MIL-53

|+Overview of reported MIL-53(M) materials

!Name

!Metal center and

oxidation state

!Year of

publication

!Alternative

name

!Reference

|V³⁺

| rowspan="2" |2002

| rowspan="2" |MIL-47

| rowspan="2" |{{citation|surname1=Karin Barthelet, Jérôme Marrot, Didier Riou, Gérard Férey|periodical=Angewandte Chemie International Edition|title=A Breathing Hybrid Organic–Inorganic Solid with Very Large Pores and High Magnetic Characteristics|volume=41|issue=2|at=pp. 281–284|issn=1521-3773|date=2002|language=German|doi=10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO;2-Y|pmid=12491409 }}{{citation|surname1=Hervé Leclerc, Thomas Devic, Sabine Devautour-Vinot, Philippe Bazin, Nathalie Audebrand|periodical=The Journal of Physical Chemistry C|title=Influence of the Oxidation State of the Metal Center on the Flexibility and Adsorption Properties of a Porous Metal Organic Framework: MIL-47(V)|volume=115|issue=40|at=pp. 19828–19840|issn=1932-7447|date=2011-10-13|language=German|doi=10.1021/jp206655y}}

|Cr³⁺

|2002

|

|C. Serre, F. Millange, C. Thouvenot, M. Noguès, G. Marsolier, D. Louër, and G. Férey: Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or Cr^III(OH)·{O₂C-C₆H₄-CO₂}·{HO₂C-C₆H₄-CO₂H}_x·H₂O_y. In: J. Am. Chem. Soc. 2002, 124, 45, S. 13519–13526, {{doi|10.1021/ja0276974}}.{{citation|title=Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first Criii hybrid inorganic–organic microporous solids: Criii(OH)·{O2C–C6H4–CO2}·{HO2C–C6H4–CO2H}xElectronic supplementary information (ESI) available: crystal data, atomic coordinates and metrical parameters for MIL-53as and MIL-53ht.|date=2002-04-11|url=http://xlink.rsc.org/?DOI=b201381a|volume=|issue=8|periodical=Chemical Communications|at=pp. 822–823|language=German|doi=10.1039/b201381a|surname1=Franck Millange, Christian Serre, Gérard Férey|pmid=12132491|url-access=subscription}}

|Al³⁺

|2004

|

|{{Cite journal|last1=Loiseau|first1=Thierry|last2=Serre|first2=Christian|last3=Huguenard|first3=Clarisse|last4=Fink|first4=Gerhard|last5=Taulelle|first5=Francis|last6=Henry|first6=Marc|last7=Bataille|first7=Thierry|last8=Férey|first8=Gérard|date=2004-03-19|title=A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration|journal=Chemistry - A European Journal|language=en|volume=10|issue=6|pages=1373–1382|doi=10.1002/chem.200305413|pmid=15034882|issn=0947-6539}}

|Fe³⁺

|2005

|

|{{citation|surname1=Tabatha R. Whitfield, Xiqu Wang, Lumei Liu, Allan J. Jacobson|periodical=Solid State Sciences|title=Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions|volume=7|issue=9|at=pp. 1096–1103|date=September 2005|language=German|doi=10.1016/j.solidstatesciences.2005.03.007|bibcode=2005SSSci...7.1096W}}

|2005

|

|

|In³⁺

|2005

|

|{{citation|surname1=Ekaterina V. Anokhina, Marie Vougo-Zanda, Xiqu Wang, Allan J. Jacobson|periodical=Journal of the American Chemical Society|title=In(OH)BDC·0.75BDCH 2 (BDC = Benzenedicarboxylate), a Hybrid Inorganic−Organic Vernier Structure|volume=127|issue=43|at=pp. 15000–15001|issn=0002-7863|date=2005-10-07|language=German|doi=10.1021/ja055757a|pmid=16248619}}

|Co²⁺

|2005

|MOF-71

|{{citation|surname1=Nathaniel L. Rosi, Jaheon Kim, Mohamed Eddaoudi, Banglin Chen, Michael O'Keeffe|periodical=Journal of the American Chemical Society|title=Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units|volume=127|issue=5|at=pp. 1504–1518|issn=0002-7863|date=2005-01-13|language=German|doi=10.1021/ja045123o|pmid=15686384}}{{citation|surname1=Alexis S. Munn, Guy J. Clarkson, Franck Millange, Yves Dumont, Richard I. Walton|periodical=CrystEngComm|title=M(ii) (M = Mn, Co, Ni) variants of the MIL-53-type structure with pyridine-N-oxide as a co-ligand|volume=15|issue=45|at=p. 9679|issn=1466-8033|date=2013|language=German|doi=10.1039/c3ce41268g|url=http://xlink.rsc.org/?DOI=c3ce41268g

