Leonhard Grill

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Leonhard Grill is an Austrian experimental physicist. He is a professor at the University of Graz in the field of nanoscience, in particular with functional molecules on surfaces.

Education

After his undergraduate studies in physics at the University of Graz,{{Cite web |title=Leonhard Grill, Professor an der Universität Graz - nano-lab.uni-graz.at |url=https://nano-lab.uni-graz.at/en/about-us/leonhard-grill/ |access-date=2024-11-26 |website=nano-lab.uni-graz.at}}Diploma thesis - {{lang|de|Leonhard Grill, Struktur und Reaktivität der seltenen Erdmetalle Praseodym, Europium und Erbium auf Si(111) : auf der Suche nach zweidimensionalen Siliziden}}, 1996

Catalogue, Library of the University of Graz

https://permalink.obvsg.at/UGR/AC01649386 Grill worked with Silvio Modesti at the {{lang|it|Istituto Nazionale per la Fisica della Materia}} (INFM) in Trieste on his doctoral thesis: "Growth of thin metallic overlayers on Ge(111): Electron confinement and characterization of image resonances by selective electron scattering".{{Cite web |title=Leonhard Grill, Professor an der Universität Graz - nano-lab.uni-graz.at |url=https://nano-lab.uni-graz.at/en/about-us/leonhard-grill/ |access-date=2024-11-26 |website=nano-lab.uni-graz.at}}PhD thesis - Leonhard Grill, Growth of thin metallic overlayers on Ge(111) : electron confinement and characterization of image resonances by selective electron scattering, 2001

Catalogue, Library of the University of Graz

https://permalink.obvsg.at/UGR/AC03345182 He then moved to the Freie University of Berlin (FU Berlin) to work with Karl-Heinz Rieder{{Cite journal |date=January 2007 |title=Research highlights |url=https://www.nature.com/articles/445342a |journal=Nature |language=en |volume=445 |issue=7126 |pages=342–343 |doi=10.1038/445342a |bibcode=2007Natur.445..342. |issn=1476-4687}} where he began to work on the manipulation of single molecules using scanning tunneling microscopy (STM).{{cite journal |doi=10.1088/1742-6596/19/1/028 |title=Force induced and electron stimulated STM manipulations: Routes to artificial nanostructures as well as to molecular contacts, engines and switches |date=2005 |last1=Rieder |first1=Karl-Heinz |last2=Meyer |first2=Gerhard |last3=Moresco |first3=Francesca |last4=Morgenstern |first4=Karina |last5=Hla |first5=Saw-Wai |last6=Repp |first6=Jascha |last7=Alemani |first7=Micol |last8=Grill |first8=Leonhard |last9=Gross |first9=Leo |last10=Mehlhorn |first10=Michael |last11=Gawronski |first11=Heiko |last12=Simic-Milosevich |first12=Violeta |last13=Henzl |first13=Jörg |last14=Braun |first14=Kai F. |last15=Foelsch |first15=Stefan |last16=Bartels |first16=Ludwig |display-authors=3 |journal=Journal of Physics: Conference Series |volume=19 |issue=1 |pages=175–181 |bibcode=2005JPhCS..19..175R |doi-access=free }}{{Cite journal |last=ALEXANDER |first=Still |date=2011 |title=MaxPlanckResearch 2/2011 - Focus: Medicine of Tomorrow |url=https://www.mpg.de/4379702/MPR_2011_2.pdf |journal=Research - the Science Magazine of the Max Planck Society |volume=2 - 2011 |pages=73–77}} In 2007 he submitted his habilitation at the FU Berlin.{{Cite thesis |last=Leonhard |first=Grill |date=2007 |title=Functionalized molecules studied by STM: Towards molecular nanotechnology: Habilitationsschrift |language=en |doi=10.17169/refubium-45504 |doi-access=free}}

Academic career

He was appointed Professor of Physical Chemistry at the University of Graz in 2013.{{Cite web |title=Journal of the University of Graz with the Appointment of Leonhard Grill as Professor, Section 329 |url=https://mitteilungsblatt.uni-graz.at/de/2012-13/39/html/ |access-date=2024-11-25 |website=mitteilungsblatt.uni-graz.at}}

