Lists of metalloids
{{Short description|none}}
{{Use dmy dates|date=June 2020}}
This is a list of 194 sources that list elements classified as metalloids. The sources are listed in chronological order. Lists of metalloids differ since there is no rigorous widely accepted definition of metalloid (or its occasional alias, 'semi-metal'). Individual lists share common ground, with variations occurring at the margins. The elements most often regarded as metalloids are boron, silicon, germanium, arsenic, antimony and tellurium.{{#tag:ref|Lack of a rigorous definition:
- Goldsmith RH 1982, 'Metalloids', Journal of Chemical Education, vol. 59, no. 6, pp. 526–527, {{doi|10.1021/ed059p526}}
- Hawkes SJ 2001, 'Semimetallicity', Journal of Chemical Education, vol. 78, no. 12, pp. 1686–87, {{doi|10.1021/ed078p1686}}|group=n}} Other sources may subtract from this list, add a varying number of other elements, or both.
Overview
{{periodic table (metalloid)}}
class="wikitable sortable" style="font-size:85%; text-align:center;" |
colspan=2 | Element
! Citations ! Frequency |
---|
colspan=2 |
! style="font-size:85%;" | in n = 194 ! style="font-size:85%;" | 194 = 100% |
! ! ! |
style="text-align:left; background:{{element color|metalloid citeclass 1 of 4}}"|Arsenic
|style="background:{{element color|metalloid citeclass 1 of 4}}; text-align:left"| As |style="background:{{element color|metalloid citeclass 1 of 4}}"|191.5 |style="background:{{element color|metalloid citeclass 1 of 4}}"|99% |
style="text-align:left; background:{{element color|metalloid citeclass 1 of 4}}"|Tellurium
|style="background:{{element color|metalloid citeclass 1 of 4}}; text-align:left"| Te |style="background:{{element color|metalloid citeclass 1 of 4}}"|190.5 |style="background:{{element color|metalloid citeclass 1 of 4}}"|98% |
style="text-align:left; background:{{element color|metalloid citeclass 1 of 4}}"|Germanium
|style="background:{{element color|metalloid citeclass 1 of 4}}; text-align:left"| Ge |style="background:{{element color|metalloid citeclass 1 of 4}}"|184.5 |style="background:{{element color|metalloid citeclass 1 of 4}}" data-sort-value="95.1" |95% |
style="text-align:left; background:{{element color|metalloid citeclass 1 of 4}}"|Silicon
|style="background:{{element color|metalloid citeclass 1 of 4}}; text-align:left"| Si |style="background:{{element color|metalloid citeclass 1 of 4}}"|183.5 |style="background:{{element color|metalloid citeclass 1 of 4}}" data-sort-value="94.6" |95% |
style="text-align:left; background:{{element color|metalloid citeclass 1 of 4}}"|Antimony
|style="background:{{element color|metalloid citeclass 1 of 4}}; text-align:left"| Sb |style="background:{{element color|metalloid citeclass 1 of 4}}"|169.5 |style="background:{{element color|metalloid citeclass 1 of 4}}"|87% |
style="text-align:left; background:{{element color|metalloid citeclass 1 of 4}}"|Boron
|style="background:{{element color|metalloid citeclass 1 of 4}}; text-align:left"| B |style="background:{{element color|metalloid citeclass 1 of 4}}"|166 |style="background:{{element color|metalloid citeclass 1 of 4}}"|86% |
style="text-align:left; background:{{element color|metalloid citeclass 2 of 4}}"|Polonium
|style="background:{{element color|metalloid citeclass 2 of 4}}; text-align:left"| Po |style="background:{{element color|metalloid citeclass 2 of 4}}"|94.5 |style="background:{{element color|metalloid citeclass 2 of 4}}"|49% |
style="text-align:left; background:{{element color|metalloid citeclass 2 of 4}}"|Astatine
|style="background:{{element color|metalloid citeclass 2 of 4}}; text-align:left"| At |style="background:{{element color|metalloid citeclass 2 of 4}}"|77 |style="background:{{element color|metalloid citeclass 2 of 4}}"|40% |
style="text-align:left; background:{{element color|metalloid citeclass 3 of 4}}"|Selenium
|style="background:{{element color|metalloid citeclass 3 of 4}}; text-align:left"| Se |style="background:{{element color|metalloid citeclass 3 of 4}}"|46 |style="background:{{element color|metalloid citeclass 3 of 4}}"|24% |
style="text-align:left; background:{{element color|metalloid citeclass 4 of 4}}"|Aluminium
|style="background:{{element color|metalloid citeclass 4 of 4}}; text-align:left"| Al |style="background:{{element color|metalloid citeclass 4 of 4}}"|18 |style="background:{{element color|metalloid citeclass 4 of 4}}"|9.3% |
style="text-align:left; background:{{element color|metalloid citeclass 4 of 4}}"|Carbon
|style="background:{{element color|metalloid citeclass 4 of 4}}; text-align:left"| C |style="background:{{element color|metalloid citeclass 4 of 4}}"|16.5 |style="background:{{element color|metalloid citeclass 4 of 4}}"|8.5% |
style="text-align:left;" | Bismuth
|style="text-align:left;" | Bi |11.5 |5.9% |
style="text-align:left;" | Phosphorus
|style="text-align:left;" | P |10 |5.2% |
style="text-align:left;" | Beryllium
|style="text-align:left;" | Be |7.5 |3.9% |
style="text-align:left;" | Tin
|style="text-align:left;" | Sn |5.5 |2.8% |
style="text-align:left;" | Sulfur
|style="text-align:left;" | S |3 |1.5% |
style="text-align:left;" | Livermorium
|style="text-align:left;" | Lv |3 |1.5% |
style="text-align:left;" | Iodine
|style="text-align:left;" | I |2.5 |1.3% |
style="text-align:left;" | Flerovium
|style="text-align:left;" | Fl |1 |0.5% |
style="text-align:left;" | Gallium
|style="text-align:left;" | Ga |1 |0.5% |
style="text-align:left;" | Hydrogen
|style="text-align:left;" | H |1 |0.5% |
style="text-align:left;" | Lead
|style="text-align:left;" | Pb |1 |0.5% |
style="text-align:left;" | Moscovium
|style="text-align:left;" | Mc |1 |0.5% |
style="text-align:left;" | Tennessine
|style="text-align:left;" | Ts |1 |0.5% |
Chronological list
This table shows which elements are included in each of 194 different lists of metalloids. A parenthesized symbol indicates an element whose inclusion in a particular metalloid list is qualified in some way by the author(s). The 'citations' rows show how many and what percentage of the authorities consider each element to be a metalloid, with qualified citations counted as one-half.