|url-access=subscription}}

|Ga³⁺

|2008

|

|{{citation|surname1=Marie Vougo-Zanda, Jin Huang, Ekaterina Anokhina, Xiqu Wang, Allan J. Jacobson|periodical=Inorganic Chemistry|title=Tossing and Turning: Guests in the Flexible Frameworks of Metal(III) Dicarboxylates|volume=47|issue=24|at=pp. 11535–11542|issn=0020-1669|date=2008-12-15|language=German|doi=10.1021/ic800008f|pmid=18433098}}

|Mn²⁺

|2010

|

|{{citation|surname1=Guohai Xu, Xiaoguang Zhang, Peng Guo, Chengling Pan, Hongjie Zhang|periodical=Journal of the American Chemical Society|title=Mn II -based MIL-53 Analogues: Synthesis Using Neutral Bridging μ 2 -Ligands and Application in Liquid-Phase Adsorption and Separation of C6−C8 Aromatics|volume=132|issue=11|at=pp. 3656–3657|issn=0002-7863|date=2010-03-24|language=German|doi=10.1021/ja910818a|pmid=20196605}}

|Sc³⁺

|2011

|

|{{Cite journal|last1=Mowat|first1=John P.S.|last2=Miller|first2=Stuart R.|last3=Slawin|first3=Alexandra M.Z.|last4=Seymour|first4=Valerie R.|last5=Ashbrook|first5=Sharon E.|last6=Wright|first6=Paul A.|date=June 2011|title=Synthesis, characterisation and adsorption properties of microporous scandium carboxylates with rigid and flexible frameworks|journal=Microporous and Mesoporous Materials|language=en|volume=142|issue=1|pages=322–333|doi=10.1016/j.micromeso.2010.12.016}}

|Ni²⁺

|2013

|

|

|+Overview of MIL-53(M) materials with functional linker molecules

! rowspan="2" |Functional linker

! colspan="6" |Metal center(M)

2-Aminobenzene-1,4-dicarboxylate

|{{citation|surname1=Karen Leus, Sarah Couck, Matthias Vandichel, Gauthier Vanhaelewyn, Ying-Ya Liu|periodical=Physical Chemistry Chemical Physics|title=Synthesis, characterization and sorption properties of NH2-MIL-47|volume=14|issue=44|at=p. 15562|issn=1463-9076|date=2012|language=German|doi=10.1039/c2cp42137b|pmid=23073025|bibcode=2012PCCP...1415562L|url=http://xlink.rsc.org/?DOI=c2cp42137b

|url-access=subscription}}

| -

|{{citation|surname1=Tim Ahnfeldt, Daniel Gunzelmann, Thierry Loiseau, Dunja Hirsemann, Jürgen Senker|periodical=Inorganic Chemistry|title=Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology|volume=48|issue=7|at=pp. 3057–3064|issn=0020-1669|date=2009-04-06|language=German|doi=10.1021/ic8023265|pmid=19245258|hdl=10536/DRO/DU:30064444|hdl-access=free}}{{citation|surname1=Tim Ahnfeldt, Nathalie Guillou, Daniel Gunzelmann, Irene Margiolaki, Thierry Loiseau|periodical=Angewandte Chemie International Edition|title=[Al 4 (OH) 2 (OCH 3 ) 4 (H 2 N-bdc) 3 ]⋅ x H 2 O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick|volume=48|issue=28|at=pp. 5163–5166|date=2009-06-29|language=German|doi=10.1002/anie.200901409|pmid=19504512}}

|{{citation|surname1=Sebastian Bauer, Christian Serre, Thomas Devic, Patricia Horcajada, Jérôme Marrot|periodical=Inorganic Chemistry|title=High-Throughput Assisted Rationalization of the Formation of Metal Organic Frameworks in the Iron(III) Aminoterephthalate Solvothermal System|volume=47|issue=17|at=pp. 7568–7576|issn=0020-1669|date=2008-08-06|language=German|doi=10.1021/ic800538r|pmid=18681423}}

|{{citation|surname1=Pablo Serra-Crespo, Elena Gobechiya, Enrique V. Ramos-Fernandez, Jana Juan-Alcañiz, Alberto Martinez-Joaristi|periodical=Langmuir|title=Interplay of Metal Node and Amine Functionality in NH 2 -MIL-53: Modulating Breathing Behavior through Intra-framework Interactions|volume=28|issue=35|at=pp. 12916–12922|issn=0743-7463|date=2012-09-04|language=German|doi=10.1021/la302824j|pmid=22891682}}

