = [https://www.youtube.com/watch?v=WH-U_qCEzT0 The Early Life of J. J. Thomson: Computational Chemistry and Gas Discharge Experiments]}}

=Experiments with cathode rays=

Earlier, physicists debated whether cathode rays were immaterial like light ("some process in the aether") or were "in fact wholly material, and ... mark the paths of particles of matter charged with negative electricity", quoting Thomson. The aetherial hypothesis was vague, but the particle hypothesis was definite enough for Thomson to test.

==Magnetic deflection==

Thomson first investigated the magnetic deflection of cathode rays. Cathode rays were produced in the side tube on the left of the apparatus and passed through the anode into the main bell jar, where they were deflected by a magnet. Thomson detected their path by the fluorescence on a squared screen in the jar. He found that whatever the material of the anode and the gas in the jar, the deflection of the rays was the same, suggesting that the rays were of the same form whatever their origin.{{cite journal |last=Thomson |first=J. J. |date=8 February 1897 |title=On the cathode rays |journal=Proceedings of the Cambridge Philosophical Society |volume=9 |page=243}}

==Electrical charge ==

File:JJ Thomson Cathode Ray Tube 1.png

While supporters of the aetherial theory accepted the possibility that negatively charged particles are produced in Crookes tubes,{{Citation needed|date=June 2012}} they believed that they are a mere by-product and that the cathode rays themselves are immaterial.{{Citation needed|date=June 2012}} Thomson set out to investigate whether or not he could actually separate the charge from the rays.

Thomson constructed a Crookes tube with an electrometer set to one side, out of the direct path of the cathode rays. Thomson could trace the path of the ray by observing the phosphorescent patch it created where it hit the surface of the tube. Thomson observed that the electrometer registered a charge only when he deflected the cathode ray to it with a magnet. He concluded that the negative charge and the rays were one and the same.

{{Clear}}

==Electrical deflection==

{{more citations needed|section|date=August 2017}}

{{multiple image

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| image1 = JJ Thomson Cathode Ray 2.png

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| caption1 = Thomson's illustration of the Crookes tube by which he observed the deflection of cathode rays by an electric field (and later measured their mass-to-charge ratio). Cathode rays were emitted from the cathode C, passed through slits A (the anode) and B (grounded), then through the electric field generated between plates D and E, finally impacting the surface at the far end.

| image2 = Thomson cathode ray exp.gif

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| caption2 = The cathode ray (blue line) was deflected by the electric field (yellow).

}}

File:JJThomsonGasDischargeTubeElectronCavendishLab2013-08-29-17-11-41.jpg

In May–June 1897, Thomson investigated whether or not the rays could be deflected by an electric field. Previous experimenters had failed to observe this, but Thomson believed their experiments were flawed because their tubes contained too much gas.

Thomson constructed a Crookes tube with a better vacuum. At the start of the tube was the cathode from which the rays projected. The rays were sharpened to a beam by two metal slits – the first of these slits doubled as the anode, the second was connected to the earth. The beam then passed between two parallel aluminium plates, which produced an electric field between them when they were connected to a battery. The end of the tube was a large sphere where the beam would impact on the glass, created a glowing patch. Thomson pasted a scale to the surface of this sphere to measure the deflection of the beam. Any electron beam would collide with some residual gas atoms within the Crookes tube, thereby ionizing them and producing electrons and ions in the tube (space charge); in previous experiments this space charge electrically screened the externally applied electric field. However, in Thomson's Crookes tube the density of residual atoms was so low that the space charge from the electrons and ions was insufficient to electrically screen the externally applied electric field, which permitted Thomson to successfully observe electrical deflection.

When the upper plate was connected to the negative pole of the battery and the lower plate to the positive pole, the glowing patch moved downwards, and when the polarity was reversed, the patch moved upwards.