class="wikitable sortable collapsible" style="text-align:center; margin:0; width:100%;" | |||||||||||||||||||||
colspan=22 | Citations as metalloid by element | |||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
style="font-size:85%; vertical-align:top; text-align:left; line-height:115%;"
! colspan=2 rowspan=2 style="font-size:120%; vertical-align:middle; text-align:right;" | Element !style="background:{{element color|metalloid citeclass 1of4}}"|Arsenic !style="background:{{element color|metalloid citeclass 1of4}}"|Tellu{{shy}}rium !style="background:{{element color|metalloid citeclass 1of4}}"|Germa{{shy}}nium !style="background:{{element color|metalloid citeclass 1of4}}"|Silicon !style="background:{{element color|metalloid citeclass 1of4}}"|Anti{{shy}}mony !style="background:{{element color|metalloid citeclass 1of4}}"|Boron !style="background:{{element color|metalloid citeclass 2of4}}"|Polo{{shy}}nium !style="background:{{element color|metalloid citeclass 2of4}}"|Asta{{shy}}tine !style="background:{{element color|metalloid citeclass 3of4}}"|Sele{{shy}}nium !style="background:{{element color|metalloid citeclass 4of4}}"|Alu{{shy}}minium !style="background:{{element color|metalloid citeclass 4of4}}"|Carbon !Tin ! Other ! style="background:{{element color|table header}};" | Count | |||||||||||||||||||||
style="background:{{element color|metalloid citeclass 1of4}}"|As
!style="background:{{element color|metalloid citeclass 1of4}}"|Te !style="background:{{element color|metalloid citeclass 1of4}}"|Ge !style="background:{{element color|metalloid citeclass 1of4}}"|Si !style="background:{{element color|metalloid citeclass 1of4}}"|Sb !style="background:{{element color|metalloid citeclass 1of4}}"|B !style="background:{{element color|metalloid citeclass 2of4}}"|Po !style="background:{{element color|metalloid citeclass 2of4}}"|At !style="background:{{element color|metalloid citeclass 3of4}}"|Se !style="background:{{element color|metalloid citeclass 4of4}}"|Al !style="background:{{element color|metalloid citeclass 4of4}}"|C !Bi !P !Be !Sn !S !Lv !I ! ! style="background:{{element color|table header}};" | {{abbr|avg|Average number of metalloids cited in one list}} | |||||||||||||||||||||
colspan=2 style="text-align:right;" |Citations {{nobold|(with qualification)}}* !style="background:{{element color|metalloid citeclass 1of4}}"|191.5 !style="background:{{element color|metalloid citeclass 1of4}}"|190.5 !style="background:{{element color|metalloid citeclass 1of4}}"|184.5 !style="background:{{element color|metalloid citeclass 1of4}}"|183.5 !style="background:{{element color|metalloid citeclass 1of4}}"|169.5 !style="background:{{element color|metalloid citeclass 1of4}}"|166 !style="background:{{element color|metalloid citeclass 2of4}}"|94.5 !style="background:{{element color|metalloid citeclass 2of4}}"|77 !style="background:{{element color|metalloid citeclass 3of4}}"|46 !style="background:{{element color|metalloid citeclass 4of4}}"|18 !style="background:{{element color|metalloid citeclass 4of4}}"|16.5 !11.5 !10 !7.5 !5.5 !3 !3 !2.5 !6 ! style="background:{{element color|table header}}; font-style:normal" | 7.15 | |||||||||||||||||||||
colspan=2 style="text-align:right;" |{{nobold|1=(% out of 194)}}
!style="background:{{element color|metalloid citeclass 1of4}}"|99% !style="background:{{element color|metalloid citeclass 1of4}}"|98% !style="background:{{element color|metalloid citeclass 1of4}}"|95% !style="background:{{element color|metalloid citeclass 1of4}}"|95% !style="background:{{element color|metalloid citeclass 1of4}}"|87% !style="background:{{element color|metalloid citeclass 1of4}}"|86% !style="background:{{element color|metalloid citeclass 2of4}}"|49% !style="background:{{element color|metalloid citeclass 2of4}}"|40% !style="background:{{element color|metalloid citeclass 3of4}}"|24% !style="background:{{element color|metalloid citeclass 4of4}}"|9.3% !style="background:{{element color|metalloid citeclass 4of4}}"|8.5% !5.9% !5.2% !3.9% !2.8% !1.5% !1.5% !1.3% !3.1% ! style="background:{{element color|table header}};" | | |||||||||||||||||||||
style="line-height:110%;"