|

2-Fluorobenzene-1,4-dicarboxylate

|{{citation|surname1=Shyam Biswas, Tom Rémy, Sarah Couck, Dmytro Denysenko, Geert Rampelberg|periodical=Physical Chemistry Chemical Physics|title=Partially fluorinated MIL-47 and Al-MIL-53 frameworks: influence of functionalization on sorption and breathing properties|volume=15|issue=10|at=p. 3552|issn=1463-9076|date=2013|language=German|doi=10.1039/c3cp44204g|pmid=23381460|bibcode=2013PCCP...15.3552B|url=http://xlink.rsc.org/?DOI=c3cp44204g

}}

| -

|

| -

| -

| -

2-Chlorobenzene-1,4-dicarboxylate

|{{citation|surname1=Shyam Biswas, Danny E. P. Vanpoucke, Toon Verstraelen, Matthias Vandichel, Sarah Couck|periodical=The Journal of Physical Chemistry C|title=New Functionalized Metal–Organic Frameworks MIL-47-X (X = −Cl, −Br, −CH 3, −CF 3, −OH, −OCH 3 ): Synthesis, Characterization, and CO 2 Adsorption Properties|volume=117|issue=44|at=pp. 22784–22796|issn=1932-7447|date=2013-11-07|language=German|doi=10.1021/jp406835n}}

|{{citation|surname1=Pascal G. Yot, Ke Yang, Vincent Guillerm, Florence Ragon, Vladimir Dmitriev|periodical=European Journal of Inorganic Chemistry|title=Impact of the Metal Centre and Functionalization on the Mechanical Behaviour of MIL-53 Metal-Organic Frameworks: Impact of the Metal Centre and Functionalization on the Mechanical Behaviour of MIL-53 Metal-Organic Frameworks|volume=2016|issue=27|at=pp. 4424–4429|date=September 2016|language=German|doi=10.1002/ejic.201600263|hdl=10023/11147|s2cid=100565312 |hdl-access=free}}

|{{citation|surname1=Shyam Biswas, Tim Ahnfeldt, Norbert Stock|periodical=Inorganic Chemistry|title=New Functionalized Flexible Al-MIL-53-X (X = -Cl, -Br, -CH 3, -NO 2, -(OH) 2 ) Solids: Syntheses, Characterization, Sorption, and Breathing Behavior|volume=50|issue=19|at=pp. 9518–9526|issn=0020-1669|date=2011-10-03|language=German|doi=10.1021/ic201219g|pmid=21899293}}

|{{citation|surname1=Thomas Devic, Patricia Horcajada, Christian Serre, Fabrice Salles, Guillaume Maurin|periodical=Journal of the American Chemical Society|title=Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions|volume=132|issue=3|at=pp. 1127–1136|issn=0002-7863|date=2010-01-27|language=German|doi=10.1021/ja9092715|pmid=20038143}}

| -

| -

2-Bromobenzene-1,4-dicarboxylate

|

| -

|

|

|{{citation|surname1=Lei Wu, Gérald Chaplais, Ming Xue, Shilun Qiu, Joël Patarin|periodical=RSC Advances|title=New functionalized MIL-53(In) solids: syntheses, characterization, sorption, and structural flexibility|volume=9|issue=4|at=pp. 1918–1928|issn=2046-2069|date=2019|language=German|doi=10.1039/C8RA08522F|pmid=35516115 |pmc=9059721 |bibcode=2019RSCAd...9.1918W |doi-access=free}}

| -

2-Iodobenzene-1,4-dicarboxylate

| -

| -

|

| -

| -

| -

2-Nitrobenzene-1,4-dicarboxylate

| -

| -

|

| -

|

| -

Benzene-1,2,4-tricarboxylate

| -

| -

|{{citation|surname1=Nele Reimer, Barbara Gil, Bartosz Marszalek, Norbert Stock|periodical=CrystEngComm|title=Thermal post-synthetic modification of Al-MIL-53–COOH: systematic investigation of the decarboxylation and condensation reaction|volume=14|issue=12|at=p. 4119|issn=1466-8033|date=2012|language=German|doi=10.1039/c2ce06649a|url=http://xlink.rsc.org/?DOI=c2ce06649a

