Neodymium perrhenate

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| CASNo = 14020-41-8

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| CASNo_Comment = anhydrate

| CASNo2 = 18222-80-5

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| CASNo2_Comment = tetrahydrate

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| StdInChI=1S/Nd.12O.3Re/q+3;;;;;;;;;;3*-1;;;

| StdInChIKey=YWVGJWGZZGKVIR-UHFFFAOYSA-N

| SMILES = [Nd+3].[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O }}

| Section2 = {{Chembox Properties

| Formula = Nd(ReO4)3

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| Solubility = soluble}}

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Neodymium perrhenate is an inorganic compound with the chemical formula Nd(ReO4)3, which exists in anhydrous and tetrahydrate.Varfolomeev, M. B.; Plyushchev, V. E.; Rybakov, K. A. Monoclinic modification of neodymium perrhenate tetrahydrate. Zhurnal Neorganicheskoi Khimii, 1967. 12 (5): 1410-1411. {{issn|0044-457X}}.Mashonkin, V. P.; Ilyukhin, V. V.; Varfolomeev, M. B. Structure of rhombic rare earth perrhenate tetrahydrates RE(ReO4)·3.4H2O (RE = praseodymium-·dysprosium). Koordinatsionnaya Khimiya, 1977. 3 (7): 1014-1019. {{issn|0132-344X}}. It can be obtained by reacting excess neodymium oxide with 240 g/L perrhenic acid solution.Plyushchev, V. E.; Amosov, V. M.; Varfolomeev, M. B. Synthesis and certain properties of lower crystallohydrates of yttrium, lanthanum, and lanthanoid perrhenates. Doklady Akademii Nauk SSSR, 1963. 150 (1): 105-108. {{ISSN|0002-3264}}. In its solution, NdReO42+ and Nd(ReO4)2+ can be observed with stability constants of 16.5 and 23.6, respectively.Petrov, K. I.; Orlin, N. A.; Plyushchev, V. E. Neodymium perrhenate complexes studied by a spectrographic method. Zhurnal Neorganicheskoi Khimii, 1969. 14 (10): 2739-2742. {{issn|0044-457X}}.

Nd4Re6O19 can be obtained by reacting neodymium perrhenate and NdRe2 at high temperature.{{Cite journal |last=Wolfgang Jeitschko, Dieter H Heumannskämper, Marietta S Schriewer-Pöttgen, Ute Ch Rodewald |date=October 1999 |title=Preparation, Crystal Structures, and Properties of Rhenates with Multiple Re–Re Bonds: Ln2ReO5 (Ln=Sm, Eu, Gd), Ln3Re2O9 (Ln=Pr, Nd, Sm), and Ln4Re6O19 (Ln=La–Nd) |url=https://linkinghub.elsevier.com/retrieve/pii/S0022459699982373 |journal=Journal of Solid State Chemistry |language=en |volume=147 |issue=1 |pages=218–228 |doi=10.1006/jssc.1999.8237 |bibcode=1999JSSCh.147..218J |archive-url=https://web.archive.org/web/20180608082045/https://linkinghub.elsevier.com/retrieve/pii/S0022459699982373 |archive-date=2018-06-08 |access-date=2020-08-30|url-access=subscription }}

See also

References

{{Reflist}}

Category:Perrhenates

Category:Neodymium(III) compounds

{{neodymium compounds}}

{{rhenium compounds}}

{{Perrhenates}}

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