! Source ! Yr !style="background-color:{{element color|metalloid citeclass 1of4}}"| !style="background-color:{{element color|metalloid citeclass 1of4}}"| !style="background-color:{{element color|metalloid citeclass 1of4}}"| !style="background-color:{{element color|metalloid citeclass 1of4}}"| !style="background-color:{{element color|metalloid citeclass 1of4}}"| !style="background-color:{{element color|metalloid citeclass 1of4}}"| !style="background-color:{{element color|metalloid citeclass 2of4}}"| !style="background-color:{{element color|metalloid citeclass 2of4}}"| !style="background-color:{{element color|metalloid citeclass 3of4}}"| !style="background-color:{{element color|metalloid citeclass 4of4}}"| !style="background-color:{{element color|metalloid citeclass 4of4}}"| ! ! ! ! ! ! ! ! !style="background-color:{{element color|table header}};" | | |||||||||||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | SimmonsSimmons LM 1947, 'A modification of the periodic table', Journal of Chemical Education, December, pp. 588–591 (589) {{doi|10.1021/ed024p588}} | 1947 | As | Te | Sb | Se | 4 | |||||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Pauling{{cite book|last1=Pauling |first1=L |author-link=Linus Pauling |year=1949 |title=General chemistry |publisher=WH Freeman, San Francisco |page=65}} | 1949 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Szabó & LakatosSzabó ZG & Lakatos B 1954, 'The new form of the periodic table and new periodic functions', Acta Chimica Academiae Scientiarum Hungaricae, IV 2–4, pp. 129–149 (133) | 1954 | As | Te | Ge | Si | Sb | B | Po | At | Al | Be | 10 | |||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Dull, Metcalfe & WilliamsDull CE, Metcalfe HC & Williams JE 1958, Modern chemistry, Henry Holt and Company, New York, pp. 59–60, 62 | 1958 | As | Te | Ge | Si | Sb | B | Po | At | Al | 9 | ||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | FreyFrey PR 1958, College chemistry, 2nd ed., Prentice-Hall, Englewood Cliffs, NJ, p. 118 | 1958 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Johnstone & MillerJohnstone RT & Miller SE 1960, Occupational diseases and industrial medicine, Saunders, Philadelphia, p. 262 | 1960 | As | Te | Ge | Si | Sb | B | Se | C | P | 9 | ||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Edwards et al.Edwards JO, Ellison HR, Luaro CG & Lorand JP 1961, 'Factors which influence the stability of anionic complexes', in S Kirschner, Advances in the chemistry of the coordination compounds: Proceedings of the sixth international conference on coordination chemistry, Macmillan, New York, pp. 230–237 (230) | 1961 | As | Te | Ge | Si | Sb | B | Se | I | 8 | |||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | BondBond GC 1962, Catalysis by metals, Academic Press, London, p. 8 | 1962 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Swift & SchaeferSwift EH & Schaefer WP 1962, Qualitative elemental analysis, WH Freeman, San Francisco, p. 100 | 1962 | As | Ge | Si | Sb | B | Bi | 6 | |||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | HoffmanHoffman KB 1963, Chemistry for the applied sciences, Prentice-Hall, Englewood Cliffs, NJ, p. 34 | 1963 | As | Te | Ge | Si | Sb | B | Be | 7 | ||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | NathansNathans MW 1963, Elementary chemistry, Prentice-Hall, Englewood Cliffs, NJ, p. 122 | 1963 | As | Te | Ge | Si | Sb | B | At | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Bailar, Moeller & KleinbergBailar JC, Moeller T & Kleinberg J 1965, University chemistry, DC Heath, Boston, p. 332 | 1965 | As | Te | Ge | Se | 4 | |||||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | SelwoodSelwood PW 1965, General chemistry, 4th ed., Holt, Rinehart and Winston, New York, inside back cover | 1965 | As | Te | Ge | Si | Sb | B | Po | At | Al | Bi | Sn | Ga | 12 | |||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Bassett et al.Bassett LG, Bunce SC, Carter AE, Clark HM & Hollinger HB 1966, Principles of chemistry, Prentice-Hall, Englewood Cliffs, NJ, pp. 127, 602 | 1966 | Te | Ge | Si | Sb | B | Po | Al | Be | 8 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | HultgrenHultgren HH 1966, 'Metalloids, in GL Clark & GG Hawley (eds), The encyclopedia of inorganic chemistry, 2nd ed., Reinhold Publishing, New York, pp. 648–649 (648) | 1966 | As | Te | Ge | Si | Sb | Se | C | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Metcalfe, Williams & CastkaMetcalfe HC, Williams JE & Castka JF 1966, Modern chemistry, Hollt, Rinehart and Winston, New York, pp. 466–67 | 1966 | As | Te | Ge | Si | Sb | B | Po | (Al) | 7.5 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | RochowRochow EG 1966, The metalloids, DC Heath, Boston, pp. 3, 7–8 | 1966 | As | Te | Ge | Si | Sb | B | (Po) | (At) | (Se) | (C) | (Bi) | (P) | 9 | |||||||
style="background:#f7f7f7;"