|url-access=subscription}}

| -

| -

| -

2-Methylbenzene-1,4-dicarboxylate

|

|

|

|

| -

| -

2-Trifluormethylbenzene-1,4-dicarboxylate

|

| -

| -

| -

| -

| -

2-Hydroxybenzene-1,4-dicarboxylate

|

| -

|{{citation|surname1=Dieter Himsl, Dirk Wallacher, Martin Hartmann|periodical=Angewandte Chemie International Edition|title=Improving the Hydrogen-Adsorption Properties of a Hydroxy-Modified MIL-53(Al) Structural Analogue by Lithium Doping|volume=48|issue=25|at=pp. 4639–4642|date=2009-06-08|language=German|doi=10.1002/anie.200806203|pmid=19455533}}

| -

| -

| -

2-Methoxybenzene-1,4-dicarboxylate

|

| -

| -

| -

| -

| -

2-Sulfobenzene-1,4-dicarboxylate

| -

| -

|{{citation|surname1=Jinzhu Chen, Kegui Li, Limin Chen, Ruliang Liu, Xing Huang|periodical=Green Chem.|title=Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal–organic frameworks|volume=16|issue=5|at=pp. 2490–2499|issn=1463-9262|date=2014|language=German|doi=10.1039/C3GC42414F|url=http://xlink.rsc.org/?DOI=C3GC42414F

|url-access=subscription}}

| -

| -

| -

2-Isocyanatbenzene-1,4-dicarboxylate

| -

| -

|{{citation|surname1=Christophe Volkringer, Seth M. Cohen|periodical=Angewandte Chemie International Edition|title=Generating Reactive MILs: Isocyanate- and Isothiocyanate-Bearing MILs through Postsynthetic Modification|volume=49|issue=27|at=pp. 4644–4648|date=2010-06-21|language=German|doi=10.1002/anie.201001527|pmid=20480478}}

| -

| -

| -

2-Isothiocyanatbenzene-1,4-dicarboxylate

| -

| -

|

| -

| -

| -

2,5-Dimethylbenzene-1,4-dicarboxylate

|{{citation|surname1=Andrea Centrone, Takuya Harada, Scott Speakman, T. Alan Hatton|periodical=Small|title=Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties|volume=6|issue=15|at=pp. 1598–1602|date=2010-07-07|language=German|doi=10.1002/smll.201000773|pmid=20623532}}

| -

| -

| -

| -

| -

2,5-Dihydroxybenzene-1,4-dicarboxylate

|

| -

|

|

|

| -

2,5-Dithiolbenzene-1,4-dicarboxylate

| -

| -

|{{citation|surname1=Alexis S. Munn, Franck Millange, Michel Frigoli, Nathalie Guillou, Clément Falaise|periodical=CrystEngComm|title=Iodine sequestration by thiol-modified MIL-53(Al)|volume=18|issue=41|at=pp. 8108–8114|issn=1466-8033|date=2016|language=German|doi=10.1039/C6CE01842D|url=http://xlink.rsc.org/?DOI=C6CE01842D

}}

| -

| -

| -

2,5-Difluorobenzene-1,4-dicarboxylate

|{{citation|surname1=Shyam Biswas, Sarah Couck, Dmytro Denysenko, Asamanjoy Bhunia, Maciej Grzywa|periodical=Microporous and Mesoporous Materials|title=Sorption and breathing properties of difluorinated MIL-47 and Al-MIL-53 frameworks|volume=181|at=pp. 175–181|date=2013-11-15|language=German|doi=10.1016/j.micromeso.2013.07.030}}

| -

|

| -

| -

| -

2,5-Bis(trifluormethyl)benzene-1,4-dicarboxylate

|{{citation|surname1=Claudia Zlotea, Delphine Phanon, Matjaz Mazaj, Daniela Heurtaux, Vincent Guillerm|periodical=Dalton Transactions|title=Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs|volume=40|issue=18|at=p. 4879|issn=1477-9226|date=2011|language=German|doi=10.1039/c1dt10115c|pmid=21431158|url=http://xlink.rsc.org/?DOI=c1dt10115c

|url-access=subscription}}

| -

| -

|

| -

| -

2-Amino-5-nitrobenzene-1,4-dicarboxylate

| -

| -

|{{citation|surname1=Karen Markey, Martin Krüger, Tomasz Seidler, Helge Reinsch, Thierry Verbiest|periodical=The Journal of Physical Chemistry C|title=Emergence of Nonlinear Optical Activity by Incorporation of a Linker Carrying the p -Nitroaniline Motif in MIL-53 Frameworks|volume=121|issue=45|at=pp. 25509–25519|issn=1932-7447|pmc=5694968|pmid=29170688|date=2017-11-16|language=German|doi=10.1021/acs.jpcc.7b09190}}

| -

|

|

Benzene-1,2,4,5-tetracarboxylate

| -

| -

|{{citation|surname1=Christophe Volkringer, Thierry Loiseau, Nathalie Guillou, Gérard Férey, Mohamed Haouas|periodical=Inorganic Chemistry|title=High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization|volume=49|issue=21|at=pp. 9852–9862|issn=0020-1669|date=2010-10-05|language=German|doi=10.1021/ic101128w|pmid=20923169}}