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==Measurement of mass-to-charge ratio==

thumb

In his classic experiment, Thomson measured the mass-to-charge ratio of the cathode rays by measuring how much they were deflected by a magnetic field and comparing this with the electric deflection. He used the same apparatus as in his previous experiment, but placed the discharge tube between the poles of a large electromagnet. He found that the mass-to-charge ratio was over a thousand times lower than that of a hydrogen ion (H+), suggesting either that the particles were very light and/or very highly charged. Significantly, the rays from every cathode yielded the same mass-to-charge ratio. This is in contrast to anode rays (now known to arise from positive ions emitted by the anode), where the mass-to-charge ratio varies from anode-to-anode. Thomson himself remained critical of what his work established, in his Nobel Prize acceptance speech referring to "corpuscles" rather than "electrons".

Thomson's calculations can be summarised as follows (in his original notation, using F instead of E for the electric field and H instead of B for the magnetic field):

The electric deflection is given by \Theta = Fel / mv^2, where Θ is the angular electric deflection, F is applied electric intensity, e is the charge of the cathode ray particles, l is the length of the electric plates, m is the mass of the cathode ray particles and v is the velocity of the cathode ray particles. The magnetic deflection is given by \phi = Hel / mv, where φ is the angular magnetic deflection and H is the applied magnetic field intensity.

The magnetic field was varied until the magnetic and electric deflections were the same, when \Theta = \phi, Fel / mv^2 = Hel / mv. This can be simplified to give m/e = H^2 l/F\Theta. The electric deflection was measured separately to give Θ and H, F and l were known, so m/e could be calculated.

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==Conclusions==

{{blockquote|As the cathode rays carry a charge of negative electricity, are deflected by an electrostatic force as if they were negatively electrified, and are acted on by a magnetic force in just the way in which this force would act on a negatively electrified body moving along the path of these rays, I can see no escape from the conclusion that they are charges of negative electricity carried by particles of matter.|J. J. Thomson}}

As to the source of these particles, Thomson believed they emerged from the molecules of gas in the vicinity of the cathode.

{{blockquote|If, in the very intense electric field in the neighbourhood of the cathode, the molecules of the gas are dissociated and are split up, not into the ordinary chemical atoms, but into these primordial atoms, which we shall for brevity call corpuscles; and if these corpuscles are charged with electricity and projected from the cathode by the electric field, they would behave exactly like the cathode rays.|J. J. Thomson{{cite journal |last=Thomson |first=J. J.|url=http://web.lemoyne.edu/~GIUNTA/thomson1897.html |title=Cathode rays |journal=Philosophical Magazine |volume=44 |page=293 |year=1897}}}}

Thomson imagined the atom as being made up of these corpuscles orbiting in a sea of positive charge; this was his plum pudding model. This model was later proved incorrect when his student Ernest Rutherford showed that the positive charge is concentrated in the nucleus of the atom.

=Other work=

In 1905, Thomson discovered the natural radioactivity of potassium.{{cite journal|doi=10.1080/14786440509463405|title=On the emission of negative corpuscles by the alkali metals|journal=Philosophical Magazine |series=Series 6|year=1905|first=J. J. |last=Thomson|volume=10|issue=59|pages=584–590|url=https://zenodo.org/record/1430786}}

In 1906, Thomson demonstrated that hydrogen had only a single electron per atom. Previous theories allowed various numbers of electrons.{{The Timetables of Science|pages=411}}{{cite journal|title=On the Number of Corpuscles in an Atom |journal=Philosophical Magazine |date=June 1906 |first=J. J. |last=Thomson |volume=11 |issue= 66|pages=769–781 |url=https://zenodo.org/record/1430808 |access-date=4 October 2008 |doi=10.1080/14786440609463496 |url-status= }}

Awards and honours

=During his life=

File:J.J. Thomson Plaque outside the Old Cavendish Laboratory.jpg

File:1923 JJ Thomson.jpg portrait by Georges Chevalier, 1923]]

