Neopentyllithium
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 424980534
| ImageFile =Neopentyllithium.svg
| ImageFile2 = Neopentyllithium-3D-balls.png
| ImageSize = 150px
| ImageAlt =
| IUPACName = Neopentyllithium
| PIN = 2,2-Dimethylpropyllithium
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 7412-67-1
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = Y3X266EZG5
| PubChem =10898631
| DTXSID = DTXSID80447510
| SMILES = CC(C)(C)C[Li]
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 10660196
| InChI = 1/C5H11.Li/c1-5(2,3)4;/h1H2,2-4H3;/rC5H11Li/c1-5(2,3)4-6/h4H2,1-3H3
| InChIKey = UWLFCNHEPBTLHT-OBZUOXEOAE
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/C5H11.Li/c1-5(2,3)4;/h1H2,2-4H3;
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = UWLFCNHEPBTLHT-UHFFFAOYSA-N}}
|Section2={{Chembox Properties
| C=5 | H=11 | Li=1
| Appearance =
| Density =
| MeltingPtC = 145.71
| BoilingPtC = 389.39
| Solubility = Decomposes
| SolubleOther = Hydrocarbons, THF, ether}}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
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Neopentyllithium is an organolithium compound with the chemical formula C5H11Li. Commercially available, it is a strong, non-nucleophilic base sometimes encountered in organometallic chemistry.
Further reading
- {{cite journal | last1 = Fraenkel | first1 = Gideon | last2 = Chow | first2 = Albert | last3 = Winchester | first3 = William R. | title = Structure and dynamic behavior of solvated neopentyllithium monomers, dimers, and tetramers: proton, carbon-13 and lithium-6 NMR | journal = Journal of the American Chemical Society | volume = 112 | pages = 6190–6198 | year = 1990 | issue = 17 | doi = 10.1021/ja00173a005| bibcode = 1990JAChS.112.6190F }}
{{Lithium compounds}}
Category:Organolithium compounds