Research

Grill's research group uses scanning tunneling microscopy and spectroscopy to study and selectively manipulate molecules on surfaces. His interests range from chemical processes of single atoms and molecules to the bottom-up growth of two-dimensional supra- and macromolecular assemblies. Additional research areas include molecules with mechanical, chemical, electronic, optical or electrical functionalities.{{Cite web |title=Leonhard Grill, Professor an der Universität Graz - nano-lab.uni-graz.at |url=https://nano-lab.uni-graz.at/de/ueber-uns/leonhard-grill/ |access-date=2024-12-04 |website=nano-lab.uni-graz.at}}

By pulling individual polymers off of a surface with the tip of the scanning tunnelling microscope, Grill's group was able to measure for the first time the conductivity of individual molecular wires as a function of their length.{{Cite journal |last1=Lafferentz |first1=Leif |last2=Ample |first2=Francisco |last3=Yu |first3=Hao |last4=Hecht |first4=Stefan |last5=Joachim |first5=Christian |last6=Grill |first6=Leonhard |date=2009-02-27 |title=Conductance of a Single Conjugated Polymer as a Continuous Function of Its Length |url=https://www.science.org/doi/10.1126/science.1168255 |journal=Science |language=en |volume=323 |issue=5918 |pages=1193–1197 |doi=10.1126/science.1168255 |pmid=19251624 |bibcode=2009Sci...323.1193L |issn=0036-8075|url-access=subscription }}{{Cite journal |last1=Koch |first1=Matthias |last2=Ample |first2=Francisco |last3=Joachim |first3=Christian |last4=Grill |first4=Leonhard |date=December 2012 |title=Voltage-dependent conductance of a single graphene nanoribbon |url=https://www.nature.com/articles/nnano.2012.169 |journal=Nature Nanotechnology |language=en |volume=7 |issue=11 |pages=713–717 |doi=10.1038/nnano.2012.169 |pmid=23064554 |bibcode=2012NatNa...7..713K |issn=1748-3387|url-access=subscription }} He studied the switching mechanism of single-molecule switches,{{Cite journal |last1=Alemani |first1=Micol |last2=Peters |first2=Maike V. |last3=Hecht |first3=Stefan |last4=Rieder |first4=Karl-Heinz |last5=Moresco |first5=Francesca |last6=Grill |first6=Leonhard |date=2006-11-01 |title=Electric Field-Induced Isomerization of Azobenzene by STM |url=https://pubs.acs.org/doi/10.1021/ja065449s |journal=Journal of the American Chemical Society |language=en |volume=128 |issue=45 |pages=14446–14447 |doi=10.1021/ja065449s |pmid=17090013 |bibcode=2006JAChS.12814446A |issn=0002-7863|url-access=subscription }} based on intramolecular isomerization or proton transfer. In addition, his group found that a strong influence of the immediate environment on each molecule existed – caused both by the atomic lattice of the surface{{Cite journal |last1=Dri |first1=Carlo |last2=Peters |first2=Maike V. |last3=Schwarz |first3=Jutta |last4=Hecht |first4=Stefan |last5=Grill |first5=Leonhard |date=November 2008 |title=Spatial periodicity in molecular switching |url=https://www.nature.com/articles/nnano.2008.269 |journal=Nature Nanotechnology |language=en |volume=3 |issue=11 |pages=649–653 |doi=10.1038/nnano.2008.269 |pmid=18989329 |bibcode=2008NatNa...3..649D |issn=1748-3387|url-access=subscription }} and single atoms in the vicinity of the molecule.