| style="text-align:left;" | MahanMahan BH 1967, University chemistry, Addison-Wesley, Reading, MA, p. 448 | 1967 | As | Te | Ge | Si | B | 5 | ||||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Paul, King & FarinholtPaul MA, King EJ & Farinholt LH 1967, General chemistry, Harcourt, Brace & World, New York, p. 135 | 1967 | As | Te | Ge | Si | Sb | Se | 6 | |||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | SiebringSiebring BR 1967, Chemistry, Macmillan, New York, p. 70 | 1967 | As | Te | Ge | Si | Sb | B | Po | Al | 8 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Cotton & LynchCotton FA & Lynch LD 1968, Chemistry: An investigative approach, Houghton Mifflin, Boston, p. 226 | 1968 | As | Te | Ge | Si | Sb | B | At | Se | C | 9 | ||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | DunstanDunstan S 1968, Principles of chemistry, D Van Nostrand, Princeton, NJ, pp. 310, 409 | 1968 | As | Te | (Ge) | Sb | Po | Al | Bi | Be | Sn | Pb | 7.5 | |||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Tyrell & WarrenTyrell LWM & Warren RK 1968, Principles of chemical science: A student's text, Edward Arnold (Publishers), n.p., p. 111 | 1968 | As | Te | (Ge) | Si | (Sb) | B | (Po) | At | (Se) | (Al) | (C) | (P) | (I) | 9.5 | ||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Williams, Embree & DeBeyWilliams AL, Embree HD & DeBey HJ 1968, Introduction to chemistry, Addison-Wesley, Reading MA, inside back cover | 1968 | As | Te | Ge | Si | Sb | B | Po | Al | 8 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | CheddChedd G 1969, Half-way elements, Aldus Books, London, p. 24 | 1969 | As | Te | Ge | Si | Sb | B | Po | At | 8 | |||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | HäggHägg G 1969, General and inorganic chemistry, John Wiley & Sons, New York, p. 92 | 1969 | As | Te | Ge | Sb | At | Sn | 6 | |||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | HolumHolum JR 1969, Introduction to principles of chemistry, John Wiley & Sons, New York, p. 59 | 1969 | As | Te | Ge | Si | Sb | B | Po | At | Al | 9 | ||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | HunterHunter D 1969, The diseases of occupations, Little, Brown, & Co., Boston, p. 232 | 1969 | As | Te | Si | Sb | Se | 5 | ||||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | MoodyMoody BJ 1969, Comparative inorganic chemistry, 2nd ed., Edward Arnold, London, pp. 67–68 | 1969 | As | Te | Ge | Si | Sb | B | Po | At | Al | Be | 10 | |||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Dickerson, Gray & HaightDickerson RE, Gray HB & Haight GP 1970, Chemical principles, WA Benjamin, New York, p. 160 | 1970 | As | Te | Ge | Si | Sb | B | 6 | |||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Hardwick & KnoblerHardwick ER & Knobler CM 1979, Chemistry: Man and matter, Xerox College, Waltham, MA, inside back cover | 1970 | As | Te | Ge | Si | Sb | B | 6 | |||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Williams, Embree & DeBayWilliams AL, Embree HD & DeBay HJ 1970, General chemistry, Addison-Wesley, Reading, MA, p. 55 | 1970 | As | Te | Ge | Si | Sb | B | Po | Al | Be | 9 | ||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | DicksonDickson TR 1971, Introduction to chemistry, John Wiley & Sons, New York, p. 160 | 1971 | As | Te | Ge | Si | Sb | Po | 6 | |||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | EmsleyEmsley J 1971, The inorganic chemistry of the non-metals, Methuen Educational, London, p. 1 | 1971 | As | Te | Ge | Sb | 4 | |||||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Nitz & DhonauNitz OW & Dhonau CA 1971, Chemistry: A brief introduction, Willard Grant, Boston, p. 64 | 1971 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Pimentel & SpratleyPimentel GC & Spratley RD 1971, Understanding chemistry, Holden-Day, San Francisco, p. 664 | 1971 | As | Te | Ge | Si | Sb | B | (Po) | (At) | Se | C | 9 | |||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | BarrowBarrow GM 1972, General chemistry, Wadsworth, Belmont CA, p. 162 | 1972 | As | Te | Ge | Si | B | 5 | ||||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Choppin & JohnsenChoppin GR & Johnsen RH 1972, Introductory chemistry, Addison-Wesley, Reading MA, p. 346 | 1972 | As | Te | Ge | Si | Sb | B | Se | 7 | ||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | HorvathHorvath AL 1973, 'Critical temperature of elements and the periodic system' Journal of Chemical Education, vol 50, no. 5, pp. 335–336 (336) | 1973 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | PascoePascoe KJ 1973, Properties of materials for electrical engineers, John Wiley & Sons, p. 7 | 1973 | Te | Ge | Si | B | At | Se | C | P | 8 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Seager & StokerSeager SL & Stoker HS 1973, Chemistry: A science for today, Scott, Foresman and Company, Glenview, Illinois, p. 58 | 1973 | As | Te | Ge | Si | Sb | B | Po | At | Al | Be | 10 | |||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Allen & KeeferAllen TL & Keefer RM 1974, Chemistry: Experiment and theory, Harper & Row, New