MIL-121

|{{citation|surname1=Morgane Sanselme, Jean-Marc Grenèche, Myriam Riou-Cavellec, Gérard Férey|periodical=Solid State Sciences|title=The first ferric carboxylate with a three-dimensional hydrid open-framework (MIL-82): its synthesis, structure, magnetic behavior and study of its dehydration by Mössbauer spectroscopy|volume=6|issue=8|at=pp. 853–858|date=August 2004|language=German|doi=10.1016/j.solidstatesciences.2004.04.001|bibcode=2004SSSci...6..853S}} MIL-82

| -

| -

2,3,5,6-tetramethylbenzene-1,4-dicarboxylate

| -

|{{citation|surname1=Christian Serre, Franck Millange, Thomas Devic, Nathalie Audebrand, Wouter Van Beek|periodical=Materials Research Bulletin|title=Synthesis and structure determination of new open-framework chromium carboxylate MIL-105 or CrIII(OH)·{O2C–C6(CH3)4–CO2}·nH2O|volume=41|issue=8|at=pp. 1550–1557|date=2006-08-10|language=German|doi=10.1016/j.materresbull.2006.01.013}}

MIL-105

| -

| -

| -

| -

2,3,5,6-Tetrachlorobenzene-1,4-dicarboxylate

|

| -

| -

| -

| -

| -

2,3,5,6-Tetrabromobenzene-1,4-dicarboxylate

|

| -

| -

| -

| -

| -

Naphthalene-1,4-dicarboxylate

|

| -

|{{citation|surname1=Angiolina Comotti, Silvia Bracco, Piero Sozzani, Satoshi Horike, Ryotaro Matsuda|periodical=Journal of the American Chemical Society|title=Nanochannels of Two Distinct Cross-Sections in a Porous Al-Based Coordination Polymer|volume=130|issue=41|at=pp. 13664–13672|issn=0002-7863|date=2008-10-15|language=German|doi=10.1021/ja802589u|pmid=18798624}}

| -

| -

| -

|+Overview of mixed-metal MIL-53 analogs

!Metal centers and

oxidation states

!Metal ratios

[-]

!Synthesis method

!Citation

|0.99 : 0.01

|Direct synthesis

hydrothermal

|{{Cite journal|last1=Mendt|first1=Matthias|last2=Jee|first2=Bettina|last3=Himsl|first3=Dieter|last4=Moschkowitz|first4=Lutz|last5=Ahnfeldt|first5=Tim|last6=Stock|first6=Norbert|last7=Hartmann|first7=Martin|last8=Pöppl|first8=Andreas|date=March 2014|title=A Continuous-Wave Electron Paramagnetic Resonance Study of Carbon Dioxide Adsorption on the Metal–Organic Frame-Work MIL-53|journal=Applied Magnetic Resonance|language=en|volume=45|issue=3|pages=269–285|doi=10.1007/s00723-014-0518-6|s2cid=94965421|issn=0937-9347}}{{Cite journal|last1=Mendt|first1=Matthias|last2=Jee|first2=Bettina|last3=Stock|first3=Norbert|last4=Ahnfeldt|first4=Tim|last5=Hartmann|first5=Martin|last6=Himsl|first6=Dieter|last7=Pöppl|first7=Andreas|date=2010-11-18|title=Structural Phase Transitions and Thermal Hysteresis in the Metal−Organic Framework Compound MIL-53 As Studied by Electron Spin Resonance Spectroscopy|journal=The Journal of Physical Chemistry C|volume=114|issue=45|pages=19443–19451|doi=10.1021/jp107487g|issn=1932-7447}}{{Cite journal|last1=Barth|first1=Benjamin|last2=Mendt|first2=Matthias|last3=Pöppl|first3=Andreas|last4=Hartmann|first4=Martin|date=2015-11-01|title=Adsorption of nitric oxide in metal-organic frameworks: Low temperature IR and EPR spectroscopic evaluation of the role of open metal sites|url=http://www.sciencedirect.com/science/article/pii/S1387181115000955|journal=Microporous and Mesoporous Materials|series=Special Issue: New Generations of Porous Metal-Organic Frameworks|language=en|volume=216|pages=97–110|doi=10.1016/j.micromeso.2015.02.020|issn=1387-1811|url-access=subscription}}

