Neopentyllithium

{{Chembox

| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 424980534

| ImageFile =Neopentyllithium.svg

| ImageFile2 = Neopentyllithium-3D-balls.png

| ImageSize = 150px

| ImageAlt =

| IUPACName = Neopentyllithium

| PIN = 2,2-Dimethylpropyllithium

| OtherNames =

|Section1={{Chembox Identifiers

| CASNo_Ref = {{cascite|correct|??}}

| CASNo = 7412-67-1

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = Y3X266EZG5

| PubChem =10898631

| DTXSID = DTXSID80447510

| SMILES = CC(C)(C)C[Li]

| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}

| ChemSpiderID = 10660196

| InChI = 1/C5H11.Li/c1-5(2,3)4;/h1H2,2-4H3;/rC5H11Li/c1-5(2,3)4-6/h4H2,1-3H3

| InChIKey = UWLFCNHEPBTLHT-OBZUOXEOAE

| StdInChI_Ref = {{stdinchicite|changed|chemspider}}

| StdInChI = 1S/C5H11.Li/c1-5(2,3)4;/h1H2,2-4H3;

| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}

| StdInChIKey = UWLFCNHEPBTLHT-UHFFFAOYSA-N}}

|Section2={{Chembox Properties

| C=5 | H=11 | Li=1

| Appearance =

| Density =

| MeltingPtC = 145.71

| BoilingPtC = 389.39

| Solubility = Decomposes

| SolubleOther = Hydrocarbons, THF, ether}}

|Section3={{Chembox Hazards

| MainHazards =

| FlashPt =

| AutoignitionPt = }}

}}

Neopentyllithium is an organolithium compound with the chemical formula C5H11Li. Commercially available, it is a strong, non-nucleophilic base sometimes encountered in organometallic chemistry.

Further reading

  • {{cite journal | last1 = Fraenkel | first1 = Gideon | last2 = Chow | first2 = Albert | last3 = Winchester | first3 = William R. | title = Structure and dynamic behavior of solvated neopentyllithium monomers, dimers, and tetramers: proton, carbon-13 and lithium-6 NMR | journal = Journal of the American Chemical Society | volume = 112 | pages = 6190–6198 | year = 1990 | issue = 17 | doi = 10.1021/ja00173a005| bibcode = 1990JAChS.112.6190F }}

{{Lithium compounds}}

Category:Organolithium compounds

Category:Non-nucleophilic bases

Category:Neopentyl compounds