York, p. 235 | 1974 | As | Te | Ge | Si | Sb | B | At | Se | 8 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | AndrewsAndrews DH 1974, Chemistry: A humanistic view, McGraw-Hill, New York, p. 217 | 1974 | As | Te | Si | B | At | 5 | ||||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Day & JohnsonDay RA & Johnson RC 1974, General chemistry, Prentice-Hall, Englewood Cliffs, NJ, p. 145 | 1974 | As | Te | Ge | Si | Sb | Po | At | 7 | ||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | DicksonDickson TR 1974, Understanding chemistry: From atoms to attitude, John Wiley & Sons, New York, p. 32 | 1974 | As | Te | Ge | Si | Sb | Po | At | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | DuffyDuffy JA 1974, General inorganic chemistry, 2nd ed., Longman, London, p. 53 | 1974 | As | Te | Ge | Sb | Se | 5 | ||||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | FullerFuller EC 1974, Chemistry and man's environment, Houghton Mifflin, Boston, p. 186 | 1974 | As | Te | Ge | Si | B | Se | C | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | NordmannNordmann J 1974, What is chemistry: a chemical view of nature, Harper & Row, New York, p. 152 | 1974 | As | Te | Ge | Si | B | Po | At | Se | 8 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | O'ConnorO'Connor RF 1974, Chemical principles and their biological implications, Hamilton Publishing, Santa Barbara, CA, p. 84 | 1974 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Rock & GerholdRock PA & Gerhold GA 1974, Chemistry: Principles and applications, WB Saunders, Philadelphia, p. 535 | 1974 | As | Te | Ge | Si | Sb | B | Po | At | 8 | |||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Pauling & PaulingPauling L & Pauling P 1975, Chemistry, WH Freeman, San Francisco, p. 114 | 1975 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
style="background:#f7f7f7;"
| style="text-align:left;" | Hearst & IfftHearst JE & Ifft JB 1976, Contemporary chemistry, WH Freeman, San Francisco, p. 104 | 1976 | As | Te | Ge | Si | Sb | B | Se | 7 | ||||||||||||
style="background:#fdfdfd;"
| style="text-align:left;" | Tyler MillerTyler Miller G 1976, Chemistry: A contemporary approach, Wadsworth, Belmont CA, p. 44 | 1976 | As | Te | Ge | Si | Sb | B | Po | At | Al | H | 10 | |||||||||
style="background:#f7f7f7;"
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| style="text-align:left;" | Řezanka & SiglerŘezanka T & Sigler K 2008, 'Biologically active compounds of semi-metals', in Atta-ur-Rahman (ed.), Studies in natural products chemistry, vol. 35, Elsevier, Amsterdam, pp. 835–922 (836) | 2008 | As | Te | Si | B | At | Se | 6 | |||||||||||||
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| style="text-align:left;" | Tro & NeuTro NJ & Neu D 2008, Chemistry in focus: A molecular view of our world, Brooks/Cole, Belmont, CA, p. 75 | 2008 | As | Te | Ge | Si | Sb | B | 6 | |||||||||||||
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| style="text-align:left;" | ValleroVallero DA 2008, Fundamentals of air pollution, Academic Press/Elsevier, Burlington MA, p. 200 | 2008 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
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| style="text-align:left;" | Brown et al.Brown TL, Le May, HE, Bursten BE, Murphy & Woodward 2009, Chemistry: The central science, 11th ed., Pearson Education, Upper Saddle River, NJ, p. 49 | 2009 | As | Te | Ge | Si | Sb | B | 6 | |||||||||||||
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| style="text-align:left;" | Burrows et al.Burrows A, Holman J, Parsons A, Pilling G & Price G 2009, Chemistry3: Introducing inorganic, organic and physical chemistry, Oxford University, Oxford, p. 1192 | 2009 | As | Te | Ge | Si | Sb | B | Se | 7 | ||||||||||||
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| style="text-align:left;" | Castor-PerryCastor-Perry S 2009, 'This week in science history – Mendeleev's periodic table', in [http://www.thenakedscientists.com/HTML/content/interviews/interview/1074/ Science Interviews], The Naked Scientists: Science Radio & Science Podcasts, viewed 14 July 2011 | 2009 | As | Te | Ge | Si | Sb | B | Po | At | I | 9 | ||||||||||
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| style="text-align:left;" | Cracolice & PetersCracolice MS & Peters EI 2009, Introductory chemistry: An active learning approach, Brooks/Cole, Belmont, CA, p. 336 | 2009 | As | Te | Ge | Si | Sb | B | At | 7 | ||||||||||||
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| style="text-align:left;" | EconomouEconomou EN 2009, The physics of solids: Essentials and beyond, Springer, Heidelberg, p. 59 | 2009 | As | Te | Ge | Si | Sb | B | Po | At | Al | 9 | ||||||||||