|0.99 : 0.01

0.95 : 0.05

0.71 : 0.29

0.32 : 0.68

0.13 : 0.87

|Direct synthesis

hydrothermal

|{{Cite journal|last1=Kozachuk|first1=Olesia|last2=Meilikhov|first2=Mikhail|last3=Yusenko|first3=Kirill|last4=Schneemann|first4=Andreas|last5=Jee|first5=Bettina|last6=Kuttatheyil|first6=Anusree V.|last7=Bertmer|first7=Marko|last8=Sternemann|first8=Christian|last9=Pöppl|first9=Andreas|last10=Fischer|first10=Roland A.|date=2013-09-03|title=A Solid-Solution Approach to Mixed-Metal Metal-Organic Frameworks - Detailed Characterization of Local Structures, Defects and Breathing Behaviour of Al/V Frameworks|journal=European Journal of Inorganic Chemistry|language=en|volume=2013|issue=26|pages=4546–4557|doi=10.1002/ejic.201300591}}

|?

|{{Cite journal|last1=Nevjestić|first1=Irena|last2=Depauw|first2=Hannes|last3=Gast|first3=Peter|last4=Tack|first4=Pieter|last5=Deduytsche|first5=Davy|last6=Leus|first6=Karen|last7=Van Landeghem|first7=Melissa|last8=Goovaerts|first8=Etienne|last9=Vincze|first9=Laszlo|last10=Detavernier|first10=Christophe|last11=Van Der Voort|first11=Pascal|date=2017|title=Sensing the framework state and guest molecules in MIL-53(Al) via the electron paramagnetic resonance spectrum of V IV dopant ions|url=http://xlink.rsc.org/?DOI=C7CP04760F|journal=Physical Chemistry Chemical Physics|language=en|volume=19|issue=36|pages=24545–24554|doi=10.1039/C7CP04760F|pmid=28852751|bibcode=2017PCCP...1924545N|hdl=1854/LU-8534452|issn=1463-9076|hdl-access=free}}

|0.85 : 0.15

0.99 : 0.01

|Direct synthesis

electrochemical

| rowspan="2" |{{Cite journal|last1=Osadchii|first1=Dmitrii Y.|last2=Olivos-Suarez|first2=Alma I.|last3=Szécsényi|first3=Ágnes|last4=Li|first4=Guanna|last5=Nasalevich|first5=Maxim A.|last6=Dugulan|first6=Iulian A.|last7=Crespo|first7=Pablo Serra|last8=Hensen|first8=Emiel J. M.|last9=Veber|first9=Sergey L.|last10=Fedin|first10=Matvey V.|last11=Sankar|first11=Gopinathan|date=June 2018|title=Isolated Fe Sites in Metal Organic Frameworks Catalyze the Direct Conversion of Methane to Methanol|journal=ACS Catalysis|language=en|volume=8|issue=6|pages=5542–5548|doi=10.1021/acscatal.8b00505|hdl=10754/627902|s2cid=104144811 |issn=2155-5435|hdl-access=free}}

|Post-synthetic metal-exchange

|≈ 0.70 : 0.30

≈ 0.85 : 0.15

|Direct synthesis

hydrothermal

|{{Cite journal|last1=Bignami|first1=Giulia P. M.|last2=Davis|first2=Zachary H.|last3=Dawson|first3=Daniel M.|last4=Morris|first4=Samuel A.|last5=Russell|first5=Samantha E.|last6=McKay|first6=David|last7=Parke|first7=Richard E.|last8=Iuga|first8=Dinu|last9=Morris|first9=Russell E.|last10=Ashbrook|first10=Sharon E.|date=2018|title=Cost-effective 17 O enrichment and NMR spectroscopy of mixed-metal terephthalate metal–organic frameworks|journal=Chemical Science|language=en|volume=9|issue=4|pages=850–859|doi=10.1039/C7SC04649A|issn=2041-6520|pmc=5873045|pmid=29629152}}

|0.05 : 0.95

0.10 : 0.90

0.23 : 0.77

0.50 : 0.50

0.75 : 0.25

|Direct synthesis

microwave

| rowspan="2" |{{Cite journal|last1=Depauw|first1=Hannes|last2=Nevjestić|first2=Irena|last3=De Winne|first3=Jonatan|last4=Wang|first4=Guangbo|last5=Haustraete|first5=Katrien|last6=Leus|first6=Karen|last7=Verberckmoes|first7=An|last8=Detavernier|first8=Christophe|last9=Callens|first9=Freddy|last10=De Canck|first10=Els|last11=Vrielinck|first11=Henk|date=2017|title=Microwave induced "egg yolk" structure in Cr/V-MIL-53|url=http://xlink.rsc.org/?DOI=C7CC04651K|journal=Chemical Communications|language=en|volume=53|issue=60|pages=8478–8481|doi=10.1039/C7CC04651K|pmid=28703241|issn=1359-7345|url-access=subscription}}