File:Sir J.J. Thomson LCCN2014715407.jpg

Thomson was elected a Fellow of the Royal Society (FRS){{cite book|last1=Thomson|first1=Sir George Paget|chapter=Sir J.J. Thomson, British Physicist|title=Encyclopædia Britannica|chapter-url=https://www.britannica.com/EBchecked/topic/593074/Sir-JJ-Thomson|access-date=11 February 2015}} and appointed to the Cavendish Professorship of Experimental Physics at the Cavendish Laboratory, University of Cambridge in 1884. Thomson won numerous awards and honours during his career including:

Thomson was elected a fellow of the Royal Society on 12 June 1884 and served as President of the Royal Society from 1915 to 1920. He was elected to membership of the Manchester Literary and Philosophical Society on 30 April 1895.

Thomson was elected an International Honorary Member of the American Academy of Arts and Sciences in 1902, and International Member of the American Philosophical Society in 1903, and the United States National Academy of Sciences in 1903.{{Cite web |date=2023-02-10 |title=Joseph John Thomson |url=https://www.amacad.org/person/joseph-john-thomson |access-date=2024-02-02 |website=American Academy of Arts & Sciences |language=en}}{{Cite web |title=APS Member History |url=https://search.amphilsoc.org/memhist/search?creator=Joseph+J.+Thomson&title=&subject=&subdiv=&mem=&year=&year-max=&dead=&keyword=&smode=advanced |access-date=2024-02-02 |website=search.amphilsoc.org}}{{Cite web |title=Joseph J. Thomson |url=https://www.nasonline.org/member-directory/deceased-members/20001201.html |access-date=2024-02-02 |publisher=National Academy of Sciences}}

In November 1927, Thomson opened the Thomson building, named in his honour, in the Leys School, Cambridge.{{cite web|url=https://www.theleys.net/about-us/history/thomson-building|archive-url=https://web.archive.org/web/20150111042826/https://www.theleys.net/about-us/history/thomson-building|url-status=dead|archive-date=2015-01-11|title=Opening of the New Science Building: Thomson|access-date=2015-01-10|date=2005-12-01}}

=Posthumous=

In 1991, the thomson (symbol: Th) was proposed as a unit to measure mass-to-charge ratio in mass spectrometry in his honour.{{cite journal|title=The 'Thomson'. A suggested unit for mass spectroscopists|journal=Rapid Communications in Mass Spectrometry|year=1991|first=R. G.|last=Cooks|author2=A. L. Rockwood|volume=5|issue=2|page=93}}

J J Thomson Avenue, on the University of Cambridge's West Cambridge site, is named after Thomson.{{cite web|url=http://www.cambridgenetwork.co.uk/news/cambridge-physicist-is-streets-ahead/|title=Cambridge Physicist is streets ahead|access-date=2014-07-31|date=2002-07-18|archive-date=2 February 2017|archive-url=https://web.archive.org/web/20170202024535/http://www.cambridgenetwork.co.uk/news/cambridge-physicist-is-streets-ahead/|url-status=dead}}

The Thomson Medal Award, sponsored by the International Mass Spectrometry Foundation, is named after Thomson.{{cite web |title=Awards Page – Thomson Medal Award |url=https://www.imss.nl/awards.html |website=International Mass Spectrometry Foundation |archive-url=https://web.archive.org/web/20190513131140/https://www.imss.nl/awards.html |access-date=7 March 2023 |archive-date=13 May 2019 |quote=The Thomson Medal Award is named after Sir J. J. Thomson, who was responsible for the first mass spectrograph}}

The Institute of Physics Joseph Thomson Medal and Prize is named after Thomson.{{cite web |title=Silver Subject Medals and Prizes |url=https://www.iop.org/about/awards/silver-subject-medals#thomson |publisher=Institute of Physics |access-date=7 March 2023 }}

Thomson Crescent in Deep River, Ontario, connects with Rutherford Ave.