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| style="text-align:left;" | HabashiHabashi F 2009, 'Metals: Typical and less typical, transition and inner transition,' Foundations of Chemistry, vol. 12, no. 1, pp. 31–39 | 2009 | As | Te | Ge | Si | Sb | B | Po | Se | Bi | 9 | ||||||||||
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| style="text-align:left;" | Hein & ArenaHein M & Arena S 2009, Foundations of college chemistry, John Wiley and Sons, alternate 13th ed., New York, p. 49 | 2009 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
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| style="text-align:left;" | LeachLeach M 2009, 'Periodic table chemical of substances under standard conditions', [http://www.meta-synthesis.com/webbook/35_pt/pt3.html The chemogenesis webook], viewed 14 July 2011 | 2009 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
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| style="text-align:left;" | ManningManning P 2009, Chemical bonds, Infobase, New York, p. 105 | 2009 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
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| style="text-align:left;" | McMurray & FayMcMurray J & Fay RC 2009, General chemistry: Atoms first, Prentice Hall, Upper Saddle River, NJ, p. 767 | 2009 | As | Te | Ge | Si | Sb | B | At | 7 | ||||||||||||
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| style="text-align:left;" | Reger, Goode & BallReger DL, Goode SR & Ball DW 2009, Chemistry: Principles & practice, Brooks/Cole, Belmont, CA, p. 56 | 2009 | As | Te | Ge | Si | Sb | B | 6 | |||||||||||||
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| style="text-align:left;" | SchneppSchnepp R 2009, Hazardous materials: Awareness and operations, Jones & Bartlett Learning, Sudbury, MA, p. 30 | 2009 | As | Te | Ge | Si | Sb | B | Po | At | 8 | |||||||||||
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| style="text-align:left;" | Shubert & LeybaShubert D & Leyba J 2009, Chemistry and physics for nurse anesthesia: A student centred approach, Springer, NY, p. 41 | 2009 | As | Te | Ge | Si | Sb | B | 6 | |||||||||||||
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| style="text-align:left;" | Whitten et al.Whitten KW, Davis RE, Peck ML, Stanley GG 2009, Chemistry, 9th ed. Revised, Brooks/Cole, Belmont, CA, p. 134 | 2009 | As | Te | Ge | Si | Sb | B | At | 7 | ||||||||||||
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| style="text-align:left;" | Aldinger & WeberrussAldinger F & Weberruss VA 2010, Advanced ceramics and future materials: An introduction to structures, properties, technologies, methods, Wiley-VCH, Weinheim, p. 49 | 2010 | As | Te | Ge | Si | Sb | B | 6 | |||||||||||||
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| style="text-align:left;" | FayerFayer MD 2010, Absolutely small: How quantum theory explains our everyday world, American Management Association, New York, p. 161 | 2010 | As | Te | Ge | Si | Sb | B | Po | At | 8 | |||||||||||
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| style="text-align:left;" | GrayGray T 2010, [http://theodoregray.com/periodictable/Elements/Metalloids/index.s7.html Metalloids (7)], viewed 2 June 2021 | 2010 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
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| style="text-align:left;" | GroysmanGroysman A 2009, Corrosion for everybody, Springer, Dordrecht, p. 4 | 2010 | As | Te | Ge | Si | Sb | Po | 6 | |||||||||||||
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| style="text-align:left;" | Halka & NordstromHalka M & Nordstrom B 2010, Nonmetals, Infobase, New York, p. xiv | 2010 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
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| style="text-align:left;" | Lombi E & Holm PELombi E & Holm PE 2010, 'Metalloids, soil chemistry and the environment', in TP Jahn (ed.), MIPS and their role in the exchange of metalloids, Landes Bioscience, Austin< TX, 33–46(33) | 2010 | As | Te | Ge | Si | Sb | B | Po | At | 8 | |||||||||||
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| style="text-align:left;" | NEST AssociationNational Earth Science Teachers Association 2010, 'Metals, nonmetals, & metalloids', [http://www.windows2universe.org/earth/geology/metals.html Windows to the universe], viewed 14 July 2011 | 2010 | As | Te | Ge | Si | Sb | B | At | 7 | ||||||||||||
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| style="text-align:left;" | RCCSResearch Centre for Computational Science 2010, [http://ccinfo.ims.ac.jp/periodic/ The periodic table of the elements], Okazaki Research Facilities, National Institutes of Natural Sciences, Aichi, Japan, viewed 14 July 2011 | 2010 | As | Te | Ge | Si | Sb | B | Po | At | Se | C | Bi | P | Sn | 13 | ||||||