0.13 : 0.87

0.17 : 0.83

0.37 : 0.63

0.58 : 0.42

|Direct synthesis

solvothermal

|0.60 : 0.40

|Direct synthesis

hydrothermal

|{{Cite journal|last1=Nouar|first1=Farid|last2=Devic|first2=Thomas|last3=Chevreau|first3=Hubert|last4=Guillou|first4=Nathalie|last5=Gibson|first5=Emma|last6=Clet|first6=Guillaume|last7=Daturi|first7=Marco|last8=Vimont|first8=Alexandre|last9=Grenèche|first9=Jean Marc|last10=Breeze|first10=Matthew I.|last11=Walton|first11=Richard I.|date=2012|title=Tuning the breathing behaviour of MIL-53 by cation mixing|url=http://xlink.rsc.org/?DOI=c2cc35348b|journal=Chemical Communications|language=en|volume=48|issue=82|pages=10237–10239|doi=10.1039/c2cc35348b|pmid=22968060|issn=1359-7345|url-access=subscription}}

|0.88 : 0.12

0.76 : 0.24

0.74 : 0.26

0.49 : 0.51

|Direct synthesis

solvothermal

|{{Cite journal|last1=Breeze|first1=Matthew I.|last2=Clet|first2=Guillaume|last3=Campo|first3=Betiana C.|last4=Vimont|first4=Alexandre|last5=Daturi|first5=Marco|last6=Grenèche|first6=Jean-Marc|last7=Dent|first7=Andrew J.|last8=Millange|first8=Franck|last9=Walton|first9=Richard I.|date=2013-07-15|title=Isomorphous Substitution in a Flexible Metal–Organic Framework: Mixed-Metal, Mixed-Valent MIL-53 Type Materials|journal=Inorganic Chemistry|language=en|volume=52|issue=14|pages=8171–8182|doi=10.1021/ic400923d|pmid=23815225|s2cid=40656565 |issn=0020-1669|url=http://bib-pubdb1.desy.de/record/167766/files/Isomorphous%20REVISED%20FINAL-unmarked.pdf}}

|0.90 : 0.10

0.88 : 0.12

0.82 : 0.18

0.74 : 0.26

| rowspan="3" |Direct synthesis

solvothermal

| rowspan="3" |{{Cite journal|last1=Sun|first1=Qiao|last2=Liu|first2=Min|last3=Li|first3=Keyan|last4=Han|first4=Yitong|last5=Zuo|first5=Yi|last6=Chai|first6=Fanfan|last7=Song|first7=Chunshan|last8=Zhang|first8=Guoliang|last9=Guo|first9=Xinwen|date=2017-01-13|title=Synthesis of Fe/M (M = Mn, Co, Ni) bimetallic metal organic frameworks and their catalytic activity for phenol degradation under mild conditions|url=https://pubs.rsc.org/en/content/articlelanding/2017/qi/c6qi00441e|journal=Inorganic Chemistry Frontiers|language=en|volume=4|issue=1|pages=144–153|doi=10.1039/C6QI00441E|issn=2052-1553|url-access=subscription}}

|0.97 : 0.03

0.94 : 0.06

0.90 : 0.10

|0.91 : 0.09

0.89 : 0.11

0.84 : 0.16

0.78 : 0.22

|+Overview of mixed-linker MIL-53 analogs

!Linker 1

!Linker 2

!Linker ratios

[-]

!Metal center

!Synthesis method

!Citation

Benzene-1,4-dicarboxylate

| rowspan="2" |File:2-Aminoterephthalate.svg

2-Aminobenzene-1,4-dicarboxylate

|0.90 : 0.10

0.50 : 0.50

0.10 : 0.90

| rowspan="2" |Al³⁺

| rowspan="2" |Direct synthesis

hydrothermal

|{{Cite journal|last1=Marx|first1=Stefan|last2=Kleist|first2=Wolfgang|last3=Huang|first3=Jun|last4=Maciejewski|first4=Marek|last5=Baiker|first5=Alfons|date=2010|title=Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al)|url=http://xlink.rsc.org/?DOI=c002483j|journal=Dalton Transactions|language=en|volume=39|issue=16|pages=3795–8|doi=10.1039/c002483j|pmid=20372702|issn=1477-9226|url-access=subscription}}