{{Cite journal |last1=Kumagai |first1=Takashi |last2=Hanke |first2=Felix |last3=Gawinkowski |first3=Sylwester |last4=Sharp |first4=John |last5=Kotsis |first5=Konstantinos |last6=Waluk |first6=Jacek |last7=Persson |first7=Mats |last8=Grill |first8=Leonhard |date=January 2014 |title=Controlling intramolecular hydrogen transfer in a porphycene molecule with single atoms or molecules located nearby |url=https://www.nature.com/articles/nchem.1804 |journal=Nature Chemistry |language=en |volume=6 |issue=1 |pages=41–46 |doi=10.1038/nchem.1804 |pmid=24345945 |bibcode=2014NatCh...6...41K |issn=1755-4330|hdl=11858/00-001M-0000-0014-7472-2 |hdl-access=free }} His contributions to the field of molecular dynamics on surfaces include rolling{{Cite journal |last1=Grill |first1=L. |last2=Rieder |first2=K.-H. |last3=Moresco |first3=F. |last4=Rapenne |first4=G. |last5=Stojkovic |first5=S. |last6=Bouju |first6=X. |last7=Joachim |first7=C. |date=February 2007 |title=Rolling a single molecular wheel at the atomic scale |url=https://www.nature.com/articles/nnano.2006.210 |journal=Nature Nanotechnology |language=en |volume=2 |issue=2 |pages=95–98 |doi=10.1038/nnano.2006.210 |pmid=18654226 |bibcode=2007NatNa...2...95G |issn=1748-3387|url-access=subscription }} the first molecular wheels across a surface, activating molecular motors with light,{{Cite journal |last1=Saywell |first1=Alex |last2=Bakker |first2=Anne |last3=Mielke |first3=Johannes |last4=Kumagai |first4=Takashi |last5=Wolf |first5=Martin |last6=García-López |first6=Víctor |last7=Chiang |first7=Pinn-Tsong |last8=Tour |first8=James M. |last9=Grill |first9=Leonhard |date=2016-12-27 |title=Light-Induced Translation of Motorized Molecules on a Surface |url=https://pubs.acs.org/doi/10.1021/acsnano.6b05650 |journal=ACS Nano |language=en |volume=10 |issue=12 |pages=10945–10952 |doi=10.1021/acsnano.6b05650 |pmid=27783488 |issn=1936-0851|url-access=subscription }} and moving individual molecules over relatively large distances with extremely high precision.{{Cite web |date=6 September 2023 |title=Nano-Forscher der Uni Graz entwickelten neuartigen molekularen Motor |url=https://science.apa.at/power-search/2632496016597912369 |access-date=4 December 2024 |website=APA Science |language=de}}{{Cite journal |last1=Civita |first1=Donato |last2=Kolmer |first2=Marek |last3=Simpson |first3=Grant J. |last4=Li |first4=An-Ping |last5=Hecht |first5=Stefan |last6=Grill |first6=Leonhard |date=2020-11-20 |title=Control of long-distance motion of single molecules on a surface |url=https://www.science.org/doi/10.1126/science.abd0696 |journal=Science |language=en |volume=370 |issue=6519 |pages=957–960 |doi=10.1126/science.abd0696 |pmid=33214276 |bibcode=2020Sci...370..957C |issn=0036-8075}}{{Cite web |last=mdr.de |title=Grazer Forscher versenden und empfangen einzelne Moleküle {{!}} MDR.DE |url=https://www.mdr.de/wissen/forscher-versenden-und-empfangen-molekuele-100.html |access-date=2024-12-04 |website=www.mdr.de |language=de}} By combining a molecule with a surface, his group discovered a novel type of molecular motor that can move unidirectionally with 100% efficiency, and even transport individual carbon monoxide molecules as "cargo".{{Cite journal |last1=Simpson |first1=Grant J. |last2=Persson |first2=Mats |last3=Grill |first3=Leonhard |date=2023-09-07 |title=Adsorbate motors for unidirectional translation and transport |url=https://www.nature.com/articles/s41586-023-06384-y |journal=Nature |language=en |volume=621 |issue=7977 |pages=82–86 |doi=10.1038/s41586-023-06384-y |pmid=37673992 |bibcode=2023Natur.621...82S |issn=0028-0836|url-access=subscription }} This system has been described as "a nanoscale bulldozer".{{cite journal |doi=10.1038/scientificamerican1223-14a |doi-access=free |title=Nanoscale Bulldozer |date=2023 |last1=Cutts |first1=Elise |journal=Scientific American |volume=329 |issue=5 |page=14 |pmid=39017309 }}