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| style="text-align:left;" | WeinerWeiner ER 2010, Applications of environmental aquatic chemistry: A practical guide, 2nd ed., CRC Press, Boca Raton, Florida, p. 109 | 2010 | As | Te | Ge | Si | Sb | B | Po | 7 | ||||||||||||
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| style="text-align:left;" | Encyclopædia Britannica Online{{cite encyclopedia|encyclopedia=Encyclopædia Britannica Online |year=2011 |url=http://www.britannica.com/EBchecked/topic/377645/metalloid |title=Metalloid |access-date=14 July 2011}} | 2011 | As | Te | Ge | Si | Sb | B | (Po) | (At) | 7 | |||||||||||
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class="sortbottom" style="font-size:85%; vertical-align:top; text-align:left; line-height:115%;"
! colspan=2 style="font-size:120%; vertical-align:middle; text-align:right;" | Element !style="background:{{element color|metalloid citeclass 1of4}}"|Arsenic !style="background:{{element color|metalloid citeclass 1of4}}"|Tellu{{shy}}rium !style="background:{{element color|metalloid citeclass 1of4}}"|Germa{{shy}}nium !style="background:{{element color|metalloid citeclass 1of4}}"|Silicon !style="background:{{element color|metalloid citeclass 1of4}}"|Anti{{shy}}mony !style="background:{{element color|metalloid citeclass 1of4}}"|Boron !style="background:{{element color|metalloid citeclass 2of4}}"|Polo{{shy}}nium !style="background:{{element color|metalloid citeclass 2of4}}"|Asta{{shy}}tine !style="background:{{element color|metalloid citeclass 3of4}}"|Sele{{shy}}nium !style="background:{{element color|metalloid citeclass 4of4}}"|Alu{{shy}}minium !style="background:{{element color|metalloid citeclass 4of4}}"|Carbon !Bis{{shy}}muth !Phos{{shy}}phorus !Beryl{{shy}}lium !Tin !Sulfur !Liver{{shy}}morium !Iodine !Other !style="background:{{element color|table header}};" | |
- () Parenthesized symbols indicate elements whose inclusion in a particular metalloid list is qualified in some way by the author(s). It is counted as 0.5 citation.
There is an average of 7.15 elements per metalloid list.
Appearance frequency clusters
File:Metalloid cluster frequencies.png
Elements cited in the listed sources (as of August 2011; n = 194) have appearance frequencies that occur in clusters of comparable values. The diamonds in the graph mark the mean appearance frequency of each cluster.
- Cluster 1 (93%): B, Si, Ge, As, Sb, Te
- Cluster 2 (44%): Po, At
- Cluster 3 (24%): Se
- Cluster 4 (9%): C, Al
- Cluster 5 (5%): Be, P, Bi
- Cluster 6 (3%): Sn
- Cluster 7 (1%): H, Ga, S, I, Pb, Fl, Mc, Lv, Ts
The resulting geometric trend line has the formula y = 199.47e−0.7423x and an R2 value of 0.9962.{{#tag:ref|The R2 value is a measure of how close a formula fits a set of data points. Values fall between 0.0 and 1.0, with those near 1.0 indicating a good fit.|group=n}}{{clear}}
Elements regarded as metalloids
The elements commonly classified as metalloids are boron, silicon, germanium, arsenic, antimony and tellurium.{{#tag:ref|Elements commonly classified as metalloids:
- Goldsmith RH 1982, 'Metalloids', Journal of Chemical Education, vol. 59, no. 6, pp. 526–7 (526), {{doi|10.1021/ed059p526}}
- Mann JB, Meek TL & Allen LC 2000, 'Configuration energies of the main group elements', Journal of the American Chemical Society, vol. 122, no. 12, pp. 2780–3 (2783), {{doi|10.1021/ja992866e}}: Mann et al. refer to these elements as 'the recognized metalloids'.
- Kotz JC, Treichel P & Weaver GC 2009, Chemistry and Chemical Reactivity, 7th ed., Brooks/Cole, Belmont, California, {{ISBN|1439041318}}|group=n}}
The status of polonium and astatine is not settled. Most authors recognise one or the other, or both, as metalloids; Herman, Hoffmann and Ashcroft, on the basis of relativistic modelling, predict astatine will be a monatomic metal.{{#tag:ref|Polonium and astatine:
- Hawkes SJ 2001, 'Semimetallicity?', Journal of Chemical Education, vol. 78, no. 12, pp. 1686–87, {{doi|10.1021/ed078p1686}}
- Holt, Rinehart & Wilson c. 2007 [http://go.hrw.com/resources/go_sc/periodic/Po_At_Metalloids.pdf 'Why polonium and astatine are not metalloids in HRW texts'], viewed 8 February 2013
- Hawkes SJ 2010, 'Polonium and astatine are not semimetals', Journal of Chemical Education, vol. 87, no. 8, p. 783, {{doi|10.1021/ed100308w}}
- Hermann A, Hoffmann R & Ashcroft NW 2013, 'Condensed Astatine: Monatomic and Metallic', Physical Review Letters, vol. 111, pp. 11604–1−11604-5, {{doi|10.1103/PhysRevLett.111.116404}}
