Neodymium(III) sulfate
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| Reference = {{Cite web|url=https://www.chemicalbook.com/ChemicalProductProperty_EN_CB1705313.htm|title=Neodymium Sulfate | 13477-91-3}}
| Name = Neodymium(III) sulfate
| IUPACName = Neodymium(III) trisulfate
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| SystematicName =
| OtherNames = {{Unbulleted list
| Neodyous sulfate
| Neodymium sulfate
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| ImageFile =File:Neodym(III)sulfat.JPG
| ImageSize = 200px
| ImageAlt = Several dozen pink, similar-sized rectangular crystals
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| ImageCaption = Neodymium sulfate crystals
| Section1 = {{Chembox Identifiers
| 3DMet =
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| CASNo = 10101-95-8
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| ChemSpiderID = 21241399
| EINECS = 233-262-1
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| PubChem = 165814
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| UNNumber =
| UNII = 4Q1946CN7K
| StdInChI=1S/2Nd.3H2O4S/c;;3*1-5(2,3)4/h;;3*(H2,1,2,3,4)/q2*+3;;;/p-6
| StdInChIKey = OJSWEKSDNUORPG-UHFFFAOYSA-H
| SMILES = [O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[Nd+3].[Nd+3]
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| Section2 = {{Chembox Properties
| AtmosphericOHRateConstant =
| Appearance = Pink crystals
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| Density = 2.85 g/cm3
| Formula = Nd2(SO4)3
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| MolarMass = 576.7 g/mol
| MeltingPt =
| MeltingPtC = 700
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| Solubility = 8 g/100 ml (20 °C)
| SolubleOther = Soluble in sulfuric acid
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| Section3 = {{Chembox Structure
| Coordination =
| CrystalStruct = Monoclinic
| MolShape =
| SpaceGroup = C2/c
| LattConst_a = 13.76 Å
| LattConst_b = 7.20 Å
| LattConst_c = 18.65 Å
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| Section4 = {{Chembox Thermochemistry
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| Section5 = {{Chembox Explosive
| ShockSens = Not explosive
| FrictionSens = Not explosive
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| Section6 = {{Chembox Pharmacology
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| Section7 = {{Chembox Hazards
| AutoignitionPt = Not flammable
| ExploLimits =
| FlashPt = Not flammable
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| MainHazards = Irritant
| NFPA-F = 0
| NFPA-H = 1
| NFPA-R = 1
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| ExternalSDS =
| GHSPictograms = {{GHS07}}
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| HPhrases = {{H-phrases|315|319|335}}
| PPhrases = {{P-phrases|261|280|304|340|305+351+338|405|501}}
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| Section9 = {{Chembox Related
| OtherAnions = Neodymium nitrate
| OtherCations = Praseodymium(III) sulfate
| OtherFunction =
| OtherFunction_label =
| OtherCompounds = Neodymium sulfate octahydrate
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Neodymium(III) sulfate is a salt of the rare-earth metal neodymium that has the formula Nd2(SO4)3. It forms multiple hydrates, the octa-, penta-, and the dihydrate, which the octahydrate is the most common. This compound has a retrograde solubility, unlike other compounds, its solubility decreases with increasing temperature.{{cite journal |author1=Art. A. Migdisov |author2=V. V. Reukov |author3=A. E. Williams-Jones |title=A spectrophotometric study of neodymium(III) complexation in sulfate solutions at elevated temperatures |journal=Geochimica et Cosmochimica Acta |date=2005 |volume=70 |issue=4 |pages=983–992 |doi=10.1016/j.gca.2005.11.001 |language=en}} This compound is used in glass for extremely powerful lasers.
Preparation
Neodymium sulfate is produced by dissolving neodymium(III) oxide in sulfuric acid:
:{{chem2 | Nd2O3 + 3 H2SO4 -> Nd2(SO4)3 + 3 H2O }}
It can also be prepared by the reaction of neodymium(III) perchlorate and sodium sulfate.
Properties
Neodymium sulfate octahydrate decomposes at 40 °C to the pentahydrate, which in turn decomposes to the dihydrate at 145 °C. The dihydrate dehydrates to the anhydrous form at 290 °C.{{cite journal |author1=Wendlandt, W W |title=The thermal decomposition of yttrium and the rare earth metal sulphate hydrates |journal=J. Inorg. & Nuclear Chem. |date=1958 |volume=7 |issue=1–2 |pages=51–54 |language=en |doi=10.1016/0022-1902(58)80026-3}}
References
{{reflist}}
{{Neodymium compounds}}
{{Sulfates}}