Lanthanum(III) sulfate
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| OtherNames = {{Unbulleted list
| Lanthanum sulfate
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| Section1 = {{Chembox Identifiers
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| CASNo = 10099-60-2
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| ChemSpiderID = 140072
| EC_number = 233-239-6
| Gmelin =
| InChI = 1S/2La.3H2O4S/c;;3*1-5(2,3)4/h;;3*(H2,1,2,3,4)/q2*+3;;;/p-6
| KEGG =
| PubChem = 159259
| UNII = 4636PY459O
| UNNumber = 4636PY459O
| StdInChIKey = VQEHIYWBGOJJDM-UHFFFAOYSA-H
| SMILES = [O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[La+3].[La+3]
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| Section2 = {{Chembox Properties
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| Appearance = White solid{{cite book |editor1-last=Haynes |editor1-first=William |title=CRC Handbook of Chemistry and Physics |date=2016 |publisher=CRC Press |isbn=9781439880500 |page=4-70 |edition=93rd |language=en}}
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| Density = 2.82 g/cm3 (nonahydrate)
| Formula = La2(SO4)3
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| MolarMass = 566.00 g/mol
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| MeltingPtC = 775
| MeltingPt_notes= (decomposition)
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| Solubility = 2.7 g/100 mL (20 °C, nonahydrate)
| SolubleOther = insoluble in ethanol
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| Section3 = {{Chembox Structure
| CrystalStruct = hexagonal
| SpaceGroup = P63
| LattConst_a = 11.01 Å
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| LattConst_c = 8.08 Å
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| Section4 = {{Chembox Thermochemistry
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| Section7 = {{Chembox Hazards
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| NFPA-H = 0
| NFPA-F = 0
| NFPA-I = 1
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| GHS_ref=[https://pubchem.ncbi.nlm.nih.gov/compound/159259#section=Safety-and-Hazards]
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|315|319|335}}
| PPhrases = {{P-phrases|261|264|264+265|271|280|302+352|304+340|305+351+338|319|321|332+317|337+317|362+364|403+233|405|501}}
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| Section9 = {{Chembox Related
| OtherAnions = Lanthanum(III) nitrate
| OtherCations = Cerium(III) sulfate
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Lanthanum(III) sulfate is an inorganic compound with the formula La2(SO4)3·xH2O (0 ≥ x ≥ 9). It forms various hydrates, the most common one being the nonahydrate, which are all white solids. It is an intermediate in producing lanthanum from its ores.{{harvp|Greenwood|Earnshaw|1984|pp=1426–1429}}
Preparation and reactions
The nonahydrate is produced by dissolving lanthanum or lanthanum hydroxide in dilute sulfuric acid, then evaporating the solution:{{cite journal |author1=Richard A. Vanderpool |author2=Masood A. Khan |author3=Roger Frech |title=Structure and Raman spectra of single crystal La2(SO4)3 · 8H2O |journal=Journal of Molecular Structure |date=1991 |volume=245 |issue=3–4 |pages=255–273 |doi=10.1016/0022-2860(91)87101-M |language=en}}
:2 La + 3 H2SO4 → La2(SO4)3 + 3 H2
The anhydrous compound can be produced by heating the hydrates to 300 °C. If heated further, anhydrous lanthanum(III) sulfate decomposes to La2O2SO4 at 775 °C, which in turn decomposes to lanthanum(III) oxide at 1100 °C.
Structure
References
{{reflist}}
Bibliography
- {{Greenwood&Earnshaw1st}} {{sfn whitelist|CITEREFGreenwoodEarnshaw1984}}
{{Lanthanum compounds}}
{{sulfates}}