Grill developed, together with Stefan Hecht, "covalent on-surface polymerization",{{Cite journal |last1=Grill |first1=Leonhard |last2=Dyer |first2=Matthew |last3=Lafferentz |first3=Leif |last4=Persson |first4=Mats |last5=Peters |first5=Maike V. |last6=Hecht |first6=Stefan |date=November 2007 |title=Nano-architectures by covalent assembly of molecular building blocks |url=https://www.nature.com/articles/nnano.2007.346 |journal=Nature Nanotechnology |language=en |volume=2 |issue=11 |pages=687–691 |doi=10.1038/nnano.2007.346 |pmid=18654406 |bibcode=2007NatNa...2..687G |issn=1748-3387|url-access=subscription }} in which molecular building blocks are connected to construct highly defined and stable networks on surfaces.{{Cite journal |last1=Grill |first1=Leonhard |last2=Hecht |first2=Stefan |date=February 2020 |title=Covalent on-surface polymerization |url=https://www.nature.com/articles/s41557-019-0392-9 |journal=Nature Chemistry |language=en |volume=12 |issue=2 |pages=115–130 |doi=10.1038/s41557-019-0392-9 |pmid=31996811 |bibcode=2020NatCh..12..115G |issn=1755-4330|url-access=subscription }}{{Cite web |date=2023-04-03 |title=Steirer des Tages: Auf Du und Du mit den kleinsten Maschinen |url=https://www.kleinezeitung.at/steiermark/6271234/Steirer-des-Tages_Auf-Du-und-Du-mit-den-kleinsten-Maschinen |access-date=2024-12-04 |website=www.kleinezeitung.at |language=de}}

Awards

  • 2024 Research Prize of the Province of Styria (Forschungspreis des Landes Steiermark){{Cite web |last=Rupprecht |first=Wissenschaft-Land Steiermark, Anita |title=Forschungspreise des Landes Steiermark |url=https://www.wissenschaft.steiermark.at/cms/ziel/76925500/de/#tb10 |access-date=2024-11-22 |website=Wissenschaft - Land Steiermark |language=de}}
  • 2023 Advanced Grant of the European Research Council (ERC){{Cite journal |last1=Simpson |first1=Grant J. |last2=García-López |first2=Víctor |last3=Petermeier |first3=Philipp |last4=Grill |first4=Leonhard |last5=Tour |first5=James M. |date=July 2017 |title=How to build and race a fast nanocar |url=https://www.nature.com/articles/nnano.2017.137 |journal=Nature Nanotechnology |language=en |volume=12 |issue=7 |pages=604–606 |doi=10.1038/nnano.2017.137 |pmid=28681857 |bibcode=2017NatNa..12..604S |issn=1748-3387|url-access=subscription }}
  • 2017 Winner of the first Nanocar Race (together with Grant Simpson and James Tour),{{Cite journal |last1=Rapenne |first1=Gwénaël |last2=Joachim |first2=Christian |date=2017-06-06 |title=The first nanocar race |url=https://www.nature.com/articles/natrevmats201740 |journal=Nature Reviews Materials |language=en |volume=2 |issue=6 |page=17040 |doi=10.1038/natrevmats.2017.40 |bibcode=2017NatRM...217040R |issn=2058-8437|url-access=subscription }}{{Cite AV media |url=https://www.youtube.com/watch?v=vFZLmesIdWQ |title=American-Austrian NanoPrix Team is winner of the first NanoCarRace |date=2017-10-05 |last=unigraz |access-date=2024-12-04 |via=YouTube}} selected as Research of the Year 2017 by the C&EN Journal of the American Chemical Society{{cite journal |doi=10.3390/molecules23030612 |doi-access=free |title=From the Synthesis of Nanovehicles to Participation in the First Nanocar Race—View from the French Team |date=2018 |last1=Jacquot De Rouville |first1=Henri-Pierre |last2=Kammerer |first2=Claire |last3=Rapenne |first3=Gwénaël |journal=Molecules |volume=23 |issue=3 |page=612 |pmid=29518034 |pmc=6017560 }}
  • 2011 Feynman Prize in Nanotechnology of the Foresight Institute{{Cite web |title=2011 Foresight Institute Feynman Prize |url=https://legacy.foresight.org/about/2011Feynman.html |access-date=2024-11-22 |website=legacy.foresight.org}}
  • 2010 Young Leaders in Science scholarship of the Schering Foundation

References

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