- Vernon RE 2013, 'Which Elements Are Metalloids?', Journal of Chemical Education, vol. 90, no. 12, pp. 1703–1707, {{doi|10.1021/ed3008457}}|group=n}} One or more of carbon, aluminium, phosphorus, selenium, tin or bismuth, these being periodic table neighbours of the elements commonly classified as metalloids, are sometimes recognised as metalloids.{{#tag:ref|Carbon, aluminium, phosphorus, selenium, tin, bismuth:
- Rochow EG 1966, The metalloids, DC Heath and Company, Boston, pp. 7–8
- Cobb HM 2012, Dictionary of Metals, ASM International, Materials Park, OH, p. 145, {{ISBN|9781615039784}}
- Walker CH 2012, Organic Pollutants: An Ecotoxicological Perspective, 2nd ed., CRC Press, Boca Raton, FL, p. 163, {{ISBN|9781420062588}}
- Whiten K, Davis R, Peck L & Stanley G 2014, Chemistry, 10th ed., Brooks/Cole Cengage Learning, Belmont, CA, p. 134, {{ISBN|9781133610663}}|group=n}}
Selenium, in particular, is commonly designated as a metalloid in environmental chemistry{{#tag:ref|Selenium as a metalloid in environmental chemistry:
- Meyer JS, Adams WJ, Brix KV, Luoma SM, Mount DR, Stubblefield WA & Wood CM (eds) 2005, Toxicity of dietborne metals to aquatic organisms, Proceedings from the Pellston Workshop on Toxicity of Dietborne Metals to Aquatic Organisms, 27 July – 1 August 2002, Fairmont Hot Springs, British Columbia, Canada, Society of Environmental Toxicology and Chemistry, Pensacola, Florida, p. 284, {{ISBN|1880611708}}
- Weiner ER 2013, Applications of Environmental Aquatic Chemistry: A Practical Guide, 3rd ed., CRC Press, Boca Raton, FL, p. 181, {{ISBN|9781439853320}}|group=n}} on account of similarities in its aquatic chemistry with that of arsenic and antimony.{{#tag:ref|Similarities in the aquatic chemistry of selenium, arsenic, and antimony:
- US Environmental Protection Agency 1988, Ambient aquatic life water quality criteria for antimony (III), draft, Office of Research and Development, Environmental Research Laboratories, Washington, p. 1
- De Zuane J 1997, Handbook of drinking water quality, 2nd ed., John Wiley & Sons, New York, p. 93, {{ISBN|047128789X}}
- Uden PC 2005, 'Speciation of selenium,' in R Cornelis, J Caruso, H Crews & K Heumann (eds), Handbook of elemental speciation II: Species in the environment, food, medicine and occupational health, John Wiley & Sons, Chichester, pp. 346–65 (347–8), {{ISBN|0470855983}}
- Dev N 2008, 'Modelling selenium fate and transport in Great Salt Lake Wetlands' PhD dissertation, University of Utah, ProQuest, Ann Arbor, Michigan, pp. 2–3, {{ISBN|054986542X}}|group=n}} There are fewer references to beryllium, in spite of its periodic table position adjoining the dividing line between metals and nonmetals. Isolated references in the literature can also be found to the categorisation of other elements as metalloids. These elements include: hydrogen, nitrogen,{{#tag:ref|Nitrogen:
Rausch MD 1960, 'Cyclopentadienyl compounds of metals and metalloids', Journal of Chemical Education, vol. 37, no. 11, pp. 568–78, {{doi|10.1021/ed037p568}}|group=n}} sulfur,{{#tag:ref|Sulfur:
- Chalmers B 1959, Physical metallurgy, John Wiley & Sons, New York, p. 72
- US Bureau of Naval Personnel 1965, Shipfitter 3 & 2, US Government Printing Office, Washington, p. 26|group=n}} zinc,{{#tag:ref|Zinc:
Siebring BR 1967, Chemistry, MacMillan, New York, p. 613|group=n}} gallium,{{#tag:ref|Gallium:
Wiberg N 2001, [https://books.google.com/books?id=Mtth5g59dEIC Inorganic chemistry], Academic Press, San Diego, p. 282, {{ISBN|0123526515}}|group=n}} iodine,{{#tag:ref|Iodine:
- Friend JN 1953, Man and the chemical elements, 1st ed., Charles Scribner's Sons, New York, p. 68
- Rausch MD 1960, 'Cyclopentadienyl compounds of metals and metalloids', Journal of Chemical Education, vol. 37, no. 11, pp. 568–78, {{doi|10.1021/ed037p568}}|group=n}} lead,{{#tag:ref|Lead:
Murray JF 1928, 'Cable-sheath corrosion', Electrical World, vol. 92, Dec 29, pp. 1295–7 (1295)|group=n}} and radon{{#tag:ref|Radon:
- Hampel CA & Hawley GG 1966, The encyclopedia of chemistry, 3rd ed., Van Nostrand Reinhold, New York,p. 950
- Stein L 1985, 'New evidence that radon is a metalloid element: ion-exchange reactions of cationic radon', Journal of the Chemical Society, Chemical Communications, vol. 22, pp. 1631–2, {{doi|10.1039/C39850001631}}
- Stein L 1987, 'Chemical properties of radon' in PK Hopke (ed.) 1987, Radon and its decay products: Occurrence, properties, and health effects, American Chemical Society, Washington DC, pp. 240–51 (240, 247–8), {{ISBN|0841210152}}|group=n}} (citations are for references other than those listed above).
Notes
{{Reflist|group=n}}
References
{{Reflist}}
{{Navbox periodic table}}
{{list of lists |science |listcat=Metalloids}}
{{DEFAULTSORT:Metalloids}}