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See also

References

{{Reflist}}

Bibliography

File:Thomson-8.jpg

File:Thomson-2.jpg

  • 1883. A Treatise on the Motion of Vortex Rings: An essay to which the Adams Prize was adjudged in 1882, in the University of Cambridge. London: Macmillan and Co., pp. 146. Recent reprint: {{ISBN|0-543-95696-2}}.
  • 1888. Applications of Dynamics to Physics and Chemistry. London: Macmillan and Co., pp. 326. Recent reprint: {{ISBN|1-4021-8397-6}}.
  • 1893. [https://libserv.aip.org/ipac20/ipac.jsp?session=1674O3899X03Q.1860471&profile=rev-nbl&source=~!horizon&view=subscriptionsummary&uri=full=3100006~!44260~!4&ri=5&aspect=power&menu=search&ipp=20&spp=20&staffonly=&term=Notes+on+Recent+Researches+in+Electricity+and+Magnetism&index=.GW&uindex=&aspect=power&menu=search&ri=5 Notes on recent researches in electricity and magnetism: intended as a sequel to Professor Clerk-Maxwell's 'Treatise on Electricity and Magnetism{{'}}.] Oxford University Press, pp. xvi & 578. 1991, Cornell University Monograph: {{ISBN|1-4297-4053-1}}.
  • {{Cite book|author=Thomson, Joseph John|title=Notes on recent researches in electricity and magnetism|publisher=Clarendon Press|location=Oxford|year=1893|language=en|url=https://gutenberg.beic.it/webclient/DeliveryManager?pid=11926786}}
  • {{Cite book|author=Thomson, Joseph John|title=Discharge of electricity through gases|publisher=Johann Ambrosius Barth|location=Leipzig|year=1900|language=de|url=https://gutenberg.beic.it/webclient/DeliveryManager?pid=6577088}}
  • Thomson, Joseph John (1904). [https://libserv.aip.org/ipac20/ipac.jsp?session=1674O3899X03Q.1860471&profile=rev-nbl&source=~!horizon&view=subscriptionsummary&uri=full=3100006~!44622~!2&ri=8&aspect=power&menu=search&ipp=20&spp=20&staffonly=&term=%22Electricity+and+Matter%22&index=.GW&uindex=&aspect=power&menu=search&ri=8 Electricity and matter] (in English). Oxford : Clarendon Press.
  • {{Cite book|author=Thomson, Joseph John|title=Electricity and matter|publisher=Hoepli|location=Milano|year=1905|language=it|url=https://gutenberg.beic.it/webclient/DeliveryManager?pid=7160090}}
  • {{Cite book|author=Thomson, Joseph John|title=Corpuscular theory of matter|publisher=Vieweg und Sohn|location=Braunschweig|year=1908|language=de|url=https://gutenberg.beic.it/webclient/DeliveryManager?pid=6577571}}
  • 1921 (1895). Elements of the Mathematical Theory of Electricity And Magnetism. London: Macmillan and Co. [https://books.google.com/books?id=w9kEAAAAYAAJ&q=elements+of+the+mathematical+theory+of+electricity+and+magnetism Scan of 1895 edition.]
  • A Text book of Physics in Five Volumes, co-authored with J.H. Poynting: (1) Properties of Matter, (2) Sound, (3) Heat, (4) Light, and (5) Electricity and Magnetism. Dated 1901 and later, and with revised later editions.
  • {{cite book|last=Dahl|first=Per F.|title=Flash of the Cathode Rays: A History of J J Thomson's Electron|url=https://archive.org/details/flashofcathodera0000dahl/page/n5/mode/2up|url-access=registration|year=1997|publisher=Institute of Physics Publishing|location=Bristol and Philadelphia|isbn=0-7503-0453-7}}
  • J.J. Thomson (1897) "Cathode Rays", The Electrician 39, 104, also published in Proceedings of the Royal Institution 30 April 1897, 1–14 – first announcement of the "corpuscle" (before the classic mass and charge experiment)
  • J.J. Thomson (1897), [http://web.lemoyne.edu/~GIUNTA/thomson1897.html Cathode rays], Philosophical Magazine, 44, 293 – the classic measurement of the electron mass and charge
  • J.J. Thomson (1904), [https://web.archive.org/web/20131213172104/http://www.cond-mat.physik.uni-mainz.de/~oettel/ws10/thomson_PhilMag_7_237_1904.pdf "On the Structure of the Atom]: an Investigation of the Stability and Periods of Oscillation of a number of Corpuscles arranged at equal intervals around the Circumference of a Circle; with Application of the Results to the Theory of Atomic Structure," Philosophical Magazine Series 6, Volume 7, Number 39, pp. 237–265. This paper presents the classical "plum pudding model" from which the Thomson Problem is posed.
  • {{cite journal