0.82 : 0.18

0.51 : 0.49

0.48 : 0.62

|{{Cite journal|last1=Lescouet|first1=Tristan|last2=Kockrick|first2=Emanuel|last3=Bergeret|first3=Gérard|last4=Pera-Titus|first4=Marc|last5=Aguado|first5=Sonia|last6=Farrusseng|first6=David|date=2012|title=Homogeneity of flexible metal–organic frameworks containing mixed linkers|url=http://xlink.rsc.org/?DOI=c2jm15966j|journal=Journal of Materials Chemistry|language=en|volume=22|issue=20|pages=10287|doi=10.1039/c2jm15966j|issn=0959-9428|url-access=subscription}}{{Cite journal|last1=Lescouet|first1=Tristan|last2=Kockrick|first2=Emanuel|last3=Bergeret|first3=Gerard|last4=Pera-Titus|first4=Marc|last5=Farrusseng|first5=David|date=2011|title=Engineering MIL-53(Al) flexibility by controlling amino tags|url=http://xlink.rsc.org/?DOI=c1dt11700a|journal=Dalton Transactions|language=en|volume=40|issue=43|pages=11359–61|doi=10.1039/c1dt11700a|pmid=21975376|issn=1477-9226|url-access=subscription}}{{Cite journal|last1=Pera-Titus|first1=M.|last2=Lescouet|first2=T.|last3=Aguado|first3=S.|last4=Farrusseng|first4=D.|date=2012-05-03|title=Quantitative Characterization of Breathing upon Adsorption for a Series of Amino-Functionalized MIL-53|journal=The Journal of Physical Chemistry C|language=en|volume=116|issue=17|pages=9507–9516|doi=10.1021/jp2117856|issn=1932-7447}}

Benzene-1,4-dicarboxylate

|File:2,5-Dihydroxybenzene-1,4-dicarboxylate.svg

2,5-Dihydroxybenzene-1,4-dicarboxylate

|0.75 : 0.25

0.50 : 0.50

0.25 : 0.75

|Al³⁺

|Direct synthesis

solvothermal

|{{Cite journal|last1=Yang|first1=Jie|last2=Yan|first2=Xing|last3=Xue|first3=Teng|last4=Liu|first4=Yongshen|date=2016|title=Enhanced CO 2 adsorption on Al-MIL-53 by introducing hydroxyl groups into the framework|url=http://xlink.rsc.org/?DOI=C6RA09350G|journal=RSC Advances|language=en|volume=6|issue=60|pages=55266–55271|doi=10.1039/C6RA09350G|bibcode=2016RSCAd...655266Y |issn=2046-2069|url-access=subscription}}{{Cite journal|last1=Andonova|first1=Stanislava|last2=Ivanova|first2=Elena|last3=Yang|first3=Jie|last4=Hadjiivanov|first4=Konstantin|date=2017-08-31|title=Adsorption Forms of CO 2 on MIL-53(Al) and MIL-53(Al)–OH x As Revealed by FTIR Spectroscopy|journal=The Journal of Physical Chemistry C|language=en|volume=121|issue=34|pages=18665–18673|doi=10.1021/acs.jpcc.7b05538|issn=1932-7447}}

Benzene-1,4-dicarboxylate

|File:2-Iodobenzene-1,4-dicarboxylate.svg

2-Iodobenzene-1,4-dicarboxylate

|0.81 : 0.19

0.55 : 0.45

0.27 : 0.73

|Al³⁺

|Direct synthesis

hydrothermal

|{{Cite journal|last1=Tahmouresilerd|first1=Babak|last2=Larson|first2=Patrick J.|last3=Unruh|first3=Daniel K.|last4=Cozzolino|first4=Anthony F.|date=2018-08-28|title=Make room for iodine: systematic pore tuning of multivariate metal–organic frameworks for the catalytic oxidation of hydroquinones using hypervalent iodine|url=https://pubs.rsc.org/en/content/articlelanding/2018/cy/c8cy00794b|journal=Catalysis Science & Technology|language=en|volume=8|issue=17|pages=4349–4357|doi=10.1039/C8CY00794B|issn=2044-4761|url-access=subscription}}