|author=J. J. Thomson

|year=1906

|title=On the Number of Corpuscles in an Atom

|journal=Philosophical Magazine

|series=6 |volume=11 |issue=66 |pages=769–781

|doi=10.1080/14786440609463496

|url=https://gilles.montambaux.com/files/histoire-physique/Thomson-1906.pdf

}}

  • {{cite book|author=Joseph John Thomson|title=On the Light Thrown by Recent Investigations on Electricity on the Relation Between Matter and Ether: The Adamson Lecture Delivered at the University on November 4, 1907|url=https://books.google.com/books?id=A0RBAAAAYAAJ|year=1908|publisher=University Press}}File:Thomson, Joseph John – Corpuscular theory of matter, 1908 – BEIC 6577571.jpg
  • J.J. Thomson (1912), "Further experiments on positive rays" Philosophical Magazine, 24, 209–253 – first announcement of the two neon parabolae
  • J.J. Thomson (1913), [http://web.lemoyne.edu/~giunta/canal.html Rays of positive electricity], Proceedings of the Royal Society, A 89, 1–20 – discovery of neon isotopes
  • J.J. Thomson (1923), The Electron in Chemistry: Being Five Lectures Delivered at the Franklin Institute, Philadelphia.
  • Thomson, Sir J. J. (1936), Recollections and Reflections, London: G. Bell & Sons, Ltd. Republished as [https://books.google.com/books?id=K8mn6N7oPzwC&q=Recollections+and+Reflections+thomson digital edition], Cambridge: University Press, 2011 (Cambridge Library Collection series).
  • Thomson, George Paget. (1964) J.J. Thomson: Discoverer of the Electron. Great Britain: Thomas Nelson & Sons, Ltd.
  • Davis, Eward Arthur & Falconer, Isobel (1997), J.J. Thomson and the Discovery of the Electron. {{ISBN|978-0-7484-0696-8}}
  • Falconer, Isobel (1988) "J.J. Thomson's Work on Positive Rays, 1906–1914" Historical Studies in the Physical and Biological Sciences 18(2) 265–310
  • Falconer, Isobel (2001) "Corpuscles to Electrons" in J Buchwald and A Warwick (eds) Histories of the Electron, Cambridge, Mass: MIT Press, pp. 77–100.
  • {{cite journal |last1=Navarro |first1=Jaume |title=J. J. Thomson on the Nature of Matter: Corpuscles and the Continuum |journal=Centaurus |date=2005 |volume=47 |issue=4 |pages=259–282 |doi=10.1111/j.1600-0498.2005.00028.x|bibcode=2005Cent...47..259N }}
  • {{cite journal|doi=10.1016/j.jasms.2009.07.008|pmid=19734055|title=J. J. Thomson goes to America|journal=Journal of the American Society for Mass Spectrometry|volume=20|issue=11|pages=1964–1973|year=2009|last1=Downard|first1=Kevin M.|s2cid=34371775 |doi-access=|bibcode=2009JASMS..20.1964D }}